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Acetone adsorption on hydroxylated silica gel: Correlation of sorption isotherms and IR spectra

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Abstract

Results of adsorption and IR studies on the interaction of acetone with fully and partially hydroxylated surfaces of a KSS-3 silica gel are presented. Two plateaus on adsorption isotherms and two CO bands in IR absorption spectra are in close connection, which clearly indicates two adsorption complexes of acetone with different surface OH groups of silica. The weaker adsorption form (CO stretching vibration at 1705 cm−1) corresponds to the formation of an adsorption complex between an acetone molecule and a terminal OH-group (OH stretching vibration at 3740 cm−1). An abnormally high fractal dimension of the silica gel surface has been obtained and discussed.

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References

  1. V.Ya. Davidov, L.T. Zhuravlev, A.V. Kiselev:Russ. J. Phys. Chem.,38, 2254 (1964).

    Google Scholar 

  2. L.R. Snyder, J.W. Word:J. Phys. Chem.,72, 3941 (1966).

    Google Scholar 

  3. J. Nawrocki:Chromatographia,31, 177 (1991).

    Article  CAS  Google Scholar 

  4. G.D. Parfitt, C.H. Rochester: inAdsorption from Solution at the Solid/Liquid Interface. Academic Press, New-York 1983.

    Google Scholar 

  5. D.M. Griffits, K. Marshall, C.H. Rochester:J. Chem. Soc. Faraday Trans. 1,70, 400 (1974).

    Article  Google Scholar 

  6. K.B. Gavrilov, Ya.E. Kutsovskiy, E.A. Paukshtis, A.G. Okunev, Yu.I. Aristov:Mol. Cryst. Liq. Cryst.,248, 159 (1994).

    Google Scholar 

  7. Ya.E. Kutsovskiy, E.A. Paukshtis, Yu.I. Aristov:React. Kinet. Catal. Lett.,46, 57 (1992).

    Article  Google Scholar 

  8. A. McClellan, H. Harnsberger:J. Coll. Interface Sci.,23, 577 (1967).

    Article  CAS  Google Scholar 

  9. P. Pfeifer, D. Avnir:J. Chem. Phys.,79, 3558 (1983).

    Article  CAS  Google Scholar 

  10. B. Mandelbrot:Fractal Geometry of Nature. Freeman, San Francisco 1982.

    Google Scholar 

  11. J.M. Drake, P. Levitz, J. Klafter:Isr. J. Chem.,31, 135 (1991).

    CAS  Google Scholar 

  12. Ya.E. Kutsovskii, E.A. Paukshtis, Yu.I. Aristov:React. Kinet. Catal. Lett.,46, 57 (1992).

    Article  CAS  Google Scholar 

  13. H. Van Damme, P. Levitz, F. Bergaya, J.F. Alcover, L. Gatineau, J.J. Fripiat:J. Chem. Phys.,85, 616 (1986).

    Article  Google Scholar 

  14. K.B. Gavrilov, A.G. Okunev, Yu.I. Aristov:React. Kinet. Catal. Lett.,58, 39 (1996).

    Article  CAS  Google Scholar 

  15. A.J. van Roosmalen, J.C. Mol:J. Phys. Chem.,82, 2748 (1978).

    Article  Google Scholar 

  16. A.J. van Roosmalen, J.C. Mol:J. Phys. Chem.,83, 2485 (1979).

    Article  Google Scholar 

  17. A.G. Okunev, Yu.I. Aristov:Langmuir, (submitted).

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Authors and Affiliations

  1. Boreskov Institute of Catalysis, 630090, Novosibirsk, Russia

    A. G. Okunev, E. A. Paukshtis & Y. I. Aristov

Authors
  1. A. G. Okunev
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  2. E. A. Paukshtis
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  3. Y. I. Aristov
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Okunev, A.G., Paukshtis, E.A. & Aristov, Y.I. Acetone adsorption on hydroxylated silica gel: Correlation of sorption isotherms and IR spectra. React Kinet Catal Lett 65, 161–167 (1998). https://doi.org/10.1007/BF02475330

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  • DOI: https://doi.org/10.1007/BF02475330

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