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Structure of adsorbed polymer layers: Loops and tails

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Trends in Colloid and Interface Science X

Part of the book series: Progress in Colloid & Polymer Science ((PROGCOLLOID,volume 100))

Abstract

In this paper we discuss the elements of a recent mean-field theory developed to describe the structure of an adsorbed polymer layer. Recently it has been shown by Semenov and Joanny that the central part of an adsorbed polymer layer does not display a self-similar structure but the profiles depend on a characteristic length-scale z*. This length separates the region domainted by the loops from the region where tails are dominant and it is only dependent on the size of the chain and on the dimension of the space. The results of the mean-field calculation are compared with the numerical solution of the full self-consistent field calculations.

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References

  1. Napper DH (1983) Polymeric Stabilization of Colloidal Dispersions. Academic Press (London)

    Google Scholar 

  2. Eiseriegler E, Kremer K, Binder K (1982) J Chem Phys 77:6296

    Article  Google Scholar 

  3. de Genes PG (1979) Scaling Concepts in Polymer Physics. Cornell University Press Ithaca, New York, and references therein

    Google Scholar 

  4. Widom B, Phase Transitions and Critical Phenomena Domb C, Green M, eds; Academic Press (New York 1972)

    Google Scholar 

  5. de Gennes PG (1981) Macromolecules 14:1637–1644

    Article  Google Scholar 

  6. Fleer GJ, Cohen Stuart MA, Scheutjens JMHM, Cosgrove B, Vincent B, Polymers at Interfaces. Chapman and Hall (London 1993)

    Google Scholar 

  7. Semenov AN, Joanny JF (1995) Europhys Lett 29:279

    Article  CAS  Google Scholar 

  8. Semenov AN, Avalos JB, Johner A, Joanny JF, Macromolecules (accepted)

    Google Scholar 

  9. Avalos JB, van der Linden CC, Semenov AN, Johner A, Joanny JF; Macromolecules (submitted)

    Google Scholar 

  10. Avalos JB, Semenov AN, Johner A, Jonnay JF; Europhys Lett (submitted)

    Google Scholar 

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C. Solans M. R. Infante M. J. García-Celma

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© 1996 Dr. Dietrich Steinkopff Verlag GmbH & Co. KG

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Avalos, J.B., Semenov, A.N., Johner, A., Joanny, J.F., van der Linden, C.C. (1996). Structure of adsorbed polymer layers: Loops and tails. In: Solans, C., Infante, M.R., García-Celma, M.J. (eds) Trends in Colloid and Interface Science X. Progress in Colloid & Polymer Science, vol 100. Steinkopff. https://doi.org/10.1007/BFb0115764

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  • DOI: https://doi.org/10.1007/BFb0115764

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  • Publisher Name: Steinkopff

  • Print ISBN: 978-3-7985-1056-2

  • Online ISBN: 978-3-7985-1665-6

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