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Effect of sintering temperature on the microstructure and properties of foamed glass-ceramics prepared from high-titanium blast furnace slag and waste glass

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Abstract

Foamed glass-ceramics were prepared via a single-step sintering method using high-titanium blast furnace slag and waste glass as the main raw materials The influence of sintering temperature (900–1060°C) on the microstructure and properties of foamed glass-ceramics was studied. The results show that the crystal shape changed from grainy to rod-shaped and finally turned to multiple shapes as the sintering temperature was increased from 900 to 1060°C. With increasing sintering temperature, the average pore size of the foamed glass-ceramics increased and subsequently decreased. By contrast, the compressive strength and the bulk density decreased and subsequently increased. An excessively high temperature, however, induced the coalescence of pores and decreased the compressive strength. The optimal properties, including the highest compressive strength (16.64 MPa) among the investigated samples and a relatively low bulk density (0.83 g/cm3), were attained in the case of the foamed glass-ceramics sintered at 1000°C.

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References

  1. J. König, R.R. Petersen, and Y.Z. Yue, Fabrication of highly insulating foam glass made from CRT panel glass, Ceram. Int., 41(2015), No. 8, p. 9793.

    Article  Google Scholar 

  2. M. Reben, M. Kosmal, M. Ziabka, P. Pichniarczyk, and I. Grelowska, The influence of TiO2 and ZrO2 on microstructure and crystallization behavior of CRT glass, J. Non-Cryst. Solids, 425(2015), No. 10, p. 118.

    Article  Google Scholar 

  3. M.G. Zhu, R. Ji, Z.M. Li, H. Wang, L.L. Liu, and Z.T. Zhang, Preparation of glass ceramic foams for thermal insulation applications from coal fly ash and waste glass, Constr. Build. Mater., 112(2016), No. 1, p. 398.

    Article  Google Scholar 

  4. E. Bernardo, G. Scarinci, P. Bertuzzi, P. Ercole, and L. Ramon, Recycling of waste glasses into partially crystallized glass foams, J. Porous Mater., 14(2010), No. 3, p. 359.

    Article  Google Scholar 

  5. E. Bernardo and F. Albertini, Glass foams from dismantled cathode ray tubes, Ceram. Int., 32(2006), No. 6, p. 603.

    Article  Google Scholar 

  6. J.G. Bai, X.H. Yang, S.C. Xu, W.J. Jing, and J.F. Yang, Preparation of foam glass from waste glass and fly ash, Mater. Lett., 136(2014), No. 14, p. 52.

    Article  Google Scholar 

  7. Z. Liu, N.N. Shao, D.M. Wang, J.F. Qin, T.Y. Huang, W. Song, M.X. Lin, J.S. Yuan, and Z. Wang, Fabrication and properties of foam geopolymer using circulating fluidized bed combustion fly ash, Int. J. Miner. Metall. Mater., 21(2014), No. 1, p. 89.

    Article  Google Scholar 

  8. Z. Li, Z.W. Luo, X.Y. Li, T.Y. Liu, L.M. Guan, T. Wu, and A.X. Lu, Preparation and characterization of glass-ceramic foams with waste quartz sand and coal gangue in different proportions, J. Porous Mater., 23(2016), No. 1, p. 231.

    Article  Google Scholar 

  9. H. Sazegaran, A. Kiani-Rashid, and J.V. Khaki, Effects of sphere size on the microstructure and mechanical properties of ductile iron–steel hollow sphere syntactic foams, Int. J. Miner. Metall. Mater., 23(2016), No. 6, p. 676.

    Article  Google Scholar 

  10. B. Chen, K.Q Wang, X.J. Chen, and A.X. Lu, Study of foam glass with high content of fly ash using calcium carbonate as foaming agent, Mater. Lett., 79(2012), No. 8, p. 263.

    Article  Google Scholar 

  11. E. Ercenk, The effect of clay on foaming and mechanical properties of glass foam insulating material, J. Therm. Anal. Calorim., 127(2017), No. 1, p. 137.

    Article  Google Scholar 

  12. H. Shi, K.Q. Feng, H.B. Wang, C.H. Chen, and H.L. Zhou, Influence of aluminium nitride as a foaming agent on the preparation of foam glass-ceramics from high-titanium blast furnace slag, Int. J. Miner. Metall. Mater., 23(2016), No. 5, p. 595.

    Article  Google Scholar 

  13. R. Lebullenger, S. Chenu, J. Rocherullé, O. Merdrignac-Conanec, F. Cheviré, F. Tessier, A. Bouzaza, and S. Brosillon, Glass foams for environmental applications, J. Non-Cryst. Solids, 365(2010), No. 44-49, p. 2562.

    Article  Google Scholar 

  14. P.K. Padhi and A. Satapathy, Analysis of sliding wear characteristics of BFS filled composites using an experimental design approach integrated with ANN, Tribol. Trans., 56(2013), No. 5, p. 789.

    Article  Google Scholar 

  15. N. Sasmal, M. Garai, and B. Karmakar, Preparation and characterization of novel foamed porous glass-ceramics, Mater. Charact., 103(2015), No. 3, p. 90.

    Article  Google Scholar 

  16. Y. Zhao, D.F. Chen, Y.Y. Bi, and M.J. Long, Preparation of low cost glass–ceramics from molten blast furnace slag, Ceram. Int., 38(2012), No. 3, p. 2495.

    Article  Google Scholar 

  17. S. Hasheminia, A. Nemati, B.E. Yekta, and P. Alizadeh, Preparation and characterisation of diopside-based glass–ceramic foams, Ceram. Int., 38(2012), No. 3, p. 2005.

    Article  Google Scholar 

  18. A.R.J. Barbosa, A.A.S. Lopes, S.I.H. Sequeira, J.P. Oliveira, A. Davarpanah, F. Mohseni, V.S. Amaral, and R.C.C. Monteiro, Effect of processing conditions on the properties of recycled cathode ray tube glass foams, J. Porous Mater., 23(2016), No. 6, p. 1663.

    Article  Google Scholar 

  19. A. Goel, D.U. Tulyaganov, S. Agathopoulos, M.J. Ribeiro, and J.M.F. Ferreira, Crystallization behaviour, structure and properties of sintered glasses in the diopside–Ca-Tschermak system, J. Eur. Ceram. Soc., 27(2007), No. 10, p. 3231.

    Article  Google Scholar 

  20. L. Liu, M.L. Hu, C.G. Bai, X.W. Lü, Y.Z. Xu, and Q.Y. Deng, Effect of cooling rate on the crystallization behavior of perovskite in high titanium-bearing blast furnace slag, Int. J. Miner. Metall. Mater., 21(2014), No. 11, p. 1052.

    Article  Google Scholar 

  21. Z.S. Ren, X.J. Hu, X.M. Hou, X.X. Xue, and K.C. Chou, Dissolution and diffusion of TiO2 in the CaO–Al2O3–SiO2 slag, Int. J. Miner. Metall. Mater., 21(2014), No. 4, p. 345.

    Article  Google Scholar 

  22. B.S. Tang, J. Lin, S. Qian, J.D Wang, and S. Zhang, Preparation of glass–ceramic foams from the municipal solid waste slag produced by plasma gasification process, Mater. Lett., 128(2014), No. 8, p. 68.

    Article  Google Scholar 

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Acknowledgments

This work was financially supported by the Science and Technology Support Program of Sichuan Province (No. 2014GZ0011) and the Industry Promotion Project of Panzhihua City, China (No. 2012CY-C-2).

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Correspondence to Ke-qin Feng.

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Chen, Ch., Feng, Kq., Zhou, Y. et al. Effect of sintering temperature on the microstructure and properties of foamed glass-ceramics prepared from high-titanium blast furnace slag and waste glass. Int J Miner Metall Mater 24, 931–936 (2017). https://doi.org/10.1007/s12613-017-1480-8

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  • DOI: https://doi.org/10.1007/s12613-017-1480-8

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