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Light-Induced Processes in Porphyrin-Fullerene Systems

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Progress in Photon Science

Part of the book series: Springer Series in Chemical Physics ((CHEMICAL,volume 119))

Abstract

Porphyrin-fullerene dyads are representative class of donor-acceptor molecular systems capable of undergoing photoinduced charge separation, the phenomenon that is the key process in solar energy conversion systems either in organic solar cells or photoredox catalysis. The charge-separated state generated in covalently linked dyad is a highly polarized electronically excited state. Formation of this state typically proceeds as a result of the relaxation of a locally excited state of higher energy, which is populated upon the initial excitation of the dyad. The review of computational and spectroscopic studies of the excited states in porphyrin-fullerene covalently linked dyads is given in the present chapter.

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Acknowledgements

The STEPS program funded by JSPS Inter-University Exchange Program and St. Petersburg State University—JTI joint program (Grant No. 12.54.1266.2016) are gratefully acknowledged.

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Authors and Affiliations

  1. Institute of Chemistry, St. Petersburg State University, Universitetskii pr. 26 Peterhof, St. Petersburg, 198504, Russian Federation

    Alexander S. Konev

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  1. Alexander S. Konev
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Correspondence to Alexander S. Konev .

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Editors and Affiliations

  1. Department of Chemistry, The University of Tokyo, Tokyo, Japan

    Kaoru Yamanouchi

  2. Institute of Chemistry, Saint Petersburg State University, Saint Petersburg, Russia

    Sergey Tunik

  3. Physics Faculty, Lomonosov Moscow State University, Moscow, Russia

    Vladimir Makarov

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Konev, A.S. (2019). Light-Induced Processes in Porphyrin-Fullerene Systems. In: Yamanouchi, K., Tunik, S., Makarov, V. (eds) Progress in Photon Science. Springer Series in Chemical Physics, vol 119. Springer, Cham. https://doi.org/10.1007/978-3-030-05974-3_22

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