Abstract
Coarse grain Brownian dynamics simulations of the bead-spring model are used to investigate the effect of attractive surfaces on the stretching of confined tethered polymers under shear flow. The weak and strong adsorbed regimes have been addressed by means of a coarse grain van der Waals potential to simulate polymer substrate interactions. Different stationary cyclic dynamics are observed upon varying shear flow intensity and surface potential strength. Polymer stretching decreases as increasing the attractive potential strength, breaking down the scaling predictions for non-adsorbed polymers. We found that adsorption is enhanced by the shear flow strength in agreement to simulations of adsorbed non-tethered polymers.
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References
P.G. de Gennes, Scaling Concepts in Polymer Physics (Cornell, New York, 1977).
F. Brochard, P.G. de Gennes, J. Chem. Phys. 67, 52 (1977).
F. Brochard-Wyart, P.G. de Gennes, Europhys. Lett. 23, 105 (1993).
A. Buguin, F. Brochard-Wyart, Macromolecules 29, 4937 (1996).
P. Doyle, B. Ladoux, Phys. Rev. Lett. 84, 4769 (2000).
B. Ladoux, P. Doyle, Europhys. Lett. 52, 511 (2000).
G. Slater, Y. Gratton, M. Kenward, L. McCormick, F. Tessier, Soft Mater. 2, 155 (2004).
R. Delgado-Buscalioni, Phys. Rev. Lett. 96, 088303 (2006).
M. Webster, J. Yeomans, J. Chem Phys. 122, 164903 (2005).
Y. Gratton, G. Slater, Eur. Phys. J. E 17, 455 (2005).
G.O. Ibáñez-García, S. Hanna, Soft Matter 5, 4464 (2009).
Ch.A. Lueth, E. Shaqfeh, Macromolecules 42, 9170 (2009).
Y. Zhang, A. Donev, T. Weisgraber, B. Alder, M. Graham, J.J. de Pablo, J. Chem. Phys. 130, 234902 (2009).
S. Litvinov, X.Y. Hu, N.A. Adams, J. Phys.: Condens. Matter 23, 184118 (2011).
F. Kuhner, Langmuir 22, 1180 (2006).
S. Morris, S. Hanna, M. Miles, Nanotechnology 15, 1296 (2004).
M. Antognozzi, A. Wotherspoon, J. Hayes, M. Miles, Nanotechnology 17, 0957 (2006).
S. Iwao, S. Granick, Langmuir 14, 4266 (1998).
M. Cohen, M. Stuart, Annu. Rev. Mater. Sci. 26, 463 (1996).
A. Panwar, S. Kumar, J. Chem. Phys. 122, 154902 (2005).
N. Hoda, S. Kumar, J. Chem. Phys. 128, 164907 (2008).
G.-L. He, R. Messina, H. Lowen, A. Kirly, V. Bocharova, M. Stammb, Soft Matter 6, 3014 (2009).
G.-L. He, R. Messina, H. Lowen, J. Chem. Phys. 132, 124903 (2010).
A. Serr, R. Netz, Europhys. Lett. 78, 68006 (2007).
R. Netz, D. Andelman, Phys. Rep. 389, 1 (2004).
G. Fleer, Polymers at Interfaces (Chapman&Hall, New York, 1993).
H. Schneider, P. Frantz, S. Granick, Langmuir 12, 994 (1996).
R. Descas, J. Sommer, A. Blumen, J. Chem. Phys. 120, 8831 (2004).
K. De Bell, T. Lookman, Rev. Mod. Phys. 150, 832 (2004).
E. Eisenriegler, Polymers near Surfaces (World Scientific, River Edge, New York, 1993).
R. Descas, J. Sommer, A. Blumen, J. Chem. Phys. 124, 094701 (2006).
Y. Marciano, F. Brochard-Wyart, Macromolecules 28, 985 (1995).
A. Serr, C. Sendner, F. Muller, T.R. Einert, R. Netz, EPL. 92, 39002 (2010).
P. Flory, Statistical Mechanics of Chain Molecules (Oxford University Press, New York, 1989).
L. Li, R. Larson, J. Rheol. 44, 291 (2000).
R. Larson, J. Rheol. 49, 1 (2005).
H.R. Warner Jr., Ind. Eng. Chem. Fund. 11, 379 (1972).
C.W. Gardiner, Handbook of Stochastic Methods (Springer, New York, 1985).
R.M. Jendrejack, J.J. de Pablo, M.D. Graham, J. Chem. Phys. 116, 7752 (2002).
F. Luettmer-Strathmann, F. Rampf, W. Paul, K. Binder, J. Chem. Phys. 128, 064903 (2008).
E. Eisenriegler, K. Kremer, K. Binder, J. Chem. Phys. 7, 12 (1982).
B. Bird, C. Curtis, C. Armstrong, O. Hassager, Dynamics of polymeric liquids: Volume II Kinetic Theory (Wiley-Interscience and Sons, New York, 1987).
Ch.M. Chroeder, R.E. Teixiera, E. Shaqfeh, S. Chu, Phys. Rev. Lett. 95, 018301 (2005).
G.O. Ibáñez-García, Ph.D Thesis (University of Bristol, 2010).
G.O. Ibáñez-García, in preparation.
J. Hatfield, S. Quake, Phys Rev. Let. 82, 3548 (1999).
R. Delgado-Buscalioni, P.V. Coveney, Physica A 362, 30 (2006).
F. Kunher, M. Erdmann, H. Gaub, Phys. Rev. Lett. 97, 218301 (2006).
H. Li, Ch.Qian, M.b. Luo, J. Appl. Polym. Sci. 124, 282 (2012).
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Ibáñez-García, G.O., Goldstein, P. & Hanna, S. Brownian dynamics simulations of confined tethered polymers in shear flow: the effect of attractive surfaces. Eur. Phys. J. E 36, 56 (2013). https://doi.org/10.1140/epje/i2013-13056-5
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DOI: https://doi.org/10.1140/epje/i2013-13056-5