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Nanomaterials Synthesis and Applications: Molecule-Based Devices

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Book cover Springer Handbook of Nanotechnology

Part of the book series: Springer Handbooks ((SHB))

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Abstract

The constituent components of conventional devices are carved out of larger materials relying on physical methods. This top-down approach to engineered building blocks becomes increasingly challenging as the dimensions of the target structures approach the nanoscale. Nature, on the other hand, relies on chemical strategies to assemble nanoscaled biomolecules. Small molecular building blocks are joined to produce nanostructures with defined geometries and specific functions. It is becoming apparent that nature's bottom-up approach to functional nanostructures can be mimicked to produce artificial molecules with nanoscaled dimensions and engineered properties. Indeed, examples of artificial nanohelices, nanotubes, and molecular motors are starting to be developed. Some of these fascinating chemical systems have intriguing electrochemical and photochemical properties that can be exploited to manipulate chemical, electrical, and optical signals at the molecular level. This tremendous opportunity has led to the development of the molecular equivalent of conventional logic gates. Simple logic operations, for example, can be reproduced with collections of molecules operating in solution. Most of these chemical systems, however, rely on bulk addressing to execute combinational and sequential logic operations. It is essential to devise methods to reproduce these useful functions in solid-state configurations and, eventually, with single molecules. These challenging objectives are stimulating the design of clever devices that interface small assemblies of organic molecules with macroscaled and nanoscaled electrodes. These strategies have already produced rudimentary examples of diodes, switches, and transistors based on functional molecular components. The rapid and continuous progress of this exploratory research will, we hope, lead to an entire generation of molecule-based devices that might ultimately find useful applications in a variety of fields, ranging from biomedical research to information technology.

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Abbreviations

CD:

compact disc

CD:

critical dimension

DNA:

deoxyribonucleic acid

SWNT:

single-wall nanotube

TTF:

tetrathiafulvalene

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Authors and Affiliations

  1. Department of Chemistry, University of Miami, 1301 Memorial Drive, 33146-0431, Coral Gables, FL, USA

    Françisco Raymo Prof.

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  1. Françisco Raymo Prof.
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Correspondence to Françisco Raymo Prof. .

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  1. Nanotribology Laboratory for Information Storage and MEMS/NEMS (NLIM), Ohio State University, 201 W. 19th Avenue, W 390 Scott Laboratory, Ohio 43210-1142, Columbus, OH, USA

    Bharat Bhushan Prof.

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Raymo, F. (2007). Nanomaterials Synthesis and Applications: Molecule-Based Devices. In: Bhushan, B. (eds) Springer Handbook of Nanotechnology. Springer Handbooks. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-540-29857-1_2

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