Skip to main content
SpringerLink
Log in

Phase composition and catalytic properties of ZrO2 and CeO2-ZrO2 in the ketonization of pentanoic acid to 5-nonanone

  • Published:
Kinetics and Catalysis Aims and scope Submit manuscript

Abstract

The phase composition, microstructure, and catalytic properties of the samples of ZrO2 and CeO2-ZrO2 calcined in air at 450–500°C in the ketonization reaction of pentanoic acid were studied. It was found that ZrO2 of tetragonal and monoclinic modifications is characterized by sufficiently high activity and selectivity for 5-nonanone; the yield of 5-nonanone was 66.3–64.9%. The modification of zirconium dioxide with cerium oxide leads to the formation of a substitutional solid solution based on tetragonal ZrO2. Upon the addition of CeO2 in an optimum amount of 10 wt % to zirconium dioxide, an increase in the conversion of pentanoic acid was observed with the retention of high selectivity for the target product, which led to an increase in the yield of 5-nonanone to 73.3%. Based on the results of physicochemical studies performed by high-resolution transmission electron microscopy, X-ray diffraction analysis, and X-ray photoelectron spectroscopy, the physicochemical and catalytic properties of the test catalysts were compared.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Deng, L., Li, J., Lai, D.M., Fu, Y., and Guo, Q.X., Angew. Chem. Int. Ed., 2009, vol. 48, p. 6529.

    Article  CAS  Google Scholar 

  2. Serrano-Ruiz, J.C., Wang, D., and Dumesic, J.A., Green Chem., 2010, vol. 12, p. 574.

    Article  CAS  Google Scholar 

  3. Leung, A., Boocock, D.G.B., and Konar, S.K., Energy Fuels, 1995, vol. 9, p. 913.

    Article  CAS  Google Scholar 

  4. Glinski, M. and Kijenski, J., React. Kinet. Catal. Lett., 2000, vol. 69, p. 123.

    Article  CAS  Google Scholar 

  5. Patent 2001094522 WO, 2001.

  6. German Patent 19958521, 2001.

  7. Hwang, Y.L. and Bedard, T.C., Kirk-Othmer Encyclopedia of Chemical Technology, New Jersey: Wiley, 2001.

    Google Scholar 

  8. Partel, A.D., Serrano-Ruiz, J.C., Dumesic, J.A., and Anex, R.P., Chem. Eng. J., 2010, vol. 160, p. 311.

    Article  Google Scholar 

  9. Tsybulya, S.V., Cherepanova, S.V., and Solov’eva, L.P., J. Struct. Chem., 1996, vol. 37, no. 2, p. 332.

    Article  Google Scholar 

  10. Young, R.A., The Rietveld Method, Oxford: Oxford Univ. Press, 1995.

    Google Scholar 

  11. Scofield, J.H., J. Electron Spectrosc. Relat. Phenom., 1976, vol. 8, p. 129.

    Article  CAS  Google Scholar 

  12. ASTM Diffraction Data Cards and Alphabetical and Grouped Numerical Index of X-Ray Diffraction Data, Philadelphia: ASTM, 1967.

  13. Zenkovets, G.A., Shutilov, A.A., Gavrilov, V.Yu., Tsybulya, S.V., and Kryukova, G.N., Kinet. Catal., 2007, vol. 48, no. 5, p. 742.

    Article  CAS  Google Scholar 

  14. Kaspar, J. and Fornasiero, P., in Catalysis by Ceria and Related Materials, Trovarelli, A., Ed., London: Imperial College Press, 2002, vol. 2, p. 217.

  15. Kataliticheskie svoistva veshchestv: Spravochnik (Catalytic Properties of Substances: A Handbook), Roiter, V.A., Ed., Kiev: Naukova Dumka, 1968.

    Google Scholar 

  16. Catalysis by Ceria and Related Materials, Trovarelli, A., Ed., London: Imperial College Press, 2002, vol. 2, p. 508.

    Google Scholar 

  17. Handbook of X-Ray Photoelectron Spectroscopy, Moulder, J.F., Stickle, W.F., and Sobol, P.E., Eds., Eden Prairie, Minn.: PerkinElmer, 1979.

    Google Scholar 

  18. Handbook of X-Ray Photoelectron Spectroscopy, Chastain, J., Ed., Eden Prairie, Minn.: PerkinElmer, 1992, p. 242.

    Google Scholar 

  19. Park, P.W. and Ledford, J.S., Langmuir, 1996, vol. 12, p. 1794.

    Article  CAS  Google Scholar 

  20. Hardacre, C., Roe, G.M., and Lambert, R.M., Surf. Sci., 1995, vol. 326, p. 1.

    Article  CAS  Google Scholar 

  21. Golodets, G.I., Geterogenno-kataliticheskoe okislenie organicheskikh veshchestv (Heterogeneous Catalytic Oxidation of Organic Compounds), Kiev: Naukova Dumka, 1978.

    Google Scholar 

  22. Golodets, G.I., Theor. Exp. Chem., 1982, vol. 18, no. 1, p. 27.

    Article  Google Scholar 

  23. Herniman, H.J. and Pyke, D.R., J. Catal., 1979, vol. 58, no. 1, p. 52.

    Article  Google Scholar 

  24. Curtufello, M.G., Ferino, I., Solinas, V., Primavera, A., Trovarelli, A., Auroux, A., and Picciau, C., Phys. Chem. Chem. Phys., 1999, vol. 1, p. 3369.

    Article  Google Scholar 

  25. Tanabe, K. and Yamaguchi, T., Catal. Today, 1994, vol. 20, p. 185.

    Article  CAS  Google Scholar 

  26. Rajadurai, S., Catal. Rev. Sci. Eng., 1994, vol. 36, p. 385.

    Article  CAS  Google Scholar 

  27. Nagashima, O., Sato, S., Takahashi, R., and Sodesawa, T., J. Mol. Catal. A: Chem., 2005, vol. 227, p. 231.

    Article  CAS  Google Scholar 

  28. Pestman, R., Koster, R.M., van Duijne, A., Pieters, J.A.Z., and Ponec, V., J. Catal., 1997, vol. 168, p. 265.

    Article  CAS  Google Scholar 

  29. Godovikov, A.A., Orbital’nye radiusy i svoistva elementov (Orbital Rdii and Properties of Elements), Novosibirsk: Nauka, 1977.

    Google Scholar 

  30. Energii razryva khimicheskikh svyazei. Potentsialy ionizatsii i srodstvo k elektronu: Spravocnik (Bond Dissociation Energies, Ionization Potentials, and Ellectron Affinity; A Handbook), Kondrat’ev, V.N., Ed., Moscow: Nauka, 1974.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, Novosibirsk, 630090, Russia

    A. A. Shutilov, M. N. Simonov, Yu. A. Zaytseva, G. A. Zenkovets & I. L. Simakova

Authors
  1. A. A. Shutilov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. M. N. Simonov
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Yu. A. Zaytseva
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. G. A. Zenkovets
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. I. L. Simakova
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to A. A. Shutilov.

Additional information

Original Russian Text © A.A. Shutilov, M.N. Simonov, Yu.A. Zaytseva, G. A. Zenkovets, I.L. Simakova, 2013 published in Kinetika i Kataliz, 2013, Vol. 54, No. 2, pp. 193–201.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Shutilov, A.A., Simonov, M.N., Zaytseva, Y.A. et al. Phase composition and catalytic properties of ZrO2 and CeO2-ZrO2 in the ketonization of pentanoic acid to 5-nonanone. Kinet Catal 54, 184–192 (2013). https://doi.org/10.1134/S0023158413020134

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0023158413020134

Keywords

Search

Navigation