Abstract
This study investigated toxic metal distribution in roadside soil and dust in the metropolitan city of Ulsan, South Korea, and the factors affecting distribution, using Korean waste-leaching tests, determination of total concentrations, sequential extraction, and statistical analysis. Composite grab samples were collected from high-traffic roads (7 sites), low-traffic roads (2 sites), and an uncontaminated control area (2 sites) in Ulsan. The pH of roadside soil and dust was slightly alkaline. The concentrations of copper, lead, and zinc in soil as determined by Korean waste-leaching tests decreased as soil depth increased, while those of arsenic, nickel, and chromium increased. Leaching concentrations in dust were lower than in soil, with the exception of copper. Total concentrations decreased as soil depth increased, and total concentrations of metals in dust were higher than in soil. The sampling sites that exceeded the regulation levels of soil contamination in South Korea were 7 points in topsoil, 3 points in middle soil, and 9 points in dust. TCLP tests showed that the concentrations of arsenic, cadmium, and lead in topsoil and dust at Duwang and Myeongchon intersections were higher than regulatory levels. The maximum correlation coefficient among two metals in soil and dust was 0.987 (p < 0.01), for cadmium and lead. Concentrations of cadmium, copper, arsenic, lead, nickel, and mercury, mostly from tire and brake-pad abrasion, were highly correlated. The strong positive correlation between traffic volume and metals in dust suggests that vehicle emissions may be responsible for metal contamination of soil and dust. Pollution indices of topsoil at 4 sites and all dust at 7 high-traffic sites were higher than 1.0, which is consistent with an effect of vehicle traffic on metal contamination in soil and dust.
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Ahmad, M., Yu, Q., Chen, J., Cheng, S., Qin, W., & Zhang, Y. (2020). Chemical characteristics, oxidative potential, and sources of PM2.5 in wintertime in Lahore and Peshawar, Pakistan. Journal of Environmental Sciences, 102, 148–158.
Bowen, H. J. M. (1979). Environmental Chemistry of the Element. New York: Academic Press.
Choi, J. Y., Jeon, H., Choi, K. Y., Hong, G. H., Yang, D. B., Kim, K., & Ra, K. (2020). Source identification and implications of heavy metals in urban roads for the coastal pollution in a beach town, Busan, Korea. Marine Pollution Bulletin, 161(A), 111724.
Ellis, J. B., & Revitt, D. M. (1982). Incidence of heavy metals in street surface sediments: Solubility and grain size studies. Water, Air, and Soil Pollution, 17(1), 87–100.
Harrison, R. M., & Wilson, S. J. (1985). The chemical composition of highway drainage waters II. Chemical associations of metals in the suspended sediment. The Science of the Total Environment, 43(1), 79–87.
Harrison, R. M., Laxen, D. P. H., & Wilson, S. J. (1981). Chemical association of lead, cadmium, copper, and zinc in street dusts and roadside soils. Environmental Science and Technology, 15(11), 1378–1383.
Jaishankar, M., Tseten, T., Anbalagan, N., Mathew, B. B., & Beeregowda, K. N. (2014). Toxicity, mechanism and health effects of some heavy metals. Interdisciplinary Toxicology, 7(2), 60–72.
Klöckner, P., Seiwert, B., Eisentraut, P., Braun, U., Reemtsmaa, T., & Wagner, S. (2020). Characterization of tire and road wear particles from road runoff indicates highly dynamic particle properties. Water Research, 185, 116262.
Kloke, A. (1979). Contents of arsenic, cadmium, chromium, fluorine, lead, mercury and nickel in plants grown on contaminated soil. UN-ECE Symposium, Geneva.
Korean Ministry of Environment. (2009). Enforcement Decree of the Soil Environment Act. Ministry Decree No. 333. Korea Ministry of Environment, Seoul (Written in Korean).
LaGrega, M., Buckingham, P., & Evans, J. (2000). Hazardous Waste Management (2nd ed.). McGraw-Hill.
Lee, E. S. (2004). A study on heavy metal pollution of highway roadside sediments. Seoul Studies, 5(4), 61–72.
Lee, P. K., & Touray, J. C. (1998). Characteristics of a polluted artificial soil located along a motorway and effects of acidification on the leaching behavior of heavy metals (Pb, Zn, Cd). Water Research, 32(11), 3425–3435.
Lee, P. K., Baillif, P., Touray, J. C., & Ildefonse, J. P. (1997). Heavy metal contamination of settling particles in a retention pond along the A-71 Motorway in Sologne, France. The Science of the Total Environment, 201(1), 1–15.
Lee, J. J., Park, Y. S., Kim, J. K., & Han, M. S. (2007). Pollution characteristics of hazardous elements for roadside dust in Gwangju City, Korea. Journal of Korean Society of Economic and Environmental Geology, 40(3), 263–275.
Lee, J. S., Baek, S. W., Son, H. J., Kang, D. S., Yun, H. J., Lee, J. Y., Jeong, S. G., & Ham, Y. S. (2011). A study on behavior characteristics and distribution of contaminated roadside sediments in Ulsan area. The annual report of Ulsan Metropolitan City Institute of Health & Environment, 6, 121–177.
Pierson, W. R., & Brachaczek, W. W. (1982). Particulate matter associated with vehicles on the road. II. Aerosol Science and Technology, 2(1), 1–40.
Seo, K. S., Kim, J. Y., Ha, K. T., Choi, N. G., Jung, H. R., Kim, G. S., Han, K. M., Lee, M. H., & Chae, Y. Z. (2011). Distribution characteristics of heavy metals in the soil of roadside in Seoul. The annual report of Seoul Metropolitan City Institute of Health & Environment, 47, 211–222.
Sparks, D. L. (1995). Environmental Soil Chemistry. Academic Press.
Tessier, A., Campbell, P. G. C., & Bisson, M. (1979). Sequential extraction procedure for the speciation of particulate trace metals. Analytical Chemistry, 51, 844–851.
U.S. EPA. (1992). Method 1311 Toxicity characteristic leaching procedure. Available from http://www.epa.gov/osw/hazard/testmethods/sw846/pdfs/1311.pdf. Accessed 17 Nov 2020.
Ulsan Traffic Management Center. (2015). The result of surveying traffic volumes and speed in 2015. Available from http://www.its.ulsan.kr. Accessed 17 Nov 2020.
Wenzel, W. W., Kirchbaumer, N., Prohaska, T., Stingeder, G., Lombi, E., & Adriano, D. C. (2001). Arsenic fractionation in soils using an improved sequential extraction procedure. Analytica Chimica Acta, 436, 309–323.
Yoo, E. H., Choi, Y. J., & Kim, M. H. (2010). Pollution characteristics of heavy metals and polycyclic aromatic hydrocarbon (PAHs) in deposited road particles of Busan. The annual report of Busan Metropolitan City Institute of Health & Environment, 20(1), 178–193.
Yoon, J. K., Kim, D. H., Kim, T. S., Park, J. G., Chung, I. R., Kim, J. H., & Kim, H. (2009). Evaluation on natural background of the soil heavy metals in Korea. Journal of Korea Society of Soil and Groundwater Environment, 14(3), 32–39.
Zhang, K., & Batteman, S. (2013). Air pollution and health risks due to vehicle traffic. Science of the Total Environment, 450-451, 307–316.
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This research was supported by the 2020 research fund of the University of Ulsan, South Korea.
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Kim, JH., Sohn, JI. & Oh, SY. Environmental monitoring of toxic metals in roadside soil and dust in Ulsan, South Korea: pollution evaluation and distribution characteristics. Environ Monit Assess 192, 773 (2020). https://doi.org/10.1007/s10661-020-08745-w
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DOI: https://doi.org/10.1007/s10661-020-08745-w