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Binuclear nickel(II) complexes with 3,5-di-tert-butylbenzoate and 3,5-di-tert-butyl-4-hydroxybenzoate anions and 2,3-lutidine: the synthesis, structure, and magnetic properties

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Abstract

Two novel binuclear nickel(II) complexes [Ni2(O2CR)4(2,3-lut)2] (O2CR is anion of 3,5-di(tert-butyl)benzoic acid (bzo, 1) and 4-hydroxy-3,5-di(tert-butyl)benzoic acid (hbzo, 2); 2,3-lut is 2,3-lutidine) with four carboxylate bridges were synthesized. The structure of complex 1 was determined by X-ray diffraction. Both dimers 1 and 2 were characterized by elemental analysis, IR spectroscopy, and magnetic measurements. The presence of the α-substituent in the apical lutidine ligand leads to a distortion of the geometry of the metal carboxylate core in complex 1 as a result of short steric contacts Me(Lut)…O(OOCR) (3.134(7) Å). This is apparently responsible for a considerable decrease in the exchange parameters of complexes 1 and 2 (J =–30.0 and–23.6 cm–1, respectively) as compared to known analogues. Density functional calculations of the structure and magnetic properties of 1 and 2 were carried out by the UB3LYP/6-31G(d,p) method.

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Authors and Affiliations

  1. N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky prosp., 119991, Moscow, Russian Federation

    S. A. Nikolaevskii, M. A. Kiskin, N. N. Efimov, A. A. Sidorov, V. M. Novotortsev & I. L. Eremenko

  2. Institute of Physical and Organic Chemistry at Southern Federal University, 194/2 prosp. Stachki, 344090, Rostov-on-Don, Russian Federation

    A. A. Starikova

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  1. S. A. Nikolaevskii
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  3. A. A. Starikova
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  4. N. N. Efimov
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  6. V. M. Novotortsev
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Correspondence to S. A. Nikolaevskii.

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Dedicated to Academician of the Russian Academy of Sciences R. Z. Sagdeev on the occasion of his 75th birthday.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 12, pp. 2812–2819, December, 2016.

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Nikolaevskii, S.A., Kiskin, M.A., Starikova, A.A. et al. Binuclear nickel(II) complexes with 3,5-di-tert-butylbenzoate and 3,5-di-tert-butyl-4-hydroxybenzoate anions and 2,3-lutidine: the synthesis, structure, and magnetic properties. Russ Chem Bull 65, 2812–2819 (2016). https://doi.org/10.1007/s11172-016-1661-z

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