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Kinetics of the reactions of tert-butanol with C2-C5 alcohols on sulfo cation exchangers

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Abstract

The kinetics of etherification of tert-butanol with aliphatic alcohols on gel KU-2×8 and macroporous KU-23 sulfo cation exchangers was studied. The first order of reaction with respect to tert-butanol and the -CSO3H groups of a catalyst was established. The activation energy of the process observed on KU-2×8 was 60–95 kJ/mol. It was shown that the etherification of tert-butanol on KU-2×8 occurred in a surface layer. The reactivity of primary alcohols introduced into the reaction with tert-butanol increased with their molecular weights (C2–C5). The rate of reaction with secondary alcohols was lower than that with primary alcohols.

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Authors and Affiliations

  1. Togliatti State University, Togliatti, 445667, Russia

    A. A. Golovanov, V. S. Pisareva & M. V. Levshenkov

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  1. A. A. Golovanov
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  2. V. S. Pisareva
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  3. M. V. Levshenkov
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Correspondence to A. A. Golovanov.

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Original Russian Text © A.A. Golovanov, V.S. Pisareva, M.V. Levshenkov, 2013, published in Kinetika i Kataliz, 2013, Vol. 54, No. 2, pp. 188–192.

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Golovanov, A.A., Pisareva, V.S. & Levshenkov, M.V. Kinetics of the reactions of tert-butanol with C2-C5 alcohols on sulfo cation exchangers. Kinet Catal 54, 179–183 (2013). https://doi.org/10.1134/S0023158413020067

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