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Preparation, magnetoresistance and magnetocaloric effect of two-layered perovskite La 2.5- xK 0.5+ xMn 2O 7+δ

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Abstract:

Polycrystalline two-layered perovskite La2.5-xK0.5+xMn2O 7 + δ (0 < x < 0.5) samples have been prepared by a modified sol-gel method and their magnetoresistance and magnetocaloric effects have been studied. A large deviation between the metal-insulator (MI) transition temperature (T ρ ) and the magnetic transition temperature (TC) is observed. Large magnetoresistance (MR) effects with Δρ/ρ of 40% at 12 kOe are obtained in wide temperature ranges. The maximum of the magnetic entropy change peaks at its Curie temperature (TC), far above its MI transition temperature (T ρ ). The large magnetic entropy change (1.4 J/kg.K) is obtained in the sample La2.5-xK0.5+xMn2O 7 + δ (x = 0.35) upon 10 kOe applied magnetic field.

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Received 2 May 2002 / Received in final form 1st October 2002 Published online 19 December 2002

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ID="a"e-mail: wzhong@ufp.nju.edu.cn

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Zhong, W., Chen, W., Jiang, H. et al. Preparation, magnetoresistance and magnetocaloric effect of two-layered perovskite La 2.5- xK 0.5+ xMn 2O 7+δ . Eur. Phys. J. B 30, 331–337 (2002). https://doi.org/10.1140/epjb/e2002-00386-3

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  • DOI: https://doi.org/10.1140/epjb/e2002-00386-3

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