Abstract
Cellulose diacetate (CDA)/kenaf fiber biocomposites were prepared using a melting process. In order to increase the fiber density and compatibilize the kenaf fiber with CDA, the fiber was sized with poly(vinyl alcohol)(PVA). The sized kenaf fiber was compounded with the plasticized CDA using a twin screw extruder, and the optimal processing conditions were determined. The incorporated kenaf fiber improved the mechanical and thermal properties of CDA. In the case of the composites containing 30 wt% kenaf fibers, the tensile strength and modulus increased almost 2 and 3 fold, which were 85.6 MPa and 4831 MPa, respectively. The PVA treated kenaf fiber showed better adhesion to the CDA matrix.
Similar content being viewed by others
References
L. Brandt, in Ullmann’s Encyclopedia of Industrial Chemistry, F.T. Campbell, Ed., VCH Verlag., Weinheim, 1986, p. 461.
H. Barani and S. H. Bahrani, Macromol. Res., 15, 605 (2007).
Y. Kiso, T. Kitao, and K. Nishimura, Appl. Polym. Sci., 71, 1657 (1999).
J. Pauly, H. Allaart, M. Rodriguez, and R. Streck, Cancer Res., 55, 253 (1995).
K. Kamide, K. Okajima, K. Kowsaka, and T. Matsui, Polym. J., 19, 1405 (1987).
S. H. Lee, S. Y. Lee, H. K. Lim, J. D. Nam, H. S. Kye, and Y. K. Lee, Polymer(Korea), 30, 202 (2006).
S. Y. Lee, M. S. Cho, J. D. Nam, and Y. Lee, Macromolecular Symposia, 242, 126 (2006).
H. K. Lim, H. Kye, S. Won, J. D. Nam, and Y. Lee, Polymer (Korea), 32, 178 (2008).
C. Lee, M. Cho, I. Kim, J. Nam, and Y. Lee, Polymer(Korea), 33, 243 (2009).
S. V. Joshi, L. T. Drzal, A. K. Mohanty, and S. Arora, Composites: A, 35, 371 (2004).
A. K. Mohanty, A. Wibowo, M. Misra, and L. T. Drzal, Comspites: A, 35, 363 (2004).
S. Ouajai and R. A. Shanks, Macromol. Mater. Eng., 294, 213 (2009).
N. Sgriccia, M. C. Hawley, and M. Misra, Composites: A, 39, 1632 (2008).
Y. H. Han, S. O. Han, D. Chi, and H. I. Kim, Macromol. Res., 16, 253 (2008).
M. Zampaloni, F. Pourbogherat, S. A. Yankovich, B. N. Rodgers, J. Moore, L. T. Drzal, A. K. Mohanty, and M. Misra, Composites: A, 38, 1569 (2007).
Che, L. Sun, O. Chiparus, I. Negulescu, V. Yachmenev, and M. Warnock, J. Polym. Environ., 13, 107 (2005).
F. L. Malten, in Encyclopedia of polymer science and engineering, J. I. Kroschwita, Ed., John Wiley and Sons, New York, 1985, Vol. 17, p. 167.
T. Ke and X. S. Sun, J. Polym. Environ., 11, 7 (2003).
M. Edeerozey, H. M. Akil, A. B. Azhar, and M. I. Z. Ariffin, Mater. Lett., 61, 2023 (2007).
D. Bachtiar, S. M. Sapuan, and M. M. Hamdan, Mater. Des., 29, 1285 (2008).
I. Van de Weyenberg, J. Ivens, A. De Coster, B. Kino, E. Baetens, and I. Verpoest, Compos. Sci. Technol., 63, 1241 (2003).
G. Bogoeva-Gaceva, M. Avella, M. Malinconico, A. Buzarovska, A. Grozdano, G. Gentile, and M. E. Errico, Polymer Composite, 28, 98 (2007).
S. Ochi, Mech. Mater., 40, 446 (2008).
S. Mishra, A. K. Mohanty, L. T. Drzal, M. Misra, S. Parija, S. K. Nayak, and S. Tripathy, Compos. Sci. Technol., 63, 1377 (2003).
S. A. Paul, A. Boudenne, L. Ibos, Y. Candau, K. Joseph, and S. Thomas, Composites: A, 39, 1582 (2008).
H. S. Lee and D. W. Cho, Macromol. Res., 16, 411 (2008).
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Lee, CK., Cho, M.S., Kim, I.H. et al. Preparation and physical properties of the biocomposite, cellulose diacetate/kenaf fiber sized with poly(vinyl alcohol). Macromol. Res. 18, 566–570 (2010). https://doi.org/10.1007/s13233-010-0611-0
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s13233-010-0611-0