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Rhodium-Catalyzed C–B Bond Formation

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Rhodium Catalysis

Part of the book series: Topics in Organometallic Chemistry ((TOPORGAN,volume 61))

Abstract

This chapter focuses on Rh-activation of boron-based reagents and its assistance in efficient catalytic borylation reactions. The introduction is a critical reflection of the importance that hydroborane reagents have had in reactions such as Rh-catalyzed hydroboration for the last 30 years. The next section shows a brief history of the Rh–B bond formation from Rh complexes and diboron reagents. The most relevant advances in Rh-catalyzed diboration are summarized in the following section. In the fourth section, examples of Rh-catalyzed β-boration of α,β-unsaturated substrates are collected, completing the fifth section with a description and comments about the new trends on Rh-catalyzed C–H and C–X borylation. At the end of this chapter, the authors compile a summary and their perspective for the related field from a mechanistic point of view.

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Acknowledgement

The authors acknowledged all the students, postdocs, and colleagues in our papers in references section, all the friends to discuss chemistry with, and all the funding resources, principally AllyChem.

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Authors and Affiliations

  1. Faculty of Chemistry, University Rovira i Virgili, C/Marcel lí Domingo s/n, 43007, Tarragona, Spain

    Ana B. Cuenca & Elena Fernández

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  1. Ana B. Cuenca
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  2. Elena Fernández
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Corresponding author

Correspondence to Elena Fernández .

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Editors and Affiliations

  1. Facultat de Química, Universitat Rovira i Virgili, Tarragona, Spain

    Carmen Claver

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Cuenca, A.B., Fernández, E. (2016). Rhodium-Catalyzed C–B Bond Formation. In: Claver, C. (eds) Rhodium Catalysis. Topics in Organometallic Chemistry, vol 61. Springer, Cham. https://doi.org/10.1007/3418_2016_168

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