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Soil washing of As-contaminated stream sediments in the vicinity of an abandoned mine in Korea

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Abstract

A soil washing process was applied to remediate arsenic (As)-contaminated stream sediments around an abandoned mine in Goro, Korea. Laboratory scale soil washing experiments for As-contaminated stream sediments were performed under various washing conditions in order to maximize As removal efficiency. Stream sediments were taken from two sites (S1 and S5) along the main stream connected to an abandoned mine. Stream sediments at the two sites were divided into two groups (≥0.35 and <0.35 mm in diameter), giving four types of sediments, which were thereupon used for soil washing experiments. The results of soil washing experiments involving various pH conditions suggested that As removal efficiency is very high in both strongly acidic and basic solutions (pH 1 and 13), regardless of sediment type. Removal efficiencies for fine sediments from S1 and S5 were >95% after 1 h of washing with 0.2 M citric acid (C6H8O7). When using 0.2 M citric acid mixed with 0.1 M potassium phosphate (KH2PO4), the As removal efficiency increased to 100%. When recycled washing solution was applied, As removal efficiency was maintained at a level greater than 70%, even after eight recycling events. This suggests that the recycling of washing solution could be successfully applied as a means of decreasing the cost of the washing process. Results from the experiments suggest that soil washing is a potentially useful process for the remediation of As-contaminated stream sediments around abandoned mines.

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References

  • Abumaizar, R., & Smith, E. (1999). Heavy metal contaminants removal by soil washing. Journal of Hazardous Materials, 70, 71–86.

    Article  CAS  Google Scholar 

  • Alam, M. G. M., Tokunaga, S., & Maekawa, T. (2001). Extraction of arsenic in a synthetic arsenic-contaminated soil using phosphate. Chemosphere, 43, 1035–1041.

    Article  CAS  Google Scholar 

  • Allen, J. P., & Torres, L. G. (1991). Physical separation techniques for contaminated sediment. In, Recent Developments in Separation Science. Florida: CRC.

    Google Scholar 

  • Azcue, J. M. (1995). Environmental significance of elevated natural levels of arsenic. Environmental Review, 3, 212–221.

    CAS  Google Scholar 

  • Bhattacharjee, S., Chakravarty, S., Maity, S., Dureja, V., & Gupta, K. K. (2005). Metal contents in the groundwater of Sahebgunj district, Jharkhand, India, with special reference to arsenic. Chemosphere, 58, 1203–1217.

    Article  CAS  Google Scholar 

  • Benschoten, J., Matsumoto, M., & Young, W. (1997). Evaluation and analysis of soil washing for seven lead-contaminated soils. Journal of Environmental Engineering, 123, 217–224.

    Article  Google Scholar 

  • Cha, J., Lee, J., & Lee, M. (2003). Environmental assessment and decision of remediation scope for arsenic contaminated farmland soils and river deposits around Goro abandoned mine, Korea. Economic and Environmental Geology, 36, 457–467.

    Google Scholar 

  • Clifford, D., Subramonian, S., & Sorg, T. J. (1986). Removing dissolved inorganic contaminants from water. Environmental Science and Technology, 20, 1072–1080.

    Article  CAS  Google Scholar 

  • Cline, S., & Reed, B. (1995). Lead removal from soils via bench-scale soil washing techniques. Journal of Environmental Engineering, 121, 700–705.

    Article  CAS  Google Scholar 

  • Cuzick, J., Sasieni, P., & Evans, S. (1992). Ingested arsenic, keratosis and bladder cancers. American Journal of Epidemiology, 136, 416–417.

    Google Scholar 

  • Evangelou, V. P. (1998). Environmental soil and water chemistry: Principles and applications. New York: Wiley.

    Google Scholar 

  • Grasso, D., Butkus, M., O’Sullivan, D., & Nikolaidis, N. (1997). Soil-washing design methodology for a lead-contaminated sandy-soil. Water Research, 31, 3045–3056.

    Article  CAS  Google Scholar 

  • Griffiths, R. (1995). Soil-washing technology and practice. Journal of Hazardous Materials, 40, 175–189.

    Article  CAS  Google Scholar 

  • Harvey, C. F., Swartz, C. H., Badruzzaman, A. B. M., Keon-Blute, N., Yu, W., Ali, M. A., Jay, J., Beckie, R., Niedan, V., Brabander, D., Oates, P. M., Ashfaque, K. N., Islam, S., Hemond, H. F., & Ahmed, M. F. (2002). Arsenic mobility and groundwater extraction in Bangladesh. Science, 298, 1602–1606.

    Article  CAS  Google Scholar 

  • Hei, T. K., & Filipic, M. (2004). Role of oxidative damage in the genotoxicity of arsenic. Free Radical Biology and Medicine, 37, 574–581.

    Article  CAS  Google Scholar 

  • Helledy, T., Nilsson, R., & Jenssen, D. (2000). Arsenic (III) and heavy metal ions induce intrachromosal homologous recombination in the hprt gene of v79 Chinese hamster ovary cells. Environmental and Molecular Mutagenesis, 35, 114–122.

    Article  Google Scholar 

  • Kim, M., Ahn, K., & Jung, Y. (2002). Distribution of inorganic arsenic species in mine tailings of abandoned mines from Korea. Chemosphere, 49, 307–312.

    Article  CAS  Google Scholar 

  • Ko, I., Lee, C., Lee, K., Lee, S., & Kim, K. (2005). Remediation of soil contaminated with arsenic, zinc and nickel by pilot-scale soil washing. Environmental Progress, 24, 1–10.

    Article  CAS  Google Scholar 

  • Lee, M., Lee, J., Cha, J., & Lee, J. (2004a). Remediation design using soil washing and soil improvement method for As contaminated soils and stream deposits around an abandoned mine. Economic and Environmental Geology, 37, 121–131.

    Google Scholar 

  • Lee, S., Kim. J., Lee, J., Ko, I., & Kim, K. (2004b). Removal of arsenic in the tailing by soil flushing and the remediation process monitoring. Environmental Geochemistry and Health, 26(4), 403–409.

    Article  CAS  Google Scholar 

  • Linn, J. H., & Elliott, H. A. (1988). Mobilization of Cu and Zn in contaminated soil by nitriloacetic acid. Water, Air, and Soil Pollution, 37, 449–458.

    Article  CAS  Google Scholar 

  • MOE (Ministry of Environment, Korea). (2003). Soil Environment Conservation Act of Korea.

  • Mondal, P., Majumder, C. B., & Mohanty, B. (2006). Laboratory based approaches for arsenic remediation from contaminated water: Recent developments. Journal of Hazardous Materials, published online doi: 10.1016/j.hazmat.2006.10.078.

  • Nordstrom, D. K., & Alpers, C. N., (1999). Negative pH, efflorescent mineralogy, and consequences for environmental restoration at the Iron Mountain Superfund Site, California, (Paper presented at the Proceeding of National Academic Science in U.S.A 99. 3455–3462).

  • NRC (National Research Council). (1999). Arsenic in Drinking Water. Washington DC: National Academy Press.

    Google Scholar 

  • Onishi, H. (1969). Arsenic. In Wedepohl, K. H. (Ed.), Handbook of Geochemistry. New York: Springer.

    Google Scholar 

  • Pongratz, R. (1998). Arsenic speciation in environmental samples of contaminated soil. Science of the Total Environment, 224, 133–141.

    Article  CAS  Google Scholar 

  • Roussel, C., Bril, H., & Fernandez, A. (2000). Heavy metals in the environment, arsenic speciation; involvement in evaluation of environmental impact caused by mine wastes. Journal of Environmental Quality, 29, 182–188.

    Article  CAS  Google Scholar 

  • Sarma, V. A. K., & Majithia, M. (2001). Soil Analysis: Sampling, Instrumentation and Quality Control. Abindon: A.A. Balkema (Translated by M. Pansu, J. Gautheyrou, & J. Y. Loyer (1998), L’anlayse du sol. Echantillonnage, instrumentation et contrôle. Paris).

  • Semer, R., & Reddy, K. (1996). Evaluation of soil washing process to remove mixed contaminants from a sandy loam. Journal of Hazardous Materials, 45, 45–57.

    Article  CAS  Google Scholar 

  • Smedley, P., & Kinniburgh, D. (2002). A review of the source, behavior and distribution of arsenic in natural water. Applied Geochemistry, 17, 517–568.

    Article  CAS  Google Scholar 

  • Tokunaga, S., & Hakuta, T. (2002). Acid washing and stabilization of an artificial arsenic-contaminated soil. Chemosphere, 46, 31–38.

    Article  CAS  Google Scholar 

  • USEPA. (2000). Regulations on the disposal of arsenic residuals from drinking water treatment plants. EPA/600/R/00/025.

  • USEPA. (2002). Arsenic treatment technologies for soil, waste, and water. EPA/542/R/02/004.

  • WHO. (1993). Guidelines for Drinking Water Quality. Geneva: World Health Organization.

    Google Scholar 

  • Yoshidea, T., Yamanchi, H., & Jun, G. F. (2004). Chronic health effect in people exposed to arsenic via the drinking water: dose-response relationship in review. Toxicology and Applied Pharmacology, 198, 243–252.

    Article  CAS  Google Scholar 

  • Zaw, M., & Emett, M. (2002). Arsenic removal from water using advanced oxidation processes. Toxicology Letters, 133, 133–118.

    Article  Google Scholar 

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Acknowledgement

This work was supported by the Korea Research Foundation Grant funded by the Korean Government (KRF-2005-070-C00137).

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Authors and Affiliations

  1. Department of Environmental Geosciences, Pukyong National University, 599-1 Daeyongdong, Namgu, Busan, 608-737, Korea

    Minhee Lee, In Sung Paik, Wonhong Do, Insu Kim & Yesun Lee

  2. Environmental Engineering Section, Division of Biotechnology, Catholic University of Korea, San 43-1, Yokkok-2Dong, Wonmi-Gu, Gyeonggi-Do, 420-743, Korea

    Sanghoon Lee

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  1. Minhee Lee
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  2. In Sung Paik
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  3. Wonhong Do
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  4. Insu Kim
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  5. Yesun Lee
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Correspondence to Minhee Lee.

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Lee, M., Paik, I.S., Do, W. et al. Soil washing of As-contaminated stream sediments in the vicinity of an abandoned mine in Korea. Environ Geochem Health 29, 319–329 (2007). https://doi.org/10.1007/s10653-007-9093-1

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  • DOI: https://doi.org/10.1007/s10653-007-9093-1

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