Skip to main content

Study of Corrosion Effect of Micronal® Phase Change Materials (PCM) with Different Metal Samples

  • Chapter
  • First Online:
Renewable Energy and Sustainable Buildings

Part of the book series: Innovative Renewable Energy ((INREE))

Abstract

Micronal® is a material designed for temperature regulation applications and its performance has been investigated in buildings (Cabeza et al. Energy Buildings 39:113–119, 2007). This wax mixture, classified as organic paraffin, is contained in small vessels with the core PCM and a hard coating (Micronal PCM BASF, Intelligent temperature management for buildings, 2012). Micronal® is an ideal candidate to use in solar applications due to the low melting point (20.9–25.8 °C), high heat fusion (119 kJ/kg) and non-toxic behaviour. In the past, the behaviour of Micronal® between different materials for 722 days has been investigated (Browne et al. Energy Procedia91:113–121, 2016). This experiment has been carried out to study the compatibility of the commercial PCM Micronal® with various common container materials following the ASTM G1-01. The container materials tested were copper, brass, aluminium, stainless steel and mild steel for a period of 1073 days. Stainless steel sample was determined to be the most suitable due to its negligible corrosion rate. Aluminium, copper and brass can encapsulate Micronal; however caution is advised as the maximum corrosion rate was found to be 0.70 mg/cm2year, 2.44 mg/cm2year and 2.26 mg/cm2year, respectively. Furthermore, SEM imaging has been used for a greater insight into the initial stages of corrosion which are not initially visible to the naked eye. From the results, it can be observed that copper, brass and aluminium samples have been corroded by pitting and this is well matched to the gravimetric analysis. No corrosion was observed in stainless steel samples.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 89.00
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 119.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 169.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

References

  1. Cabeza LF, Castellón C, Nogués M, Medrano M, Leppers R, Zubillaga O (2007) Use of microencapsulated PCM in concrete walls for energy savings. Energ Buildings 39(2):113–119

    Article  Google Scholar 

  2. Micronal PCM BASF, Intelligent temperature management for buildings. 2012

    Google Scholar 

  3. Browne MC, Quigley D, Hard HR, Gilligan S, Ribeiro NCC, Almeida N, McCormack SJ (2016) Assessing the thermal performance of phase change material in a photovoltaic/thermal system. Energy Procedia 91:113–121

    Article  Google Scholar 

  4. Browne MC, Norton B, McCormack SJ (2015) Phase change materials for photovoltaic thermal management. Renew Sust Energ Rev 47:762–782

    Article  Google Scholar 

  5. Browne MC, Lawlor K, Kelly A, Norton B, Cormack SJM (2015) Indoor characterisation of a photovoltaic/thermal phase change material system. Energy Procedia 70:163–171

    Article  Google Scholar 

  6. Dheep GR, Sreekumar A (2018) Investigation on thermal reliability and corrosion characteristics of glutaric acid as an organic phase change material for solar thermal energy storage applications. Appl Therm Eng 129:1189–1196

    Article  Google Scholar 

  7. Farrell AJ, Norton B, Kennedy DM (2006) Corrosive effects of salt hydrate phase change materials used with aluminium and copper. J Mater Process Technol 175(1–3):198–205

    Article  Google Scholar 

  8. Liu M, Bell S, Segarra M, Steven Tay NH, Will G, Saman W, Bruno F (Oct. 2017) A eutectic salt high temperature phase change material: thermal stability and corrosion of SS316 with respect to thermal cycling. Sol Energy Mater Sol Cells 170:1–7

    Article  Google Scholar 

  9. Cabeza LF, Roca J, Âs MN, Mehling H, Hiebler S (2002) Immersion corrosion tests on metal-salt hydrate pairs used for latent heat storage in the 48 to 58°C temperature range. Mater Corros 53:902–907

    Article  Google Scholar 

  10. Cabeza LF, Illa J, Roca J, Badia F, Mehling H, Hiebler S, Ziegler F (2001) Middle term immersion corrosion tests on metal-salt hydrate pairs used for latent heat storage in the 32 to 36 °C temperature range. Mater Corros 52:748–754

    Article  Google Scholar 

  11. Cabeza LF, Roca J, Nogueés M, Mehling H, Hiebler S (2005) Long term immersion corrosion tests on metal-PCM pairs used for latent heat storage in the 24 to 29°C temperature range. Mater Corros 56(1):33–38

    Article  Google Scholar 

  12. Sari A, Kaygusuz K (2003) Some fatty acid used for latent heat storage: thermal stability and corrosion of metals with respect to thermal cycling. Renew Energy 28:939–948

    Article  Google Scholar 

  13. Ferrer G, Sol A, Barreneche C, Martorell I, Cabeza LF (2015) Corrosion of metal containers for use in PCM energy storage. Renew Energy 76:465–469

    Article  Google Scholar 

  14. Browne MC, Boyd E, Mccormack SJ (2017) Investigation of the corrosive properties of phase change materials in contact with metals and plastic. Renew Energy 108:555–568

    Article  Google Scholar 

  15. ASTM Standard G1-01 (2001) Standard practice for preparing, cleaning, and evaluation corrosion test specimens. ASTM B Stand 1:1–8

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Rebeca Salgado .

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2020 Springer Nature Switzerland AG

About this chapter

Check for updates. Verify currency and authenticity via CrossMark

Cite this chapter

Salgado, R., Akbari, H., Brown, M.C., Reid, I., McCormack, S.J. (2020). Study of Corrosion Effect of Micronal® Phase Change Materials (PCM) with Different Metal Samples. In: Sayigh, A. (eds) Renewable Energy and Sustainable Buildings. Innovative Renewable Energy. Springer, Cham. https://doi.org/10.1007/978-3-030-18488-9_57

Download citation

  • DOI: https://doi.org/10.1007/978-3-030-18488-9_57

  • Published:

  • Publisher Name: Springer, Cham

  • Print ISBN: 978-3-030-18487-2

  • Online ISBN: 978-3-030-18488-9

  • eBook Packages: EnergyEnergy (R0)

Publish with us

Policies and ethics