Abstract
Advanced oxidation process such as photocatalysis is seen as a potential future technology to offer clean water for various human needs. Through this process, different organic pollutants and recalcitrant chemicals are effectively removed from both water and wastewater. Some of the AOPs, such as ozonation (O3), catalysis by iron ions, electrodes, metal oxides, UV/Fenton, UV/hydrogen peroxide (H2O2), etc., generate harmful intermediates which restrict their full-scale implementation. Alternatively, irradiation techniques such as photocatalysis are a viable option and have shown to treat wastewater contaminated with hazardous chemicals, organic dyes, pesticides, antibiotics, viruses, bacteria, protozoa, etc., without producing toxic levels of by-products. This chapter reviews emerging aspects of photocatalysis for treatment of various recalcitrant pollutants with a special emphasis on polyethylene degradation. It summarizes the source, types, mechanism, and parameters of wastewater treatment using photocatalytic activity. Polyethylene is well known as serious cause of threats to human health and environment. Polyethylene, polystyrene, plastic film, and polypropylene degradation has been shown to occur via photocatalysis. This could be achieved using TiO2, ZnO, and doped and undoped metal oxides as photocatalysts. Also, photocatalytic degradation is compared with microbial techniques for polyethylene degradation along with brief reports on novel photobioreactors; a combination of microbial and photocatalytic reactors in degradation of polyethylene.
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Arumugam, K., Meenkashisundaram, S., Sharma, N.K. (2020). Photocatalysis for Wastewater Treatment with Special Emphasis on Plastic Degradation. In: Kharissova, O.V., Martínez, L.M.T., Kharisov, B.I. (eds) Handbook of Nanomaterials and Nanocomposites for Energy and Environmental Applications. Springer, Cham. https://doi.org/10.1007/978-3-030-11155-7_41-1
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