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Metal compound nanoparticles: Flame retardants for polymer composites

  • Selected articles originally published in Russian in Rossiiskii Khimicheskii Zhurnal (Russian Chemistry Journal)
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Abstract

Nanoparticles of metal compounds (zinc oxide, zinc borate, magnesium hydroxide, and layered double hydroxides) were shown to be effective flame retardants for polymers. Fillers can be used either in the pure form or as synergistic additives to phosphorus-containing flame retardants. The influence of the particle size on the flame-retardant properties of plasticized polyvinyl alcohol and polymethylmethacrylate was demonstrated.

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References

  1. Aseeva, R.M. and Zaikov, E.G., Gorenie polimernykh materialov (Combustion of Polymer materials), Moscow: Nauka, 1981.

    Google Scholar 

  2. Kodolov, V.I., Goryuchest’ i ognestoikost’ polimernykh materialov (Combustibility and Fire Resistance of Polymer Materials), Moscow: Khimiya, 1976.

    Google Scholar 

  3. Weil, E.D. and Levchik, S.V., J. Fire Sci., 2008, vol. 26, p. 5.

    Article  CAS  Google Scholar 

  4. Polymer Green Flame Retardants, Papaspyrides, C.D. and Kiliaris, P., Eds., Oxford: Elsevier, 2014.

  5. Taguet, A., Cassagnau, P., and Lopez-Cuesta, J.-M., Prog. Polymer Sci., 2014, vol. 39, p. 1526. doi org/10.1016/j.progpolymsci.2014.04.002

    Article  CAS  Google Scholar 

  6. Kumar, A.P., Depan, D., and Tomer, N.S., Prog. Polymer Sci., 2009, vol. 34, p. 479. doi org/10.1016/j.progpolymsci.2009.01.002

    Article  CAS  Google Scholar 

  7. Alarie, Y., Crit. Rev. Toxicol., 2002, vol. 32, p. 259. doi org/10.1080/20024091064246

    Article  CAS  Google Scholar 

  8. Paabo, M.A. and Levin, B.C., Fire Mater., 1987, vol. 11, p. 55.

    Article  CAS  Google Scholar 

  9. Stefanidou, M., Athanazelis, S., and Spillopoulou, C., Inhal. Toxicol., 2008, vol. 20, p. 761. doi org/10.1080/08958370801975311

    Article  CAS  Google Scholar 

  10. Fire Retardancy of Polymer Materials, Wilkie, C.A. and Morgan, A.B., Eds., Boca Raton: CRC, 2010.

  11. Costa, L.G. and Giordano, G., Neurotoxicology, 2007, vol. 28, p. 1047. doi org/10.1016/j.neuro.2007.08.007

    Article  CAS  Google Scholar 

  12. Reistad, T., Mariussen, E., Ring, A., and Fonnum, F., Toxicol. Sci., 2007, vol. 96, p. 268. doi org/10.1093/toxsci/kfl198

    Article  CAS  Google Scholar 

  13. Talsness, C.E., Env. Res., 2008, vol. 108, p. 158. doi org/10.1016/j.envres.2008.08.008

    Article  CAS  Google Scholar 

  14. Green, J., in Fire Retardancy of Polymer Materials, Grand, A.F. and Wilkie, C.A., Eds., New York: Marcel Dekker, 2000, p. 147.

  15. Zubkova, N.S., Butylkina, N.G., and Gal’braikh, L.S., Fibre Chem., 1999, no. 4, p. 263.

    Article  Google Scholar 

  16. Khalturinskii, N.A., Russ. Chem. Rev., 1984, no. 2, p. 197.

    Article  Google Scholar 

  17. Plotnikova, G.V., Egorov, A.N., Khaliullin, A.K., Malysheva, S.F, and Shaikhudinova, S.I., Plast. Massy, 2002, no. 11, p. 25.

    Google Scholar 

  18. Grassie, N. and Scott, G., Polymer Degradation and Stabilisation, Cambridge: Cambridge Univ. Press, 1985.

    Google Scholar 

  19. Tesoro, G.C., Macromol. Rev., 1978, vol. 13, p. 283.

    Article  CAS  Google Scholar 

  20. Saladino, M.L., Motaung, T.E., Luyt, A.S., Spinella, A., Nasillo, G., and Caponetti, E., Polym. Degrad. Stab., 2012, vol. 97, p. 452. doi org/10.1016/j.polymdegradstab.2011.11.006

    Article  Google Scholar 

  21. Vahabi, H., Ferry, L., Longuet, C., Otazaghine, B., Negrell-Guirao, C., David, G., and Lopez-Cuesta, J.-M., Mater. Chem. Phys., 2012, vol. 136, p. 762. doi org/10.1016/j.matchemphys.2012.07.053

    Article  CAS  Google Scholar 

  22. Minsker, K.S. and Fedoseeva, G.T., Destruktsiya i stabilizatsiya polivinilkhlorida (Polyvinylchloride Degradation and Stabilization), Moscow: Khimiya, 1972.

    Google Scholar 

  23. Hornsby, P.R., Fire Mater., 1994, vol. 18, p. 269.

    Article  CAS  Google Scholar 

  24. Kodolov, V.I., Zamedliteli goreniya polimernykh materialov (Flame Retardants for Polymer Materials), Moscow: Khimiya, 1980.

    Google Scholar 

  25. Hull, T.R, Witkowski, A., and Hollingbery, L., Polymer Degrad. Stab., 2011, vol. 96, p. 1462. doi org/10.1016/j.polymdegradstab.2011.05.006

    Article  CAS  Google Scholar 

  26. Yi, D., Yang, R., and Wilkie, C.A., Polymer Degrad. Stab., 2014, vol. 105, p. 31. doi org/10.1016/j.polymdegradstab.2014.03.042

    Article  CAS  Google Scholar 

  27. Lv, J., Qie, L., and Qu, B., Nanotechnology, 2004, vol. 15, p. 1576.

    Article  Google Scholar 

  28. Gallo, E., Schartel, B., Acierno, D., and Russo, P., Polymer Degrad. Stab., 2010, vol. 95, p. 1183. doi org/10.1016/j.polymdegradstab.2010.04.008

    Article  Google Scholar 

  29. Cui, Y., Liu, X., Tian, Y., Ding, N., and Wang, Z., Colloids Surf.: A, 2012, vol. 414, p. 274. doi org/10.1016/j.colsurfa.2012.08.028

    Article  CAS  Google Scholar 

  30. Mergen, A., Ipek, Y., Bölek, H., and Öksüz, M., J. Eur. Ceram. Soc., 2012, vol. 32, p. 2001. doi org/10.1016/j.jeurceramsoc.2011.10.034

    Article  CAS  Google Scholar 

  31. Baltaci, B., Çaka, G.Ö., Bayram, G., Eroglu, I., and Özkar, S., Powder Technol., 2013, vol. 244, p. 38. doi org/10.1016/j.powtec.2013.04.006

    Article  CAS  Google Scholar 

  32. Li, S., Long, B., Wang, Z., Tian, Y., Zheng, Y., and Zhang, Q., J. Solid State Chem., 2010, vol. 183, p. 957. doi org/10.1016/j.jssc.2010.02.017

    Article  CAS  Google Scholar 

  33. Witkowski, A., Stec, A.A, and Hull, T.R., Polymer Degrad. Stab., 2012, vol. 97, p. 231.

    Article  Google Scholar 

  34. Jiao, C.M., Wang, Z.Z., Ye, Z., Hu, Y., and Fan, W.C., J. Fire Sci., 2006, vol. 24, p. 47.

    Article  CAS  Google Scholar 

  35. Fomin, D.L and Deberdeev, R.Ya., Plast. Massy, 2012, no. 12, p. 47.

    Google Scholar 

  36. Sertsova, A.A., Koroleva, M.Yu., Yurtov, E.V., Pravednikova, O.B., Dutikova, O.S., and Gal’braikh, L.S., Khim. Tekhnol., 2009, no. 12, p. 706.

    Google Scholar 

  37. Mishra, S., Sonawane, S.H., Singh, R., Bendale, A., and Patil, K., J. Appl. Polym. Sci., 2004, vol. 94, p. 116. doi 10.1002/app. 20750

    Article  CAS  Google Scholar 

  38. Si, M., Feng, J., Hao, J., Xu, L., and Du, J., Polymer Degrad. Stab., 2014, vol. 100, p. 70. doi org/10.1016/j.polymdegradstab.2013.12.023

    Article  CAS  Google Scholar 

  39. Gallo, E., Schartel, B., Acierno, D., and Russo, P., Eur. Polym. J., 2011, vol. 47, p. 1390. doi org/10.1016/j.eurpolymj.2011.04.001

    Article  CAS  Google Scholar 

  40. Pravednikova, O.B., Dutikova, O.S., Koroleva, M.Yu., Sertsova, A.A., Karelina, I.M., Gal’braikh, L.S., and Yurtov, E.V., Fibre Chem., 2009, no. 2, p. 80. doi 10.1007/s10692-009-9151-9

    Article  Google Scholar 

  41. Sertsova, A.A., Subcheva, E.N., and Yurtov, E.V., Russ. J. Inorg. Chem., 2015, vol. 60, no. 1, p. 23. doi 10.1134/S0036023615010167

    Article  CAS  Google Scholar 

  42. Wang, L., Su, S., Chen, D., and Wilkie, C.A., Polymer Degrad. Stab., 2009, vol. 94, p. 770. doiorg/10.1016/j.polymdegradstab.2009.02.003

    Article  CAS  Google Scholar 

  43. Velasco, J.I., Ardanuy, M., and Antunes, M., Adv. Polym. Nanocomp., 2012, p. 91–130.

    Book  Google Scholar 

  44. Bergaya, F. and Lagaly, G., Handbook of Clay Science, Amsterdam: Elsevier, 2006.

    Google Scholar 

  45. GOST (State Standard) 21207–81: Plastics: Methods for Determination of Flammability.

  46. GOST 19932–99: Petroleum Products: Determination of Carbon Residue: Conradson Method.

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Correspondence to A. A. Sertsova.

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Original Russian Text © A.A. Sertsova, S.I. Marakulin, E.V. Yurtov, 2015, published in Rossiiskii Khimicheskii Zhurnal, 2015, Vol. 59, No. 3, pp. 78–85.

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Sertsova, A.A., Marakulin, S.I. & Yurtov, E.V. Metal compound nanoparticles: Flame retardants for polymer composites. Russ J Gen Chem 87, 1395–1402 (2017). https://doi.org/10.1134/S1070363217060421

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  • DOI: https://doi.org/10.1134/S1070363217060421

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