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Removal of mercury cyanide species from solutions using dimethyl dithiocarbamates

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Abstract

The dissolution of mercury during the gold cyanidation process is the cause of many environmental, health and processing problems. The removal of mercury-cyanide complexes from synthetic solutions and process water were investigated using sodium and potassium dimethyl dithiocarbamates and sodium sulfide as precipitating reagents. The results have shown that efficient mercury removal can be achieved by the formation of stable mercury compounds with the addition of potassium dimethyl dithiocarbamate. The mercury dimethyl dithiocarbamate precipitates are stable under plant operating conditions, and they do not have any deleterious effect on gold adsorption by activated carbon. Furthermore, it is possible to stabilize mercury in the heap during cyanidation by adding dimethyl dithiocarbomate.

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References

  • Baldi, G.J., and Olsen, 1987, “Effects of cinnabar on pyrite oxidation by Thiobacillus ferroxidans and cinnabar mobilization by a mercury resistant strain,” Applied and Environmental Microbiology, pp. 772–776.

    Google Scholar 

  • Diaz, X., Miller, J.D., and Wan, R.-Y, 1993, “Selective solvent extraction of gold from mercury in concentrated alkaline cyanide solutions,” EPD Congress, pp. 245–257.

    Google Scholar 

  • Entberg, H., Baxter, D.C., Sharp, M., and Freeh, W., 1995, “Evaluation, mechanism and applications of solid phase extraction using a dithio-carbamate resin for the sampling and determination of mercury species in humic-rich natural waters,” Analyst, Vol. 120, pp. 69–77, January.

    Article  Google Scholar 

  • Garner, H.R., Moss, J.M., and Block, D.G., 1981, “Waste treatment of electroless nickel,” Proceedings Electroless Nickel Conference, pp. 1–17.

    Google Scholar 

  • Ibrado and Fuerstenau, D.W., 1989, “Adsorption of the cyano complexes of Ag(I), Cu(I), Hg(II), Cd(II) and Zn(II) on activated carbon,” Minerals and Metallurgical Processing, pp. 23–28.

    Google Scholar 

  • Kerry, P.M., Welbourn, B., Prucha and Mierle, G., 1991, “mercury methyla-tion by sulfate-reducing bacteria from sediments of an acid stressed lake,” Water, Air and Soil Pollution, Vol. 56, pp. 565–575.

    Article  Google Scholar 

  • Leja, J., 1982, Surface Chemistry of Froth Flotation, Plenum Press, New York, pp. 258–259.

    Google Scholar 

  • Lorengo, J.A., 1995, “The Removal of Mercury from Cyanide Leach Solution using Dithiocarbamates,” M.S. Thesis, University of Nevada.

    Google Scholar 

  • Miller, J.D., Alfaro, E., Misra, M., and Lorengo, J., 1995, “Mercury control in the cyanidation of gold ores,” Proceedings of the Engineering Foundation: Technical Solutions for the Pollution Prevention in the Mining and Minerals Processing Industry.

    Google Scholar 

  • Milosavjevic, J.H, Nelson, J.H., and Hendrix, J.L., 1994, “Mercury Species in Precious Metals Extraction Wastes-Stabilization Methods,” Private Communication, University of Nevada, Reno.

    Google Scholar 

  • Misra, M., and Lorengo, J., 1997, “Method of Removing Mercury from Solution,” U.S. Patent 5,599,515.

    Google Scholar 

  • Sandberg, R.G., Simpson, W.W., and Staker, W.L., 1984, “Calcium Sulfide Precipitation of Mercury During Cyanide Leaching of Gold Ores,” USBM, Report of Investigation 8907.

    Google Scholar 

  • Simpson, W.W., Staker, W.L., and Sandberg, R.G., 1986, “Calcium Sulfate Precipitation of Mercury from Gold-Silver Cyanide Leach Slurries,” USBM, Report of Investigation 9042.

    Google Scholar 

  • Staker, W.L., and Sandberg, R.G, —DATE—, “Mercury Removal from Gold Cyanide Leach Solution,” USBM, Report of Investigation 3.

  • Stalidis, G.A., Matis, K.A., and Lazaridis, N.K., 1988, “a statistical approach to precipitation flotation of CuS/ZnS,” International Journal of Mineral Processing, Vol. 24, p. 203.

    Article  Google Scholar 

  • Wing, R.E, and Redford, W.E., 1982, “Heavy metals removal using dithiocarbamates,” Plating and Surface Finishing, Vol. 69, No. 1, pp. 67–71, January.

    Google Scholar 

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Misra, M., Lorengo, J., Nanor, J.B. et al. Removal of mercury cyanide species from solutions using dimethyl dithiocarbamates. Mining, Metallurgy & Exploration 15, 60–64 (1998). https://doi.org/10.1007/BF03403160

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  • DOI: https://doi.org/10.1007/BF03403160

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