Abstract.
Two-level electron-phonon systems with reflection symmetry linearly coupled to one or two phonon modes (exciton and E \(\otimes(b_1 + b_2)\) Jahn-Teller model) exhibit strong enhancement of quantum fluctuations of the phonon coordinates and momenta due to the complex interplay of quantum fluctuations and nonlinearities inherent to the models. We show that for the complex correlated quantum fluctuations of the anisotropic two-level systems the Shannon entropies of phonon coordinate and momentum and their sum yield their proper global description. On the other hand, the variance measures of the Heisenberg uncertainties suffer from several shortcomings to provide proper description of the fluctuations. Wave functions, related entropies and variances were determined by direct numerical simulations. Illustrative variational calculations were performed to demonstrate the effect on an analytically tractable exciton model.
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It is worth noting that the problem mentioned arises in more general context, namely within the realm of descriptive statistics. The conventional parametric statistics which is based on momenta estimation often fails to represent adequately the characteristics of nonuniform data and sometimes it leaves the scene in favour to the “nonparametric statistics” As the simplest example, consider the ordinary mean (first momentum) \(\int x p(x) d x\) of a strongly asymmetric distribution function. Within the nonparametric statistics in order to characterize intuitive notion of the “distribution center” it is common to use the median, or \(1/2\)-quantile instead of the mean value
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Received: 22 September 2003, Published online: 20 April 2004
PACS:
71.38.-k Polarons and electron-phonon interactions - 63.70. + h Statistical mechanics of lattice vibrations and displacive phase transitions - 02.50.-r Probability theory, stochastic processes and statistics
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Majerníková, E., Majerník, V. & Shpyrko, S. Entropic uncertainty measure for fluctuations in two-level electron-phonon models. Eur. Phys. J. B 38, 25–35 (2004). https://doi.org/10.1140/epjb/e2004-00095-y
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DOI: https://doi.org/10.1140/epjb/e2004-00095-y