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Cryoozonolysis of Some Perfluoroolefins and Use of Perfluoro Ozonides as Polymerization Initiators

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Abstract

Low-temperature (77-280 K) ozonolysis of perfluoro-4-methyl-2-pentene and perfluoro-2,4-dimethyl-3-ethyl-2-pentene by direct contact with ozone in the absence of solvents and oxygen was studied. The resulting perfluoro ozonides can be used as initiators of low-temperature polymerization and copolymerization.

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Authors and Affiliations

  1. Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow oblast, Russia

    D. P. Kiryukhin, I. M. Barkalov & I. L. Ismoilov

Authors
  1. D. P. Kiryukhin
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  2. I. M. Barkalov
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  3. I. L. Ismoilov
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Kiryukhin, D.P., Barkalov, I.M. & Ismoilov, I.L. Cryoozonolysis of Some Perfluoroolefins and Use of Perfluoro Ozonides as Polymerization Initiators. Russian Journal of Applied Chemistry 74, 1740–1743 (2001). https://doi.org/10.1023/A:1014829924249

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  • DOI: https://doi.org/10.1023/A:1014829924249

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