Abstract
Special applications like pumping, spraying or printing of concrete require the precise adjustment of very specific rheological properties at different time steps during the casting process. Superplasticizers such as polycarboxylate ethers (PCE) can be used to obtain the required flowability, which, possibly in combination with additional rheology modifying admixtures, generate the required specified consistency. However, after the application, the concrete should change the rheological properties immediately in order to avoid deformations at rest. Therefore, the use of accelerators can be effective. Accelerators influence the hydration of cementitious materials, and thus the rheological properties over the course of time and the setting.
In this paper, the influence of different accelerators on the rheology and early hydration of cement paste as well as the interaction of accelerator and PCE are presented. Methods like rheometry, needle penetration tests and practical tests like spread flow were applied. The used accelerators showed accelerating behavior on the cement pastes without and in the presence of PCE. At the same time an influence on the rheology could be observed. This effect was less in the mixes with PCE, especially at the highest water/cement ratio (w/c).
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
References
Roussel N (2012) Understanding the rheology of concrete. Woodhead Publishing, Sawston
Myrdal R (2007) Accelerating admixtures for concrete
Justnes H, Nygaard EC (1995) Technical calcium nitrate as set accelerator for cement at low temperatures. Cem Concr Res 25:1766–1774
Justnes H (2010) Calcium nitrate as a multifunctional concrete admixture. https://de.scribd.com/document/311682442/Calcium-Nitrate-as-a-Multifunctional-Concrete-Admixture
Bost P, Regnier M, Horgnies M (2016) Comparison of the accelerating effect of various additions on the early hydration of Portland cement. Constr Build Mater 113:290–296
Land G, Stephan D (2015) Controlling cement hydration with nanoparticles. Cement Concr Compos 57:64–67
DIN (2007) Methods of test for mortar for masonry - Part 3: determination of consistence of fresh mortar (by flow table). In: EN 1015-3, ed. European committee for standardization, Brussels
Vogel R (2008) A measuring cell for special mortars. Concr Plant + Precast Technol 1:124–126
Schmidt W, Brouwers HJH, Kühne H-C, Meng B (2014) Influences of superplasticizer modification and mixture composition on the performance of self-compacting concrete at varied ambient temperatures. Cement Concr Compos 49:111–126
Schmidt W, Brouwers HJH, Kühne H-C, Meng B (2017) Interactions of polysaccharide stabilising agents with early cement hydration without and in the presence of superplasticizers. Constr Build Mater 139:584–593
Stroh J, Schlegel MC, Schmidt W, Thi YN, Meng B, Emmerling F (2016) Time-resolved in situ investigation of Portland cement hydration influenced by chemical admixtures. Constr Build Mater 106:18–26
Acknowledgement
The author would like to thank the funding from German Research Association (DFG) for the project program Opus Fluidum Futurum – Rheology of reactive, multiscale, multiphase construction materials (SPP 2005) (Project number 387092747) and the supply of cement and superplasticizer from HeidelbergCement and BASF, respectively.
Author information
Authors and Affiliations
Corresponding author
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2020 RILEM
About this paper
Cite this paper
Leinitz, S., Lu, Z., Becker, S., Stephan, D., von Klitzing, R., Schmidt, W. (2020). Influence of Different Accelerators on the Rheology and Early Hydration of Cement Paste. In: Mechtcherine, V., Khayat, K., Secrieru, E. (eds) Rheology and Processing of Construction Materials. RheoCon SCC 2019 2019. RILEM Bookseries, vol 23. Springer, Cham. https://doi.org/10.1007/978-3-030-22566-7_13
Download citation
DOI: https://doi.org/10.1007/978-3-030-22566-7_13
Published:
Publisher Name: Springer, Cham
Print ISBN: 978-3-030-22565-0
Online ISBN: 978-3-030-22566-7
eBook Packages: EngineeringEngineering (R0)