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Structure and Bonding in Molecular Vanadium Oxides: From Templates via Host–Guest Chemistry to Applications

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Polyoxometalate-Based Assemblies and Functional Materials

Part of the book series: Structure and Bonding ((STRUCTURE,volume 176))

Abstract

Molecular vanadium oxides are a structurally and chemically versatile sub-class of polyoxometalates. Fundamental concepts of their formation, templating mechanism and aggregation under aqueous and non-aqueous conditions are presented. Details about different template classes and their consequences on the vanadate reactivity are discussed together with concepts of linking vanadates into supramolecular architectures using various linkages. The final section briefly describes major applications of vanadium oxide clusters in (photo)catalysis, magnetism and molecular nanostructure design.

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Authors and Affiliations

  1. Institute of Inorganic Chemistry I, Ulm University, Albert-Einstein-Allee 11, Ulm, 89081, Germany

    Carsten Streb

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  1. Carsten Streb
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Correspondence to Carsten Streb .

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  1. Beijing University of Chemical Technology, Beijing, China

    Yu-Fei Song

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Streb, C. (2017). Structure and Bonding in Molecular Vanadium Oxides: From Templates via Host–Guest Chemistry to Applications. In: Song, YF. (eds) Polyoxometalate-Based Assemblies and Functional Materials. Structure and Bonding, vol 176. Springer, Cham. https://doi.org/10.1007/430_2017_2

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