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Lithium-Ion Battery Systems and Technology

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Encyclopedia of Sustainability Science and Technology

Definition of the Subject

Lithium-ion battery (LIB) is one of rechargeable battery types in which lithium ions move from the negative electrode (anode) to the positive electrode (cathode) during discharge, and back when charging. It is the most popular choice for consumer electronics applications mainly due to high-energy density, longer cycle and shelf life, and no memory effect. With Li-ion batteries currently gaining much attraction in electric drive vehicle, the concern for global warming and a clean environment may be well served with advances in such systems.

Introduction

During the last 15 years, lithium-ion batteries have dominated the advanced energy sources by powering the modern portable electronics and replaced many other commercial battery systems in the market. The prime reasons for its rapid success and proliferation in consumer electronic market are its superior characteristics over other battery systems, namely, high voltage, high-energy...

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Abbreviations

Active material:

The material in the electrodes of a cell or battery that takes part in the electrochemical reactions of charge or discharge.

Battery/battery pack:

An assembly of any number of Li-ion cells, associated electronics, battery packaging, and connector(s).

Capacity:

The total number of Ampere-hours (Ah) that can be withdrawn from a fully charged cell or battery under specified conditions of discharge.

Cell:

Basic lithium ion unit providing a source of electrical energy by direct conversion of chemical energy that consists of electrodes, separator, electrolyte, container, and terminals, and that is designed to be charged electrically.

Current collector:

An inert member of high electrical conductivity used to conduct current from or to an electrode during discharge or charge.

Cycle:

The discharge and subsequent or preceding charge of a Li-ion cell or battery such that it is restored to its original conditions.

Cycle life:

The number of cycles under specified conditions which are available from a Li-ion cell or battery before it fails to meet specified criteria as to performance.

Electrolyte:

The medium which provides the ion transport mechanism between the positive and negative electrodes of a cell.

Negative electrode:

The electrode acting as an anode when a cell or battery is discharging.

Overcharge:

The forcing of a current through a Li-ion cell or battery pack after it has been fully charged.

Positive electrode:

The electrode acting as a cathode when a cell or battery is discharging.

Separator:

An ionically conductive, electronically insulative material which prevents electronic contact between electrodes of opposite polarity in the same cell.

Thermal runaway:

The cell condition where the internal cell reactions generate more thermal heat than the cell can dissipate. The condition causes cell venting and premature failure.

Bibliography

  1. Whittingham MS (1976) Electrical energy storage and intercalation chemistry. Science 192(4244):1126

    Article  CAS  Google Scholar 

  2. Goodenough JB (1980) U.S. Patent 4,302,518 (Issued 31 Mar 1980)

    Google Scholar 

  3. Ikeda H, Narukawa K, Nakashim H (1981) Japanese Patent 1769661 (Issued 18 June 1981)

    Google Scholar 

  4. Basu S (1982) U.S. Patent 4,423,125 (Issued 13 Sept 1982)

    Google Scholar 

  5. Yoshino A, Jitsuchika K, Nakashima T (1985) Japanese Patent 1989293 (Issued 10 May 1985)

    Google Scholar 

  6. Gozdz AS, Schmutz CN, Tarascon JM (1994) U.S. Patent 5,296,318 (Issued 22 Mar 1994)

    Google Scholar 

  7. Gozdz AS, Schmutz CN, Tarascon JM, Warren PC (1995) U.S. Patent 5,418,091 (Issued 23 May 1995)

    Google Scholar 

  8. Gozdz AS, Schmutz CN, Tarascon JM, Warren PC (1995) U.S. Patent 5,456,000 (Issued 10 Oct 1995)

    Google Scholar 

  9. Gozdz AS, Tarascon JM, Warren PC (1995) U.S. Patent 5,460,904 (Issued 24 Oct 1995)

    Google Scholar 

  10. Global Industrial Analysts Report. http://www.prweb.com/releases/2011/1/prweb8040051.htm. Accessed Feb 2011

  11. Institute of Information Technology, Ltd. (IIT) report, Year 2010, Q4, Chapter 7

    Google Scholar 

  12. Brodd RJ (2009) In: Yoshio M, Brodd RJ, Kozawa A (eds) Li-ion batteries: science and technologies. Springer, New York, pp 1–7

    Chapter  Google Scholar 

  13. Takeshita H (2006) 23 rd international seminar on primary and secondary batteries, Ft. Lauderdale, Mar 2006

    Google Scholar 

  14. Peled E (1979) The electrochemical behavior of alkali and alkaline earth metals in nonaqueous battery systems—the solid electrolyte interphase model. J Electrochem Soc 126:2047

    Google Scholar 

  15. Peled E (1999) In: Besenhard JO (ed) Handbook of battery materials. Wiley-VCH, Weinheim, pp 419–458

    Google Scholar 

  16. Whittingham MS (2004) Lithium batteries and cathode materials. Chem Rev 104:4271–4301

    Google Scholar 

  17. Zhang ZJ (2011) Li-ion application in EDV and its safety perspectives, Pacific power sources symposium 2011, Hawaii

    Google Scholar 

  18. Zhengming (John) Z, Ramadass P (2009) In: Yoshio M, Brodd RJ, Kozawa A (eds) Li-ion batteries: science and technologies. Springer, New York, pp 367–412

    Google Scholar 

  19. Tagawa K, Brodd RJ (2009) In: Yoshio M, Brodd RJ, Kozawa A (eds) Li-ion batteries: science and technologies. Springer, New York, pp 181–193

    Google Scholar 

  20. Kim J, Hong JJ, Koh S (2006) Proceedings of the 42nd power sources conference, Philadelphia, June 2006

    Google Scholar 

  21. Tullo A (2006) Dell recalls lithium batteries. In: Chemical and engineering news: American Chemical Society, 21 Aug 2006

    Google Scholar 

  22. Hales P (2006) Dell laptop explodes at Japanese conference. In: The inquirer, June 2006 Staff (27 July 2007). Nokia – Retrieved 15 June 2010

    Google Scholar 

  23. N91 cell phone explodes Mukamo. In: Filipino news (blog), July 2007

    Google Scholar 

  24. IEEE 1625 (2008) IEEE standard for rechargeable batteries for multi-cell mobile computing devices

    Google Scholar 

  25. IEEE 1725 (2011) IEEE standard for rechargeable batteries for cellular telephones

    Google Scholar 

  26. UL 1642 (1995) UL standard for safety for lithium batteries, 3rd edn., Dated April 26, 1995

    Google Scholar 

  27. Jacoby M (2007) Burning batteries. Chem Eng News 85:26–28

    Article  Google Scholar 

  28. Santhanagopalan S, Ramadass P, Zhang Z (2009) Analysis of internal short-circuit in a lithium ion cell. J Power Sources 194:550–557

    Google Scholar 

  29. Nishi H (1998) Lithium ion batteries. In: Wakihara M, Yamamoto O (eds) Fundamentals and performances. Codensha/Wiley, New York, pp 181–198

    Google Scholar 

  30. Dahn JR (1991) The phase diagram of LixC6. Phys Rev B 44:9170

    Google Scholar 

  31. Tatsumi K, Zaghib K, Sawada Y, Abe H, Ohsaki T (1995) Anode performance of vapor-grown carbon fibers in secondary lithium-ion batteries. J Electrochem Soc 142:1090

    Google Scholar 

  32. Aurbach D, Levi M, Levi E (1997) The mechanism of lithium intercalation in graphite film electrodes in aprotic media. Part 1. High resolution slow scan rate cyclic voltammetric studies and modeling. J Electroanal Chem 421:79

    Google Scholar 

  33. Aurbach D, Ein-Eli E (1995) The study of Li-Graphite intercalation processes in several electrolyte systems using In Situ X-ray diffraction. J Electrochem Soc 142:1746

    Google Scholar 

  34. Ohzuku T, Iwakoshi Y, Sawai K (1993) Formation of Lithium-Graphite intercalation compounds in nonaqueous electrolytes and their application as a negative electrode for a lithium ion (Shuttlecock) cell. J Electrochem Soc 140:2490

    Google Scholar 

  35. Inaba M, Yoshida H, Ogumi Z, Abe T, Mizutani Y, Asano M (1995) In Situ raman study on electrochemical Li intercalation into graphite. J Electrochem Soc 142:20

    Google Scholar 

  36. Funabiki A, Inaba M, Abe T, Ogumi Z (1999) Nucleation and phase-boundary movement upon stage transformation in lithium–graphite intercalation compounds. Electrochim Acta 45:865

    Google Scholar 

  37. Xu K, Zhang S, Poese BA, Jow TR (2002) Lithium bis(oxalato)borate stabilizes graphite anode in propylene carbonate. Electrochem Solid-State Lett 5:A259

    Google Scholar 

  38. Kinoshita K (1998) Carbo: electrochemical and physico-chemical properties. Wiley, New York, p 70

    Google Scholar 

  39. Wang H, Ikeda T, Fukuda K, Yoshio M (1999) Effect of milling on the electrochemical performance of natural graphite as an anode material for lithium-ion battery. J Power Sources 83:141

    Google Scholar 

  40. Yoshio M, Wang H, Fukuda K, Hara Y, Adachi Y (2000) Effect of carbon coating on electrochemical performance of treated natural graphite as lithium-ion battery anode material. J Electrochem Soc 147:1245

    Google Scholar 

  41. Wang H, Yoshio M (2001) Carbon-coated natural graphite prepared by thermal vapor decomposition process, a candidate anode material for lithium-ion battery. J Power Sources 93:123–129

    Google Scholar 

  42. Wang H, Yoshio M, Abe T, Ogumi Z (2002) Characterization of carbon-coated natural graphite as a lithium-ion battery anode material. J Electrochem Soc 149:A499

    Google Scholar 

  43. Nishida T (2009) In: Yoshio M, Brodd RJ, Kozawa A (eds) Li-ion batteries: science and technologies. Springer, New York, pp 329–341

    Google Scholar 

  44. Wakihara M, Yamamoto O (1998) Lithium batteries-fundamentals and performance. Wiley-VCH, Germany

    Book  Google Scholar 

  45. Besenhard JO, Yang J, Winter M (1997) Will advanced lithium-alloy anodes have a chance in lithium-ion batteries?. J Power Sources 68:87

    Google Scholar 

  46. Ozhuku T, Tomura H, Sawai K (1997) Monitoring of particle fracture by acoustic emission during charge and discharge of Li/MnO2 cells. J Electrochem Soc 144:3496

    Google Scholar 

  47. Ozhuku T, Matoba N, Sawai K (2001) Direct evidence on anomalous expansion of graphite-negative electrodes on first charge by dilatometry. J Power Sources 97–98:73

    Google Scholar 

  48. Yoshio M, Wang H, Fukuda K, Umeno T (2002) Carbon-coated Si as a lithium-ion battery anode material. J Electrochem Soc 149:A1598

    Google Scholar 

  49. Neudecker BJ, Zuhr RA, Bates JB (1999) Lithium silicon tin oxynitride (LiySiTON): high-performance anode in thin-film lithium-ion batteries for microelectronics. J Power Sources 81:27

    Google Scholar 

  50. Bordearu S, Brousse T, Schleich DM (1999) Amorphous silicon as a possible anode material for Li-ion batteries. J Power Sources 81:233

    Google Scholar 

  51. Green M, Fielder E, Scrosati B, Watchler M, Moreno JS (2003) Structured silicon anodes for lithium battery applications. Electrochem Solid State Lett 6:A75

    Google Scholar 

  52. Takamura T, Ohara S, Suzuki J, Sekine K (2002) The 11th international meeting on Lithium batteries, Monterey, 23–28 June 2002, Abs#257

    Google Scholar 

  53. Zaghib K, Kinoshita K (2004) 12th international meeting on Lithium batteries, Nara, 27 June–2 July 2004, Abs#7

    Google Scholar 

  54. Yonezu I, Tarui H, Yoshimura S, Fujitani S, Nohma T (2004) 12th international meeting on Lithium batteries, Nara, 27 June–2 July 2004, Abs#58

    Google Scholar 

  55. Yoshio M, Wang H, Fukuda K, Umeno T, Dimov N, Ogumi Z (2002) Carbon-coated Si as a lithium-ion battery anode material. J Electrochem Soc 149:A1598

    Google Scholar 

  56. Dimov N, Fukuda K, Umeno T, Kugino S, Yoshio M (2003) Characterization of carbon-coated silicon: structural evolution and possible limitations. J Power Sources 114:88

    Google Scholar 

  57. Liu Y, Hanai K, Yang J, Imanishi N, Hirano A, Takeda Y (2004) Morphology-stable silicon-based composite for Li-intercalation. Solid State Ionics 168:61

    Google Scholar 

  58. Mitzushima K, Jones PC, Wiseman PJ, Goodenough JB (1980) LixCoO2 (0<x<−1): a new cathode material for batteries of high energy density. Mater Res Bull 15:783

    Google Scholar 

  59. Tarascon JM, McKinnon WR, Coowar F, Bowmer TN, Amatucci G, Guyomard D (1994) Synthesis conditions and oxygen stoichiometry effects on Li insertion into the spinel LiMn2O4. J Electrochem Soc 141:1421

    Google Scholar 

  60. Thackeray MM, David WIF, Bruce PG, Goodenough JB (1983) Lithium insertion into manganese spinels. Mater Res Bull 18:461

    Google Scholar 

  61. Padhi AK, Nanjundaswamy KS, Goodenough JB (1997) Phospho-olivines as positive-electrode materials for rechargeable lithium batteries. J Electrochem Soc 144:1188

    Google Scholar 

  62. Mukerjee S, Yang XQ, Sun X, Lee SJ, McBreen J, Ein-Eli Y (2004) In situ synchrotron X-ray studies on copper–nickel 5 V Mn oxide spinel cathodes for Li-ion batteries. Electrochim Acta 49:3373

    Google Scholar 

  63. Yamada A, Chung S-C (2001) Crystal chemistry of the olivine-type Li(Mn y Fe1−y )PO4 and (Mn y Fe1−y )PO4 as possible 4 V cathode materials for lithium batteries. J Electrochem Soc 148:A960

    Google Scholar 

  64. Li G, Azuma H, Tohda M (2002) LiMnPO4 as the cathode for lithium batteries. Electrochem Solid State Lett 5:A135

    Google Scholar 

  65. Nakai I, Nakagome T (1998) In Situ transmission X-ray absorption fine structure analysis of the Li deintercalation process in Li(Ni0.5Co0.5)O2. Electrochem Solid State Lett 1:259

    Google Scholar 

  66. Yoshio M et al (2009) In: Yoshio M, Brodd RJ, Kozawa A (eds) Li-ion batteries: science and technologies. Springer, New York, pp 9–48

    Chapter  Google Scholar 

  67. Ohzuku T, Ariyoshi K, Yamamoto S, Makimura Y (2001) A 3-volt lithium-ion cell with Li[NiMn3/2]O4 and Li[Li1/3Ti5/3]O4: a method to prepare stable positive-electrode material of highly crystallized Li[Ni1/2Mn3/2]O4. Chem Lett 30:1270

    Article  Google Scholar 

  68. Ohzuku T, Makimura Y (2001) Layered lithium insertion material of LiCo1/3Ni1/3Mn1/3O2 for lithium-ion batteries. Chem Lett 30:642

    Google Scholar 

  69. Yabuuchi N, Ohzuku T (2003) Novel lithium insertion material of LiCo1/3Ni1/3Mn1/3O2 for advanced lithium-ion batteries. J Power Sources 119–121:171

    Google Scholar 

  70. Park SH, Yoon CS, Kang SG, Kim H-S, Moon S-I, Sun Y-K (2004) Synthesis and structural characterization of layered Li[Ni1/3Co1/3Mn1/3]O2 cathode materials by ultrasonic spray pyrolysis method. Electrochim Acta 49:557

    Google Scholar 

  71. Ohzuku T, Ariyoshi K, Yamamoto S, Makimura Y (2001) A 3-volt lithium-ion cell with Li[Ni1/2Mn3/2]O4 and Li[Li1/3Ti5/3]O4: a method to prepare stable positive-electrode material of highly crystallized Li[Ni1/2Mn3/2]O4. Chem Lett 30:1270

    Google Scholar 

  72. Sun YK et al (2005) Synthesis and characterization of Li[(Ni0.8Co0.1Mn0.1)0.8(Ni0.5Mn0.5)0.2]O2 with the microscale core−shell structure as the positive electrode material for lithium batteries. J Am Chem Soc 127:13411

    Google Scholar 

  73. Sun YK et al (2006) Novel core−shell-structured Li[(Ni0.8Co0.2)0.8(Ni0.5Mn0.5)0.2]O2 via coprecipitation as positive electrode material for lithium secondary batteries. J Phys Chem B 110:6810

    Google Scholar 

  74. Sun YK et al (2009) High-energy cathode material for long-life and safe lithium batteries. Nat Mater 8:320

    Google Scholar 

  75. Thackeray M (2009) US DOE-VT Annual merit review, Proj ID ES020

    Google Scholar 

  76. Amine K (2010) US DOE merit review, Proj. ID ES015

    Google Scholar 

  77. Ho-Jin Kweon, Jun-Won Suh, Won II Jung (2004) U.S. Patent 6, 753, 111 (Issued 22 June 2004)

    Google Scholar 

  78. Cho J et al (2001) High-performance ZrO2-coated LiNiO2 cathode material. Electrochem Solid State Lett 4(10):A159

    Google Scholar 

  79. Cho J et al (2000) Novel LiCoO2 cathode material with Al2O3 coating for a Li ion cell. Chem Mater 12(12):3788

    Google Scholar 

  80. Fujimoto M, Takahashi M, Nishio A (1992) Japan patent 3059832 (Issued 27 July 1992)

    Google Scholar 

  81. Simon A, Boeuve J-P (1997) U.S. patent 5,626,981 (Issued 6 May 1997)

    Google Scholar 

  82. Wrodnigg GH, Besenhard JO, Winter M (1999) Ethylene sulfite as electrolyte additive for lithium-ion cells with graphitic anodes. J Electrochem Soc 146:470

    Google Scholar 

  83. Wrodnigg GH, Wrodnigg TM, Besenhard JO, Winter M (1999) Propylene sulfite as film-forming electrolyte additive in lithium ion batteries. Electrochem Commun 1:148

    Google Scholar 

  84. Wrodnigg GH, Besenhard JO, Winter M (2001) Cyclic and acyclic sulfites: new solvents and electrolyte additives for lithium ion batteries with graphitic anodes?. J Power Sources 97–98:592

    Google Scholar 

  85. Kusachi Y, Utsugi K (2003) Extended abstracts of the 44th battery symposium in Japan ,Sakai, p 526 4–6 Nov (2003)

    Google Scholar 

  86. Xiao L, Ai X, Cao Y, Yang H (2004) Electrochemical behavior of biphenyl as polymerizable additive for overcharge protection of lithium ion batteries. Electrochim Acta 49:4189

    Google Scholar 

  87. Kim H-J, Yoo S-I, Cho J-J (2002) Extended abstracts of the 43 rd battery symposium in Japan, Fukuoka, 12–14 Oct 2002, p 78

    Google Scholar 

  88. Tobishima S, Ogino Y, Watanabe Y (2002) Effect of electrolyte additives to provide safety and discharge characteristics of lithium batteries. Electrochemistry 70:875

    Google Scholar 

  89. Adachi M, Tanaka K, Sekai K (1999) Aromatic compounds as redox shuttle additives for 4 V class secondary lithium batteries. J Electrochem Soc 146:1256

    Google Scholar 

  90. Lee D-Y, Lee H-S, Kim H-S, Sun H-Y, Seung D-Y (2002) Redox shuttle additives for chemical overcharge protection in lithium ion batteries. Korean J Chem Eng 19:645

    Google Scholar 

  91. Blomgren GE (1999) Electrolytes for advanced batteries. J Power Sources 81–82:112

    Google Scholar 

  92. Suzuki H, Shima N, Hasegawa K, Yoshida Y (1996) JP1996–306387A; JP3893627B

    Google Scholar 

  93. Noda D, Kotato M, Fuji T, Suzuki H (2002) JP2002–319433A

    Google Scholar 

  94. Lee CW, Venkatachalapathy R, Prakash J (2000) A novel flame-retardant additive for lithium batteries. Electrochem Solid-State Lett 3:63

    Google Scholar 

  95. Zhang S, Xu K, Jow TR (2003) Tris(2,2,2-trifluoroethyl) phosphite as a co-solvent for nonflammable electrolytes in Li-ion batteries. J Power Sources 113:166

    Google Scholar 

  96. Gozales SI, Li W, Lucht BL (2004) Hexamethylphosphoramide as a flame retarding additive for lithium-ion battery electrolytes. J Power Sources 135:291

    Google Scholar 

  97. Okuno H et al (1996) U.S. patent 5,525, 443 (Issued 11 June 1996)

    Google Scholar 

  98. Yamaguchi et al (2009) U.S. patent 7,491, 471 B2, 17 Feb 2009

    Google Scholar 

  99. Abe K et al (2011) U.S. patent application 20110045361 (Pub. Date 24 Feb 2011)

    Google Scholar 

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Zhang, Z.(., Ramadass, P. (2012). Lithium-Ion Battery Systems and Technology . In: Meyers, R.A. (eds) Encyclopedia of Sustainability Science and Technology. Springer, New York, NY. https://doi.org/10.1007/978-1-4419-0851-3_663

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