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N4-Macrocyclic Metal Complexes

  • Book
  • © 2006

Overview

Editors:
  1. José H. Zagal

    1. Departamento de Química de los Materiales Facultad de Química y Biología, Universidad de Santiago de Chile, Santiago, Chile

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  2. Fethi Bedioui

    1. Laboratoire de Pharmacologie Chimique et Génétique UMR CNRS No. 8151/U 64, Ecole Nationale Supérieure de Chimie de Paris, Paris, France

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  3. Jean-Pol Dodelet

    1. INRS-énergie, Matériaux et Télécommunications, Varennes, Canada

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  • Wide scope, encompassing the fundamental chemistry of N4- metal complexes, their characterization, and applications
  • This group of compounds has found application to biomimetic electrocatalysis, electroanalysis and energy storage

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Table of contents (14 chapters)

  1. Front Matter

    Pages i-xviii
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  2. Billion-Year-Old Oxygen Cathode that Actually Works: Respiratory Oxygen Reduction and Its Biomimetic Analogs

    • Roman Boulatov
    Pages 1-40

  3. Fundamental Aspects on the Catalytic Activity of Metallomacrocyclics for the Electrochemical Reduction of O2

    • José H. Zagal, Maritza A. Páez, J. Francisco Silva
    Pages 41-82

  4. Oxygen Reduction in PEM Fuel Cell Conditions: Heat-Treated Non-Precious Metal-N4 Macrocycles and Beyond

    • Jean-Pol Dodelet
    Pages 83-147

  5. Biomimetic NOx Reductions by Heme Models and Proteins

    • Emek Blair, Filip Sulc, Patrick J. Farmer
    Pages 149-190

  6. Electroreduction of CO2 Catalyzed by Metallomacrocyclics

    • Juan A. Costamagna, Mauricio Isaacs, María J. Aguirre, Galo Ramírez, Ignacio Azocar
    Pages 191-254

  7. Supramolecular Porphyrins as Electrocatalysts

    • Koiti Araki, Henrique Eisi Toma
    Pages 255-314

  8. Electrodes Modified with Monomeric M-N4 Catalysts for the Detection of Environmentally Important Molecules

    • Tebello Nyokong
    Pages 315-361

  9. Electropolymerized Metalloporphyrin Metallophthalocyanine and Metal Schiff Base Complex Films: Applications to Biomimetic Electrocatalysis and Bioelectroanalysis

    • Alain Pailleret, Fethi Bedioui
    Pages 363-438

  10. Electron Transfer Processes of β-Pyrrole Brominated Porphyrins: Structural vs. Electronic Effects

    • Francis D'Souza, Karl Kadish
    Pages 439-466

  11. Photoelectrochemical Reactions at Phthalocyanine Electrodes

    • Derck Schlettwein
    Pages 467-515

  12. Organisation and Photoelectrochemical Reactivity of Water-Soluble Metalloporphyrins at the Liquid/Liquid Interface

    • David Fermín, Nicolas Eugster
    Pages 517-574

  13. Theoretical Insights on the Chemical Reactivity of Metalloporphyrins Using Density Functional Theory

    • Ilaria Ciofin, Laurent Jouber, Michele Pavone, Vincenzo Barone, Carlo Adamo
    Pages 575-601

  14. Organized Multiporphyrinic Assemblies for Photoconduction and Electroconduction

    • Jean Weiss, Jennifer Wytko
    Pages 603-724

  15. Vibrational Spectra and Surface-Enhanced Vibrational Spectra of Azamacrocycles

    • Marcelo M. Campos Vallete
    Pages 725-800

  16. Back Matter

    Pages 801-814
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Reviews

From the reviews:

"This is an excellent and detailed book of 14 chapters that is timely in its reviews of the electrochemical and electrocatalytic properties of the porphyrinoids and is written by a range of experts in the different fields covered. … this is an exciting book to read. It would be a really useful book to have in the laboratory library. The chapters are detailed and informative with excellent tables and figures … ." (Martin Stillman, Journal of the American Chemical Society, Vol. 129 (5), 2007)

Editors and Affiliations

  • Departamento de Química de los Materiales Facultad de Química y Biología, Universidad de Santiago de Chile, Santiago, Chile

    José H. Zagal

  • Laboratoire de Pharmacologie Chimique et Génétique UMR CNRS No. 8151/U 64, Ecole Nationale Supérieure de Chimie de Paris, Paris, France

    Fethi Bedioui

  • INRS-énergie, Matériaux et Télécommunications, Varennes, Canada

    Jean-Pol Dodelet

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