Abstract
Cellulose and chitosan are naturally abundant biopolymers which can be used as ion exchange polymers in various applications. Due to their useful characteristics, a lot of research has been done on using these materials as a base for obtaining ionic polymer metal composite actuators. The present chapter discusses numerous ways of combination between polysaccharide and various electrically conductive materials such as carbon nanotubes and graphene in the presence or absence of different ionic liquids, and subsequent use of these materials to improve the actuation performance of the polysaccharide-based actuators. Though a lot of studies have been performed for obtaining optimal compositions and suitable methods in respect of polysaccharide-based ionic polymer metal composite actuators. There is still a niche to find the best composition structure and the most efficient and low-cost method of obtaining actuators in order to meet the needs of various industries. The search continues for actuators with enhanced mechanical, electrical and electroactive performance, with good durability and flexibility in processing.
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References
Singh, V., Kumar, P., Sanghi, R.: Use of microwave irradiation in the grafting modification of the polysaccharide—a review. Prog. Polym. Sci. 37, 340–364 (2012). https://doi.org/10.1016/j.progpolymsci.2011.07.005
Dias, A.M., Cortez, A.R., Barsan, M., Santos, J., Brett, C.M., de Sousa, H.C.: ACS Sustain. Chem. Eng. 1, 1480–1492 (2013). https://doi.org/10.1021/sc4002577
Chirayil, C.J., Mathew, L., Thomas, S.: Review of recent research in nano cellulose preparation from different lignocellulosic fibres. Rev. Adv. Mater Sci. 37, 20–28 (2014)
Yi, H., Wu, L.-Q., Bentley, W.E., Ghodssi, R., Rubloff, G.W., Culver, J.N., Payne, G.F.: Biofabrication with Chitosan. Biomacromolecules 6, 2881–2894 (2005). https://doi.org/10.1021/bm050410l
Li, Y., Li, G., Peng, H., Chen, K.: Facile synthesis of electroactive polypyrroleechitosan composite nanospheres with controllable diameters. Polym. Int. 60(4), 647–651 (2011). https://doi.org/10.1002/pi.2995
Silva Simone, S., Mano João, F., Reis Rui, L.: Ionic liquids in the processing and chemical modification of chitin and chitosan for biomedical applications. Green Chem. 19, 1208–1220 (2017). https://doi.org/10.1039/C6GC02827F
Tiyaboonchai, W.: Chitosan nanoparticles: a promising system for drug delivery. Naresuan Univ. J. Sci. Technol. 11(3), 51–66 (2013)
Lu, L., Chen, W.: Biocompatible composite actuator: a supramolecular structure consisting of the biopolymer chitosan, carbon nanotubes, and an ionic liquid. Adv. Mater. 22(33), 3745–3748 (2010). https://doi.org/10.1002/adma.201001134
He, Q., Yu, M., Yang, X., Kim, K.J., Dai, Z.: An ionic electro-active actuator made with graphene film electrode, chitosan and ionic liquid. Smart Mater. Struct. 24(6), 065026 (9 pp) (2015). https://doi.org/10.1088/0964-1726/24/6/065026
Cai, Z., Kim, J.: Characterization and electromechanical performance of cellulose-chitosan blend electro-active paper. Smart Mater. Struct. 17(3), 035028 (9 pp) (2008). https://doi.org/10.1088/0964-1726/17/3/035028
Shang, J., Shao, Z., Chen, X.: Chitosan-based electroactive hydrogel, Chitosan-based electroactive hydrogel. Polymer 49(25), 5520–5525 (2008). https://doi.org/10.1016/j.polymer.2008.09.067
Siqueira, J.R., Gasparotto, L.H., Crespilho, F.N., Carvalho, A.J., Zucolotto, V., Oliveira, O.N.: Physicochemical properties and sensing ability of metallophthalocyanines/chitosan nanocomposites. J. Phys. Chem. B 110(45), 22690–22694 (2006). https://doi.org/10.1021/jp0649089
Jang, S.-D., Kim, J.-H., Zhijiang, C., Kim, J.: The effect of chitosan concentration on the electrical property of chitosan-blended cellulose electroactive paper. Smart Mater. Struct. 18(1), 015003 (5 pp.) (2009). https://doi.org/10.1088/0964-1726/18/1/015003
Jeon, J.H., Cheedarala, R.K., Kee, C.D., Oh, I.K.: Dry-type artificial muscles based on pendent sulfonated chitosan and functionalized graphene oxide for greatly enhanced ionic interactions and mechanical stiffness. Adv. Funct. Mater. 23(48), 6007–6018 (2013). https://doi.org/10.1002/adfm.201203550
Kim, J., Yun, S.: Discovery of cellulose as a smart material. Macromolecules 39, 4202–4206 (2006). https://doi.org/10.1021/ma060261e
Sabo, R.C., Elhajjar, R.F., Clemons, C.M., Pillai, K.M.: Characterization and Processing of nanocellulose thermosetting composites. In: Pandey, J., Takagi, H., Nakagaito, A., Kim, H.J. (eds.) Handbook of Polymer Nanocomposites. Processing, Performance and Application, Volume C: Polymer Nanocomposites of Cellulose Nanoparticles, pp. 265–295. Springer, Berlin, Heidelberg (2015). https://doi.org/10.1007/978-3-642-45232-1_64
Farid, M., Zhao, G., Khuong, T.L., Sun, Z.Z., Ur, Rehman N., Rizwan, M.: Biomimetic applications of ionic polymer metal composites (IPMC) actuators-a critical review. J. Biomim. Biomater. Biomed. Eng. 20, 1–10 (2014). https://doi.org/10.4028/www.scientific.net/JBBBE.20.1
Gross, J.H.: Liquid injection field desorption/ionization-mass spectrometry of ionic liquids. J. Am. Soc. Mass Spectrom. 18(12), 2254–2262 (2007). https://doi.org/10.1016/j.jasms.2007.09.019
Jastorff, B., Störmann, R., Ranke, J., Mölter, K., Stock, F., Oberheitmann, B., Hoffmann, W., Hoffmann, J., Nüchter, M., Ondruschka, B., Filser, J.: How hazardous are ionic liquids? Structure-activity relationships and biological testing as important elements for sustainability evaluation. Green Chem. 5, 136–142 (2003). https://doi.org/10.1039/B211971d
Swatloski, R.P., Spear, S.K., Holbrey, J.D., Rogers, R.D.: Dissolution of cellose with ionic liquids. J. Am. Chem. Soc. 124, 4974–4975 (2002). https://doi.org/10.1039/B211971D
Kim, K.B., Kim, J.: Fabrication and characterization of electro-active cellulose films regenerated by using 1-butyl-3-methylimidazolium chloride ionic liquid. Proc. Inst. Mech. Eng. Part C J. Mech. Eng. 227, 2665–2670 (2013). https://doi.org/10.1177/0954406213478707
Edgar, K.J., Buchanan, C.M., Debenham, J.S., Rundquist, P.A., Seiler, B.D., Shelton, M.C., Tindall, D.: Advances in cellulose ester performance and application. Prog. Polym. Sci. 26(9), 1605–1688 (2001). https://doi.org/10.1016/S0079-6700(01)00027-2
Vidal, F., Plesse, C., Teyssié, D., Chevrot, C.: Long-life air working conducting semi-IPN/ionic liquid based actuator. Synth. Met. 142(1), 287–291 (2004). https://doi.org/10.1016/j.synthmet.2003.10.005
Vidal, F., Plesse, C., Randriamahazaka, H., Teyssie, D., Chevrot, C.: Long-life air working semi-IPN/ionic liquid: new precursor of artificial muscles. Mol. Cryst. Liq. Cryst. 448, 95/[697]–102/[704] (2006). https://doi.org/10.1080/15421400500377453
Ozdemir, O., Karakuzu, R., Sarikanat, M., Seki, Y., Akar, E., Cetin, L., Yilmaz, O.C., Sever, K., Sen, I., Gurses, B.O.: Improvement of the electrochemical performance of carboxymethylcellulose-based actuators by graphene nanoplatelet loading. Cellulose 22, 3251–3260 (2015). https://doi.org/10.1007/s10570-015-0702-3
Murphy, E.B., Wudl, F.: The world of smart healable materials. Prog. Polym. Si 35, 223–251 (2010). https://doi.org/10.1016/j.progpolymsci.2009.10.006
Qiu, X.Y., Hu, S.W.: “Smart” materials based on cellulose: a review of the preparations, properties, and applications. Materials 6, 738–781 (2013). https://doi.org/10.3390/Ma6030738
Sen, I., Seki, Y., Sarikanat, M., Cetin, L., Gurses, B.O., Ozdemir, O., Yilmaz, O.C., Sever, K., Akar, E., Mermer, O.: Electroactive behavior of graphene nanoplatelets loaded cellulose composite actuators. Compos. Part B 69, 369–377 (2015). https://doi.org/10.1016/j.compositesb.2014.10.016
Cao, Y., Wu, J., Zhang, J., Li, H.Q., Zhang, Y., He, J.S.: Room temperature ionic liquids (RTILs): a new and versatile platform for cellulose processing and derivatization. Chem. Eng. J. 147, 13–21 (2009). https://doi.org/10.1016/j.cej.2008.11.011
Zhu, S., Wu, Y., Chen, Q., Yu, Z., Wang, C., Jin, S., Ding, Y., Wu, G.: Dissolution of cellulose with ionic liquids and its application: a mini-review. Green Chem. 8, 325–327 (2006). https://doi.org/10.1039/B601395C
Zhang, H., Wu, J., Zhang, J., He, J.: 1-Alkyl-3-methylimidazolium chloride room temperature ionic liquid: a new and powerful nonderivatezing solvent for cellulose. Macromolecules 30(20), 8272–8277 (2005). https://doi.org/10.1021/ma0505676
Akar, E., Seki, Y., Ozdemir, O., Sen, I., Sarikanat, M., Gurses, B.O., Yilmaz, O.C., Cetin, L., Sever, K.: Electromechanical characterization of multilayer graphene-reinforced cellulose composite containing 1-ethyl-3-methylimidazolium diethylphosphonate ionic liquid. Sci. Eng. Compos. Mater. 24(2), 289–295 (2015). https://doi.org/10.1515/secm-2015-0038
Stankovich, S., Dikin, D.A., Domment, G.H.B., Kohlhaas, K.M., Zimmery, E.J., Stach, E.A., Piner, R.D., Nguyen, S.B.T., Ruoff, R.S.: Graphene-based composite materials. Nature 442, 282–286 (2006)
Eda, G., Chhowalla, M.: Graphene-based composite thin films for electronics. Nano Lett. 9(2), 814–818 (2009). https://doi.org/10.1021/nl8035367
Ozdemir, O., Karakuzu, R., Sarikanat, M., Akar, E., Seki, Y., Cetin, L., Sen, I., Gurses, B.O., Yilmaz, O.C., Sever, K., Mermer, O.: Effects of PEG loading on electromechanical behavior of cellulose-based electroactive composite. Cellulose 22, 1873–1881 (2015). https://doi.org/10.1007/s10570-015-0581-7
Song, W., Yang, L., Sun, Z., Li, F., Du, S.: Study on the actuation enhancement for ionic-induced IL-cellulose based biocompatible composite actuators by glycerol plasticization treatment method. Cellulose 25(5), 2885–2889 (2018). https://doi.org/10.1007/s10570-018-1783-6
Wang, F., Jeon, J.H., Park, S., Kee, C.D., Kim, S.J., Oh, I.K.: Soft biomolecule actuator based on highly functionalized bacterial cellulose nano-fiber network with carboxylic acid groups. Soft Matter 12, 246–254 (2012). https://doi.org/10.1039/C5SM00707K
Cheedarala, R.V., Jeon, J.H., Kee, C.D., Oh, I.K.: Bio‐inspired all‐organic soft actuator based on a π–π stacked 3D ionic network membrane and ultra‐fast solution processing. Adv. Funct. Mater. 24, 6005–6015 (2014). https://doi.org/10.1002/adfm.201401136
Greco, F., Zucca, A., Taccola, S., Menciassi, A., Fujie, T., Haniuda, H., Takeoka, S., Dario, P., Mattoli, V.: Ultra-thin conductive free-standing PEDOT/PSS nanofilms. Soft Matter 7, 10642–10650 (2011). https://doi.org/10.1039/C1SM06174G
Greco, F., Domenici, V., Desii, A., Sinibaldi, E., Zalar, B., Mazzolai, B., Mattoli, V.: Liquid single crystal elastomer/conducting polymer bilayer composite actuator: modelling and experiments. Soft Matter 9, 11405–11416 (2013). https://doi.org/10.1039/C3SM51153G
Okuzali, H., Tagaki, S., Hishiki, F., Tanigawa, R.: Ionic liquid/polyurethane/PEDOT:PSS composites for electro-active polymer actuators. Sens. Actuators B 194, 59–63 (2014). https://doi.org/10.1016/j.snb.2013.12.059
Haldorai, Y., Shim, J.J.: Chemo-responsive bilayer actuator film: fabrication, characterization and actuator response. New J. Chem. 38, 2653–2659 (2014). https://doi.org/10.1039/c4nj00014e
Seiffert, S., Oppermann, W., Saalwachter, K.: Hydrogel formation by photocrosslinking of dimethylmaleimide functionalized polyacrylamide polymer 48, 5599–5611 (2007). https://doi.org/10.1016/j.polymer.2007.07.013
Kim, J., Wang, N., Chen, Y., Lee, S.K., Yun, G.Y.: Electroactive-paper actuator made with cellulose/NaOH/urea and sodium alginate. Cellulose 14, 217–223 (2007). https://doi.org/10.1007/s10570-007-9111-6
Kim, J., Yun, S., Mahadeva, S.K., Yun, K., Yang, S.Y., Maniruzzaman, M.: Paper actuators made with cellulose and hybrid materials. Sensors 10, 1473–1485 (2010). https://doi.org/10.3390/s100301473
Mahadeva, S.K., Yi, C., Kim, J.: Effect of room temperature ionic liquids adsorption on electromechanical behaviour of cellulose electro-active paper. Macromol. Res. 17(2), 116–120 (2009)
Wang, N., Chen, Y., Kim, J.: Electroactive paper actuator made with chitosan-cellulose films: effect of acetic acid. Macromol. Mater. Eng. 292, 748–753 (2007)
Kim, J., Wang, N., Chen, Y.: Effect of chitosan and ions on actuation behaviour of cellulose-chitosan laminated films as electro-active paper actuators. Cellulose 14, 439–445 (2007)
Kim, J., Seo, Y.B.: Electro-active paper actuators. Smart Mater. Struct. 11, 355–360 (2002)
Sun, Z., Zhao, G., Song, W.: A naturally crosslinked chitosan based ionic actuator with cathode deflection phenomenon. Cellulose 24(2), 441–445 (2016). https://doi.org/10.1007/s10570-016-1161-1
Dos Santos, D.S., Riul, A., Malmegrum, R.R.: A layer-by-layer film of chitosan in a taste sensor application. Macromol. Biosci. 3(10), 591–595 (2003)
Zolfagharian, A., Kouzani, A.Z., Khoo, S.Y., Nasri-Nasrabadi, B., Kaynak, A.: Development and analysis of a 3D printed hydrogel soft actuator. Sens. Actuators A 265, 94–101 (2017). https://doi.org/10.1016/j.sna.2017.08.038
Shahinpoor, M.: Chitosan/IPMC artificial muscle. Adv. Sci. Technol. 79, 32–40 (2013)
Muralidharan, M.N., Shinu, K.P., Seema, A.: Optically triggered actuation in chitosan/reduced graphene oxide nanocomposites. Carbohydr. Polym. 144, 115–121 (2016). https://doi.org/10.1016/j.carbpol.2016.02.047
Lu, L.H., Chen, W.: Large-scale aligned carbon nanotubes from their purified highly concentrated suspension. ACS Nano 4(2), 1042–1048 (2010). https://doi.org/10.1021/nn901326m
Harrison, B.S., Atala, A.: Carbon nanotube applications for tissue engineering. Biomaterials 28(2), 344–353 (2007). https://doi.org/10.1016/j.biomaterials.2006.07.044
Li, J., Ma, W., Song, L., Niu, Z., Cai, L., Zeng, Q., Zhang, X., Dong, H., Zhao, D., Zhoud, W., Xie, S.: Superfast-response and ultrahigh-power-density electromechanical actuators based on hierarchal carbon nanotube electrodes and chitosan. Nano Lett. 11, 4636–4641 (2011). https://doi.org/10.1021/n120132m
Zhao, G., Yang, J., Wang, Y., Zhao, H., Wang, Z.: Preparation and electromechanical properties of the chitosan gel polymer actuator based on heat treating. Sens. Actuators 279, 481–492 (2018). https://doi.org/10.1016/j.sna.2018.06.036
Zhao, G., Sun, Z., Wang, J., Xu, Y., Li, L., Ge, Y.: Electrochemical properties of a highly biocompatible chitosan polymer actuator based on a different nanocarbon/ionic liquid electrode. Polym. Compos. (2015). https://doi.org/10.1002/pc.23822
Sun, Z., Zhao, G., Song, W.L., Wang, J., Haq, M.U.: Investigation into electromechanical properties of biocompatible chitosan-based ionic actuator. Exp. Mech. 58(1), 99–109 (2017)
Di Martino, A., Sittinger, M., Risbud, M.V.: Chitosan: a versatile biopolymer for orthopedic tissue-engineering. Biomaterials 26(3), 5983–5990 (2005)
Neto, G.T., Dantas, T.N.C., Fonseca, J.L.C.: Permeability studies in chitosan membranes. Effects of crosslinking and poly (ethylene oxide) addition. Carbohyd. Res. 340(17), 2630–2636 (2005)
Altinkaya, E., Seki, Y., Yilmaz, O.C., Cetin, L., Ozdemir, O., Sen, I., Sever, K., Gurses, B.O., Sarikanat, M.: Electromechanical performance of chitosan-based composite electroactive actuators. Compos. Sci. Technol. 129, 108–115 (2016). https://doi.org/10.1016/j.compscitech.2016.04.019
Yeng, C.M., Husseinsyah, S., Ting, S.S.: Effect of cross-linked agent on tensile properties of chitosan/corn cob biocomposite films. Polym. Plast Technol. 54(3), 270–275
Altinkaya, E., Seki, Y., Cetin, L., Gurses, B.O., Ozdemir, O., Sever, K., Sarikanat, M.: Characterization and analysis of motion mechanism of electroactive chitosan-based actuator. Carbohyd. Polym. 181, 404–411 (2018). https://doi.org/10.1016/j.carbpol.2017.08.113
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Popa, A., Filimon, A., Lupa, L. (2019). Polysaccharide-Based Ionic Polymer Metal Composite Actuators. In: Inamuddin, Asiri, A. (eds) Ionic Polymer Metal Composites for Sensors and Actuators. Engineering Materials. Springer, Cham. https://doi.org/10.1007/978-3-030-13728-1_2
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