Abstract
A scaling law for bubble nucleation data is developed based on the classical nucleation theory and a scaled surface tension correlation. The scaled approach is applied to a set of bubble nucleation data for lower alkanes available in the literature. The results are found to agree well also with the nucleation data for several other non-polar substances. The scaling approach is presented as a tool useful for checking the consistency of bubble nucleation data reported in the literature, and for predicting bubble nucleation for substances not measured experimentally.
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References
R. McGraw, J. Chem. Phys. 75, 5514 (1981).
D. Rasmussen, S. Babu, Chem. Phys. Lett. 108, 449 (1984).
B.N. Hale, Phys. Rev. A 33, 4156 (1986).
B. Hale, D. DiMattio, J. Phys. Chem. B 108, 19780 (2004).
B.N. Hale, J. Chem. Phys. 122, 204509 (2005).
D. Martinez, F. Ferguson, R. Heist, J. Nuth, J. Chem. Phys. 115, 310 (2001).
B. Hale, G. Wilemski, Chem. Phys. Lett. 305, 263 (1999).
B.N. Hale, M. Thomason, Phys. Rev. Lett. 105, 046101 (2010).
V. Skripov, G. Ermakov, Russ. J. Phys. Chem. 38, 396 (1964).
V.G. Baidakov, A.M. Kaverin, V.P. Skripov, Zh. Fiz. Khim. 54, 2119 (1980).
V.G. Baidakov, Low Temp. Phys. 39, 643 (2013).
C.T. Avedisian, J. Phys. Chem. Ref. Data 14, 695 (1985).
Y. Mori, K. Hijikata, T. Nagatani, Int. J. Heat Mass Transfer 19, 1153 (1976).
D. Kashchiev, Nucleation - Basic Theory with Applications (Butterworth-Heinemann, 2000).
C. Miqueu, D. Broseta, J. Satherley, B. Mendiboure, J. Lachaise, A. Graciaa, Fluid Phase Equilib. 172, 169 (2000).
V.G. Baidakov, V.P. Skripov, Zh. Fiz. Khim. 56, 818 (1982).
P. Linstrom, W. Mallard, NIST Chemistry WebBook, NIST Standard Reference Database Number 69 (National Institute of Standards and Technology, Gaithersburg MD, 2014), http://webbook.nist.gov.
B.E. Poling, J.M. Prausnitz, J.P. O'Connell, The Properties Of Gases And Liquids, 5th edn. (McGraw-Hill Companies, Inc., 2001).
K.S. Pitzer, Thermodynamics, Vol. 3 (McGraw-Hill, New York, 1995).
B.N. Hale, Metallurg. Trans. A 23, 1863 (1992).
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Němec, T. Scaled nucleation theory for bubble nucleation of lower alkanes. Eur. Phys. J. E 37, 111 (2014). https://doi.org/10.1140/epje/i2014-14111-5
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DOI: https://doi.org/10.1140/epje/i2014-14111-5