Abstract
Density (ρ) and speed of sound (u) of binary liquid mixtures of dimethyl carbonate and N-methylformamide have been determined at T = (303.15, 308.15, 313.15 and 318.15) K over the entire composition range. Experimental data are used to evaluate excess values of molar volume (\(V_{\text{m}}^{\text{E}}\)), isentropic compressibility (\(k_{\text{s}}^{\text{E}}\)), isothermal compressibility (\(k_{\text{T}}^{\text{E}}\)), intermolecular free length (\(L_{\text{f}}^{\text{E}}\)), acoustic impedance (\(Z^{\text{E}}\)) and ultrasonic speed (\(u^{\text{E}}\)). The VE data in the present investigation were analysed by using Prigogine–Flory–Patterson (PFP) theory. Partial and excess partial molar volumes (\(\bar{V}_{{{\text{m}},1}}\), \(\bar{V}_{{{\text{m}},2}}\)), (\(\bar{V}_{{{\text{m}},1}}^{\text{E}}\), \(\bar{V}_{{{\text{m}},2}}^{\text{E}}\)) and partial and excess partial molar volume of the components at infinite dilution (\(\overline{V}_{{{\text{m}},1}}^{\infty }\), \(\overline{V}_{{{\text{m}},2}}^{\infty }\)), (\(\overline{V}_{{{\text{m}},1}}^{{{\text{E}},\infty }}\), \(\overline{V}_{{{\text{m}},2}}^{{{\text{E}},\infty }}\)) at T = (303.15, 308.15, 313.15, 318.15) K have been calculated. The excess/deviation properties were fitted to Redlich–Kister equation to obtain their coefficients and standard deviations. The present investigation also comprises the acoustic nonlinearity parameter (B/A) in the mixtures and calculation of cohesive energy \(\Delta A\), Van der Wall’s constants (a, b) and distance of closest approach (d). Moreover, various semi-empirical relations of ultrasonic speed have been used to correlate the theoretical velocities. FT-IR spectra of pure components and their binaries have been measured at T = 298.15 K.
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One of the authors, Sk. Beebi, wishes to thank the Department of Chemistry and Department of Physics, Acharya Nagarjuna University, Nagarjuna Nagar, Guntur, for providing laboratory facilities.
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Beebi, S., Nayeem, S.M. & Rambabu, C. Investigation of molecular interactions in binary mixture of dimethyl carbonate + N-methylformamide at T = (303.15, 308.15, 313.15 and 318.15) K. J Therm Anal Calorim 135, 3387–3399 (2019). https://doi.org/10.1007/s10973-018-7574-3
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DOI: https://doi.org/10.1007/s10973-018-7574-3