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Structure control of heterometallic Li2Co2 metal core in pivalate clusters by varying apical ligands

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Abstract

Based on the heterometallic fragment {Li2Co2(Piv)6}, a new complex [(terpy)2Li2Co2(Piv)6] (1) was obtained, in which the terminal cobalt atoms coordinate the 2,2’:6’,2″-terpyridine (terpy) molecules. The metal core of the molecule is a Co—Li—Li—Co chain, the metal atoms in which are bonded between each other by the pairs of carboxylate bridges.

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Authors and Affiliations

  1. N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky prosp., 119991, Moscow, Russian Federation

    A. A. Sidorov, M. A. Kiskin, G. G. Aleksandrov & I. L. Eremenko

Authors
  1. A. A. Sidorov
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  2. M. A. Kiskin
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  3. G. G. Aleksandrov
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  4. I. L. Eremenko
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Corresponding author

Correspondence to M. A. Kiskin.

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Deceased.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 11, pp. 2754—2756, November, 2016.

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Sidorov, A.A., Kiskin, M.A., Aleksandrov, G.G. et al. Structure control of heterometallic Li2Co2 metal core in pivalate clusters by varying apical ligands. Russ Chem Bull 65, 2754–2756 (2016). https://doi.org/10.1007/s11172-016-1647-x

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  • DOI: https://doi.org/10.1007/s11172-016-1647-x

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