Abstract.
Ag nanoparticles were deposited on a hydrogenate amorphous carbon (a-C:H) thin film as a host by radio frequency plasma enhanced chemical vapor deposition (RF-PECVD) for various deposition times. We observed that as the sputtering time increases, the particle shape of the deposited nanostructures changes to a cluster shape. AFM images show that the accumulation of the nanoparticles on each other leads to the vertical growth of the nanoclusters. According to X-ray diffraction patterns, the crystalline structure is formed for the nanocluster shape. The Fourier-transform infrared (FTIR) spectroscopy showed that bonds are formed between Ag ions and free hands of carbons on the surface of the a-C:H film. The peak related to carbide structures is seen around 2100cm^-1. UV-Vis spectroscopy demonstrates that the formation of Ag nanoclusters leads to the appearance of a sharp plasmonic peak, shifted towards longer wavelengths. The plasmonic peak of Ag was used for detecting CO gas in the ambient air. The adhesion of CO molecules to the Ag particles makes a significant change in the plasmonic peak. In the presence of CO gas flow, the localized surface plasmon resonance (LSPR) of Ag nanoclusters moves to a longer wavelength (red-shift) and the LSPR intensity increases. The sample with a nanocluster structure is a better adsorber for CO molecules due to its larger specific surface area.
Similar content being viewed by others
References
V. Kreibig, M. Vollmer, Optical Properties of Metal Clusters (Springer, Berlin, 1995)
R. Aroca, Surface-Enhanced Vibrational Spectroscopy (John Wiley and Sons, Inc., England, 2006) pp. 48--57
E. Hao, G.C. Schatz, J. Chem. Phys. 120, 357 (2004)
K.L. Kelly, E. Coronado, L.L. Zhao, G.C. Schatz, J. Phys. Chem. B 107, 668 (2003)
E. Hutter, J.H. Fendler, Adv. Mater. 16, 1685 (2004)
P.M. Mendes, S. Jacke, K. Critchley, J. Plaza, Y. Chen, K. Nikitin, R.E. Palmer, J.A. Preece, S.D. Evans, D. Fitzmaurice, Langmuir 20, 3766 (2004)
F. Juillerat, H.H. Solak, P. Bowen, H. Hoffmann, Nanotechnology 16, 1311 (2005)
S. Meškinis, A. Čiegis, A. Vasiliauskas, A. Tamulevičiene, K. Slapikas, R. Juškenas, G. Niaura, S. Tamulevičius, Appl. Surf. Sci. 317, 1041 (2014)
A. Moores, F. Goettmann, New J. Chem. 30, 1121 (2006)
C. Noguez, J. Phys. Chem. C 111, 3806 (2007)
J. Oviedo, R.E. Palmer, J. Chem. Phys. 117, 9548 (2002)
G. Schmid, D. Fenske, Philos. Trans. Math. Phys. Eng. Sci. 368, 1207 (2010)
S. Talu, Micro and Nanoscale Characterization of Three Dimensional Surfaces. Basics and Applications (Napoca Star Publishing House, Cluj-Napoca, Romania, 2015)
S. Ţălu, M. Bramowicz, S. Kulesza, V. Dalouji, S. Solaymani, S. Valedbagi, Microsc. Res. Tech. 79, 1208 (2016)
M. Zare, S. Solaymani, A. Shafiekhani, S. Kulesza, S. Ţălu, M. Bramowicz, Sci. Rep. 8, 10870 (2018)
S. Ţălu, M. Bramowicz, S. Kulesza, A. Shafiekhani, M. Rahmati, A. Ghaderi, M. Ahmadirad, S. Solaymani, Surf. Interface Anal. 49, 153 (2017)
T. Ghodselahi, M.A. Vesaghi, A. Shafiekhani, M. Ahmadi, M. Panahandeh, M. Heidari Saani, Physica B: Condens. Matter 405, 3949 (2010)
S. Tamulevičius, S. Meškinis, K. Slapikas, A. Vasiliauskas, R. Gudaitis, M. Andrulevičius, A. Tamulevičiene, G. Niaura, Thin Solid Films 538, 78 (2013)
M. Ahmadirad, A. Yazdani, K. Rahimi, Eur. Phys. J. Plus 133, 216 (2018)
J.M. Bingham, J.N. Anker, L.E. Kreno, R.P. Van Duyne, J. Am. Chem. Soc. 132, 17358 (2010)
X. Lang, L. Qian, P. Guan, J. Zi, M. Chen, Appl. Phys. Lett. 98, 093701 (2011)
T.R. Jensen, M.D. Malinsky, C.L. Haynes, R.P. Van Duyne, J. Phys. Chem. B 104, 10549 (2000)
M. Treguer- Delapierre, J. Majimel, S. Mornet, E. Duguet, S. Ravaine, Gold Bull. 41, 195 (2008)
U. Kreibig, L. Genzel, Surf. Sci. 156, 678 (1985)
L.M. Liz-Marzan, Mater. Today 7, 26 (2004)
J. Liu, J.C. Bernard, K. Seeger, R.E. Palmer, Appl. Phys. Lett. 73, 2030 (1998)
A.J. Parker, P.A. Childs, R.E. Palmer, M. Brust, Appl. Phys. Lett. 74, 2833 (1999)
T.J. Krinke, H. Fissan, K. Deppert, M.H. Magnusson, Appl. Phys. Lett. 78, 3708 (2001)
N.C. Bigall, A. Eychmüller, Philos. Trans. R. Soc. A 368, 1385 (2010)
B. Corain, M. Zecca, P. Canton, P. Centomo, Philos. Trans. R. Soc. A 368, 1495 (2010)
S. Meškinis, T. Tamulevičius, G. Niaura, K. Slapikas, A. Vasiliauskas, O. Ulčinas, S. Tamulevičius, J. Nanosci. Nanotechnol. 16, 10143 (2016)
R. Dreyfus et al., Nature 437, 862 (2005)
I. Musevic, M. Skarabot, U. Tkalec, M. Ravnik, S. Zumer, Science 313, 954 (2006)
S.L. Biswal, A.P. Gast, Phys. Rev. E 69, 041406 (2004)
J.B. Jackson, S.C. Westcott, L.R. Hirsch, J.L. West, N. Halas, J. Appl. Phys. Lett. 82, 257 (2003)
I.L. Garzón, K. Michaelian, M.R. Beltrán, A. Posada-Amarillas, P. Ordejón, E. Artacho, D. Sánchez-Portal, J.M. Soler, Phys. Rev. Lett. 81, 1600 (1998)
J.P.K. Doye, D.J. Wales, New J. Chem. 22, 733 (1998)
B.B. Yellen, O. Hovorka, G. Friedman, Proc. Natl. Acad. Sci. U.S.A. 102, 8860 (2005)
Y. Yin, Y. Lu, B. Gates, Y. Xia, J. Am. Chem. Soc. 123, 8718 (2001)
Y. Lu, Y. Yin, Z.Y. Li, Y. Xia, Nano Lett. 2, 785 (2002)
W.C. Hung, W.H. Cheng, M.S. Tsai, Y.C. Juan, I.M. Jiang, P. Yeh, Appl. Phys. Lett. 90, 183115 (2007)
S.Y. Park, D. Stroud, Phys. Rev. B 68, 224201 (2003)
T. Ghodselahi, H. Zahrabi, M. Heidari Saani, M.A. Vesaghi, J. Phys. Chem. C 115, 22126 (2011)
M. Ando, T. Kobayashi, S. Iijima, M. Haruta, J. Mater. Chem. 7, 1779 (1997)
M. Ando, T. Kobayashi, S. Iijima, M. Haruta, Sens. Actuators B 96, 589 (2003)
G. Sirink, R. Siddique, I. Manning, Ph.H. Rogers, M. Carpenter, J. Phys. Chem. B 110, 13508 (2006)
Y. Chao, H. Yang, Y. Li, S. Guo, Cheng Wang, Chuan Wang, Chem. Phys. Lett. 708, 183 (2018)
P. Prosposito et al., Beilstein J. Nanotechnol. 7, 1654 (2016)
C.J. Hulteen, A.D. Treichel, T.M. Smith, L.M. Duval, R.T. Jensen, P.R. Van Duyne, J. Phys. Chem. B 103, 3854 (1999)
M.E. Hicks, O. Lyandres, W.P. Hall, S. Zou, R.M. Glucksberg, P.R. Van Duyne, J. Phys. Chem. C 111, 4116 (2007)
M.A. Hung, M.C. Micheel, D.L. Bozano, W.L. Osterbur, M.G. Wallraff, N.J. Cha, Nat. Nanotechnol. 5, 121 (2009)
S. Meškinis, A. Vasiliauskas, K. Slapikas, R. Gudaitis, M. Andrulevičius, A. Čiegis, G. Niaura, R. Kondrotas, S. Tamulevičius, Surf. Coat. Technol. 255, 84 (2014)
I. Yaremchuk, S. Meškinis, V. Fitio, Y. Bobitski, K. Slapikas, A. Čiegis, Z. Balevičius, A. Selskis, S. Tamulevičius, Nanoscale Res. Lett. 10, 157 (2015)
W.C. Lan, S.F. Ou, M.H. Lin, K.L. Ou, M.Y. Tsai, Ceram. Int. 39, 4099 (2013)
Y. Wu, J. Chen, H. Li, L. Ji, Y. Ye, H. Zhou, Appl. Surf. Sci. 284, 165 (2013)
J. Robertson, Mater. Sci. Eng.: R: Reports 37, 129 (2002)
M. Ohring, The Materials Science of Thin Films (Academic Press, Inc., 1992)
M. Spolaore, V. Antoni, M. Bagatin, A. Buffa, Surf. Coat. Technol. 116, 1083 (1999)
R.E.H. Clark, D.H. Reiter (Editors), Nuclear Fusion Research (Springer, 2005)
Y. Kudriavtsev et al., Appl. Surf. Sci. 239, 273 (2005)
K.B. Mogensen, K. Kneipp, J. Phys. Chem. C 118, 28075 (2014)
V. Ţucureanu, A. Matei, A.M. Avram, Crit. Rev. Anal. Chem. 46, 502 (2016)
R. Paul, R.N. Gayen, S. Hussain, V. Khanna, R. Bhar, A.K. Pal, Eur. Phys. J. Appl. Phys. 47, 10502 (2009)
D. Makwana, J. Castano, R.S. Somani, H.C. Bajaj, Arab. J. Chem. (2018) https://doi.org/10.1016/j.arabjc.2018.08.017
A. Fahmy, W.H. Eisa, M. Yosef, A. Hassan, J. Spectrosc. 2016, 7489536 (2016)
Author information
Authors and Affiliations
Corresponding author
Additional information
Publisher’s Note
The EPJ Publishers remain neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
About this article
Cite this article
Ahmadirad, M., Yazdani, A. & Rahimi, K. Optical detection of CO gas by the surface-plasmon resonance of Ag nanoparticles and nanoclusters synthesized on a hydrogenated amorphous carbon (a-C:H) film. Eur. Phys. J. Plus 134, 328 (2019). https://doi.org/10.1140/epjp/i2019-12646-6
Received:
Accepted:
Published:
DOI: https://doi.org/10.1140/epjp/i2019-12646-6