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Electrochemical Synthesis of Metal Oxides for Energy Applications

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Electrodeposition and Surface Finishing

Part of the book series: Modern Aspects of Electrochemistry ((MAOE,volume 57))

Abstract

The development of a sustainable global energy policy requires the availability of efficient, reliable and inexpensive energy conversion and storage technologies using renewable, carbon free energy sources. The ability to synthesize functional materials that are both cost effective and highly efficient is a critical step towards this goal. In particular, the electrodeposition of metal oxides is an attractive option for the production of materials for energy applications due to its low cost, high scalability, and versatility. This chapter reviews the fundamentals of the electrochemical formation and growth of oxide materials and describes possible methods to control their composition, morphology, and crystal structure towards performance optimization. Examples of metal oxides systems and specifically how the synthesis process influences their performance will be discussed. The materials examined include ZnO for solar cells, Cu2O for photovoltaic and photoelectrochemical systems, α-Fe2O3 for photoelectrochemical water splitting, and MnO2 for supercapacitor energy storage. Techniques to enhance device performance common to these materials system include varying electrochemical deposition parameters to fine tune morphology, nanostructuring to better control and enhance relevant device properties, and the integration of materials with complementary functions to systematically maximize efficiency through a system approach.

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Authors and Affiliations

  1. Department of Materials Science and Engineering, University of Virginia, Charlottesville, VA, 22904, USA

    Lok-kun Tsui & Giovanni Zangari

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  1. Lok-kun Tsui
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  2. Giovanni Zangari
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Correspondence to Giovanni Zangari .

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  1. Elchem Consulting Ltd., Edmonton, Alberta, Canada

    Stojan S. Djokić

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Tsui, Lk., Zangari, G. (2014). Electrochemical Synthesis of Metal Oxides for Energy Applications. In: Djokić, S. (eds) Electrodeposition and Surface Finishing. Modern Aspects of Electrochemistry, vol 57. Springer, New York, NY. https://doi.org/10.1007/978-1-4939-0289-7_4

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