Skip to main content
Log in

Molecular orientation effects in gas-surface dynamical processes

  • Regular Article
  • Published:
The European Physical Journal B Aims and scope Submit manuscript

Abstract

We report studies of chemical reactions on single crystalline Si surfaces induced by oriented molecular beams. We discuss the obtained steric effects on Si from the viewpoint of the strength of the gas-surface interaction, in comparison with the steric effects appearing on the graphite surface. Oriented molecular beams demonstrate the possibility for controlling surface chemical reactions by varying the orientation of the incident molecules. The steric effects found on Si surfaces hint at new ways of material fabrication on Si surfaces.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. E.W. Kuipers, M.G. Tenner, A.W. Kleyn, S. Stolte, Nature 334, 420 (1988)

    Article  ADS  Google Scholar 

  2. M.G. Tenner, E.W. Kuipers, A.W. Kleyn, S. Stolte, J. Chem. Phys. 89, 6552 (1988)

    Article  ADS  Google Scholar 

  3. F.H. Geuzebroek, A.E. Wiskerke, M.G. Tenner, A.W. Kleyn, S. Stolte, A. Namiki, J. Phys. Chem. 95, 8409 (1991)

    Article  Google Scholar 

  4. M.G. Tenner, E.W. Kuipers, A.W. Kleyn, S. Stolte, Surf. Sci. 242, 376 (1991)

    Article  ADS  Google Scholar 

  5. A.W. Kleyn, E.W. Kuipers, M.G. Tenner, S. Stolte, J. Chem. Soc. Faraday Trans. 285, 1337 (1989)

    Google Scholar 

  6. D.C. Jacobs, I. Pois, E.W. Kuipers, A.W. Kleyn, L. Schröter, D.H. Zacharias, G. Fecher, M. Volkmer, N. Böwering, B. Pawlitzky, U. Heinzmann, R.D. Levine, K.J. Snowdon, R.N. Dixon, J. Chem. Soc. Faraday Trans. 285, 1357 (1989)

    Google Scholar 

  7. E.W. Kuipers, M.G. Tenner, A.W. Kleyn, S. Stolte, Phys. Rev. Lett. 62, 2152 (1989)

    Article  ADS  Google Scholar 

  8. R.J.W.E. Lahaye, S. Stolte, S. Holloway, A.W. Kleyn, J. Chem. Phys. 104, 8301 (1996)

    Article  ADS  Google Scholar 

  9. A.W. Kleyn, Prog. Surf. Sci. 54, 407 (1997)

    Article  ADS  Google Scholar 

  10. A.J. Komorowski, H. Ternow, R. Razaznejad, B. Berenbak, J.Z. Sexton, I. Zoric, B. Kasemo, B.I. Lundqvist, S. Stolte, A.W. Kleyn, A.C. Kummel, J. Chem. Phys. 117, 8185 (2002)

    Article  ADS  Google Scholar 

  11. B. Berenbak, B. Riedmüller, S. Stolte, A.W. Kleyn, Chem. Phys. 301, 309 (2004)

    Article  ADS  Google Scholar 

  12. G.H. Fecher, N. Böwering, M. Volkmer, B. Pawlitzky, U. Heinzmann, Surf. Sci. 230, L169 (1990)

    Article  Google Scholar 

  13. H. Müller, B. Dierks, F. Hamza, G. Zagatta, G.H. Fecher, N. Böwering, U. Heinzmann, Surf. Sci. 269–270, 207 (1992)

    Article  Google Scholar 

  14. H. Müller, G. Zagatta, M. Brandt, O. Wehmeyer, N. Böwering, U. Heinzmann, Surf. Sci. 307–309, 159 (1994)

    Article  Google Scholar 

  15. M. Brandt, H. Müller, G. Zagatta, O. Wehmeyer, N. Böwering, U. Heinzmann, Surf. Sci. 331–333, 30 (1995)

    Article  Google Scholar 

  16. M. Brandt, H. Müller, G. Zagatta, N. Böwering, U. Heinzmann, Surf. Sci. 352–354, 290 (1996)

    Article  Google Scholar 

  17. M. Brandt, G. Zagatta, N. Böwering, U. Heinzmann, Surf. Sci. 385, 346 (1997)

    Article  ADS  Google Scholar 

  18. M. Brandt, T. Gerber, N. Böwering, U. Heinzmann, Phys. Rev. Lett. 81, 2376 (1998)

    Article  ADS  Google Scholar 

  19. M. Brandt, T. Gerber, F. Kuhlmann, N. Böwering, U. Heinzmann, Surf. Sci. 402–404, 160 (1998)

    Article  Google Scholar 

  20. M. Brandt, F. Kuhlmann, T. Gerber, N. Böwering, U. Heinzmann, Surf. Sci. 439, 49 (1999)

    Article  ADS  Google Scholar 

  21. T.J. Curtiss, R.B. Bernstein, Chem. Phys. Lett. 161, 212 (1989)

    Article  ADS  Google Scholar 

  22. R.S. Mackay, T.J. Curtiss, R.B. Bernstein, Chem. Phys. Lett. 164, 341 (1989)

    Article  ADS  Google Scholar 

  23. R.S. Mackay, T.J. Curtiss, R.B. Bernstein, J. Chem. Phys. 92, 801 (1990)

    Article  ADS  Google Scholar 

  24. T.J. Curtiss, R.S. Mackay, R.B. Bernstein, J. Chem. Phys. 93, 7387 (1990)

    Article  ADS  Google Scholar 

  25. S.I. Ionov, M.E. Lavilla, R.S. Mackay, R.B. Bernstein, J. Chem. Phys. 93, 7406 (1990)

    Article  ADS  Google Scholar 

  26. S.I. Ionov, M.E. Lavilla, R.B. Bernstein, J. Chem. Phys. 93, 7416 (1990)

    Article  ADS  Google Scholar 

  27. S.I. Ionov, R.B. Bernstein, J. Chem. Phys. 94, 1564 (1991)

    Article  ADS  Google Scholar 

  28. D.B. Whitehouse, A.D. Buckingham, R.B. Bernstein, V.A. Cho, R.D. Levine, J. Phys. Chem. 95, 8175 (1991)

    Article  Google Scholar 

  29. I.V. Ionova, S.I. Ionov, R.B. Bernstein, J. Phys. Chem. 95, 8371 (1991)

    Article  Google Scholar 

  30. M. Hashinokuchi, M. Okada, H. Ito, T. Kasai, K. Moritani, Y. Teraoka, Phys. Rev. Lett. 100, 256104 (2008)

    Article  ADS  Google Scholar 

  31. M. Okada, S. Goto, T. Kasai, Phys. Rev. Lett. 95, 176103 (2005)

    Article  ADS  Google Scholar 

  32. M. Okada, S. Goto, T. Kasai, J. Am. Chem. Soc. 129, 10052 (2007)

    Article  Google Scholar 

  33. M. Okada, S. Goto, T. Kasai, J. Phys. Chem. C 112, 19612 (2008)

    Article  Google Scholar 

  34. T. Fukuyama, M. Okada, T. Kasai, J. Phys. Chem. A 113, 14749 (2009)

    Article  Google Scholar 

  35. H. Ito, M. Okada, D. Yamazaki, T. Kasai, J. Phys. Chem. A, in press (2010)

  36. K. Moritani, M. Okada, S. Goto, T. Kasai, J. Vac. Soc. Jpn 46, 692 (2003)

    Google Scholar 

  37. M. Okada, K. Moritani, S. Goto, T. Kasai, Jpn J. Appl. Phys. 44, 8580 (2005)

    Article  ADS  Google Scholar 

  38. M. Okada, M. Hashinokuchi, K. Moritani, T. Kasai, Y. Teraoka, Jpn J. Appl. Phys. 47, 3686 (2008)

    Article  ADS  Google Scholar 

  39. C.H. Townes, A.L. Schawlow, Microwave Spectroscopy (McGraw-Hill, New York, 1955)

    Google Scholar 

  40. P.R. Brooks, Science 193, 11 (1976)

    Article  ADS  Google Scholar 

  41. K.H. Kramer, R.B. Bernstein, J. Chem. Phys. 42, 767 (1965)

    Article  ADS  Google Scholar 

  42. S. Stolte, J. Reuss, H.L. Schwartz, Physica 66, 211 (1973)

    Article  ADS  Google Scholar 

  43. D.H. Parker, R.B. Bernstein, Ann. Rev. Phys. Chem. 40, 561 (1989)

    Article  ADS  Google Scholar 

  44. T. Kasai, K. Kuwata, in Advanced Series in Physical Chemistry edited by K. Liu, A. Wagner (World Scientific, Singapore, 1995), Vol. 6, Chap. 19, p. 842

    Google Scholar 

  45. M.G. Tenner, E.W. Kuipers, W.Y. Langhout, A.W. Kleyn, G. Nicolasen, S. Stolte, Surf. Sci. 236, 151 (1990)

    Article  ADS  Google Scholar 

  46. E.G. Rochow, J. Am. Chem. Soc. 67, 963 (1945)

    Article  Google Scholar 

  47. T.C. Frank, J.L. Falconer, Langmuir 1, 104 (1985)

    Article  Google Scholar 

  48. M.J. Bronikowski, R.J. Hamers, J. Vac. Sci. Technol. A 13, 777 (1995)

    Article  ADS  Google Scholar 

  49. M.L. Colaianni, P.J. Chen, H. Gutleben, J.T. Yates Jr., Chem. Phys. Lett. 191, 561 (1992)

    Article  ADS  Google Scholar 

  50. K.A. Brown, W. Ho, Surf. Sci. 338, 111 (1995)

    Article  ADS  Google Scholar 

  51. J.Y. Lee, S. Kim, Surf. Sci. 482–485, 196 (2001)

    Article  Google Scholar 

  52. A. Woelke, S. Imanaka, S. Watanabe, S. Goto, M. Hashinokuchi, M. Okada, T. Kasai, J. Electron Microscopy 54 Supplement 1, i21 (2005)

    Article  Google Scholar 

  53. M. Nagao, H. Umeyama, K. Mukai, Y. Yamashita, J. Yoshinobu, K. Akagi, S. Tsuneyuki, J. Am. Chem. Soc. 126, 9922 (2004)

    Article  Google Scholar 

  54. W. Mönch, Semiconductor Surfaces and Interfaces (Springer, Berlin, 1993)

    Google Scholar 

  55. A.H. Romero, C. Sbraccia, P.L. Silvestrelli, F. Ancilotto, J. Chem. Phys. 119, 1085 (2003)

    Article  ADS  Google Scholar 

  56. M. Preuss, W.G. Schmidt, F. Bechstedt, J. Phys. Chem. B 108, 7809 (2004)

    Article  Google Scholar 

  57. M. Preuss, W.G. Schmidt, K. Seino, F. Bechstedt, Appl. Surf. Sci. 234, 155 (2004)

    Article  ADS  Google Scholar 

  58. A. Groß, Theoretical Surface Science (Springer, Berlin, 2002)

    Google Scholar 

  59. A. Gerbi, L. Savio, L. Vattuone, F. Pirani, D. Cappelletti, M. Rocca, Angwev. Chem. Int. Ed. 45, 6655 (2006)

    Article  Google Scholar 

  60. D.J.D. Sullivan, H.C. Flaum, A.C. Kummel, J. Phys. Chem. 97, 12051 (1993)

    Article  Google Scholar 

  61. W.H. Weinberg, Dynamics of Gas-Surface Interactions, in Advances in Gas-Phase Photochemistry and Kinetics edited by C.T. Rettner, M.N.R. Ashfold (Royal Society of Chemistry, Cambridge, 1991), p. 171

    Google Scholar 

  62. J. Wilkes, C.L.A. Lamont, L. Siller, J.M. Coquel, R.E. Palmer, Surf. Sci. 390, 237 (1997)

    Article  ADS  Google Scholar 

  63. R. Küster, K. Chritmann, Ber. Bunsenges. Phys. Chem. 101, 1799 (1997)

    Google Scholar 

  64. P. Gupta, C.H. Mak, P.A. Coon, S.M. George, Phys. Rev. B 40, 7739 (1989)

    Article  ADS  Google Scholar 

  65. A.G. Schrott, S.C. Fain, Jr., Surf. Sci. 111, 39 (1981)

    Article  ADS  Google Scholar 

  66. W.H. Weinberg, in Kinetics of Interface Reactions edited by M. Grunze, H.J. Kreuzer (Springer, New York, 1987), p. 94

    Google Scholar 

  67. C.E. Brown, P.G. Hall, J. Colloid and Interface Sci. 42, 334 (1973)

    Article  Google Scholar 

  68. Z.C. Ying, W. Ho, J. Chem. Phys. 91, 2689 (1989)

    Article  ADS  Google Scholar 

  69. C.W. Muhlhausen, L.R. Williams, J.C. Tully, J. Chem. Phys. 83, 2594 (1985)

    Article  ADS  Google Scholar 

  70. Z. Su, X. Lu, Q.N. Zhang, Chem. Phys. Lett. 375, 106 (2003)

    Article  ADS  Google Scholar 

  71. H. Müller, G. Zagatta, N. Bowering, U. Heinzmann, Chem. Phys. Lett. 223, 197 (1994)

    Article  ADS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to M. Okada.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Okada, M., Kasai, T. Molecular orientation effects in gas-surface dynamical processes. Eur. Phys. J. B 75, 71–79 (2010). https://doi.org/10.1140/epjb/e2010-00045-2

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1140/epjb/e2010-00045-2

Keywords

Navigation