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Effect of monophenyl borate on properties of high-ortho phenolic fibers

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Abstract

A series of monophenyl borate (MPB) modified high-ortho phenolic copolymer fibers (BOPFs) were prepared by melt-spinning of the high-ortho phenol-formaldehyde resins with different content of MPB, and cured in a formaldehyde solution. The solution curing fibers were heated up to 240 °C at elevated temperatures in N2. The effect of MPB on the structure and properties of the BOPFs was investigated by Fourier transform infrared spectrometer (FTIR), nuclear magnetic resonance spectroscopy (NMR), thermogravimetric analysis (TGA) and scanning electron microscope (SEM). The results show that a B-O linkage inserts into the high-ortho phenolic copolymer molecular chain with the addition of MPB, and increases the crosslinkage and thermal stability. The peak of O/P (ortho/para) value of fiber (1.94) and elongation (5.6 %) were obtained when BOPFs-4 was heat-cured at 240 °C for 2 h.

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Authors and Affiliations

  1. School of Materials & Chemical Engineering, Zhongyuan University of Technology, Zhengzhou, 450007, China

    Mingli Jiao, Quan Diao, Dongxue Ren & Jian Cao

  2. School of Fashion, Zhongyuan University of Technology, Zhengzhou, 450007, China

    Kai Yang

  3. Textiles and Paper, School of Materials, University of Manchester, Manchester, M13 9PL, UK

    R. Hugh Gong

Authors
  1. Mingli Jiao
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  2. Kai Yang
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  3. Quan Diao
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  4. R. Hugh Gong
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  5. Dongxue Ren
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  6. Jian Cao
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Correspondence to Kai Yang or Jian Cao.

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Jiao, M., Yang, K., Diao, Q. et al. Effect of monophenyl borate on properties of high-ortho phenolic fibers. Fibers Polym 18, 875–881 (2017). https://doi.org/10.1007/s12221-017-6972-7

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  • DOI: https://doi.org/10.1007/s12221-017-6972-7

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