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Asymmetric Hydroformylation Using Rhodium

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Rhodium Catalysis

Part of the book series: Topics in Organometallic Chemistry ((TOPORGAN,volume 61))

Abstract

Asymmetric hydroformylation is a powerful catalytic reaction that produces chiral aldehydes from inexpensive feedstock (alkenes, syngas) in a single step. The elucidation of the different steps of the catalytic cycle and the characterization of the resting state, together with the discovery of several types of ligands, have made possible that nowadays a variety of chiral products incorporating a formyl unit can be enantioselectively prepared by Rh-catalyzed asymmetric hydroformylation, and that this process is now considered as a useful tool in organic synthesis.

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Authors and Affiliations

  1. Department of Physical Chemistry and Inorganic Chemistry, Universitat Rovira i Virgili, Campus Sescelades, C/ Marcel.li Domingo s/n, 43007, Tarragona, Spain

    Anton Cunillera, Cyril Godard & Aurora Ruiz

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  1. Anton Cunillera
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  2. Cyril Godard
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  3. Aurora Ruiz
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Correspondence to Cyril Godard .

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  1. Facultat de Química, Universitat Rovira i Virgili, Tarragona, Spain

    Carmen Claver

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Cunillera, A., Godard, C., Ruiz, A. (2017). Asymmetric Hydroformylation Using Rhodium. In: Claver, C. (eds) Rhodium Catalysis. Topics in Organometallic Chemistry, vol 61. Springer, Cham. https://doi.org/10.1007/3418_2017_176

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