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Effect of hydrothermal treatment on the structure of an aluminosilicate polymer

  • Research Article
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Central European Journal of Chemistry

Abstract

The effect of hydrothermal treatment on the structure of an aluminosilicate polymer prepared by a polycondensation reaction between silicate and hydroxoaluminate in alkaline aqueous solution was studied. The structural changes were investigated using X-ray diffraction analysis, Fourier-transform infrared spectroscopy, scanning electron microscopy imaging and thermogravimetric analysis. The results indicated that the amorphous aluminosilicate polymer transformed into a crystalline product during the hydrothermal treatment at 145°C. The crystalline phase was identified as a mineral of the zeolite group, most likely phillipsite. This transformation required an alkaline environment during the hydrothermal treatment.

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Authors and Affiliations

  1. Department of Environment Protection Engineering, Faculty of Technology, Tomas Bata University in Zlin, 762 72, Zlin, Czech Republic

    Jaroslav Melar, Vratislav Bednarik & Roman Slavik

  2. Department of Polymer Engineering, Faculty of Technology, Tomas Bata University in Zlin, 762 72, Zlin, Czech Republic

    Miroslav Pastorek

Authors
  1. Jaroslav Melar
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  2. Vratislav Bednarik
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  3. Roman Slavik
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  4. Miroslav Pastorek
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Correspondence to Vratislav Bednarik.

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Melar, J., Bednarik, V., Slavik, R. et al. Effect of hydrothermal treatment on the structure of an aluminosilicate polymer. cent.eur.j.chem. 11, 782–789 (2013). https://doi.org/10.2478/s11532-013-0204-9

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  • DOI: https://doi.org/10.2478/s11532-013-0204-9

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