Polymer-mediated interactions of fluid membranes in a lyotropic lamellar phase: a small angle X-ray and neutron scattering study

Abstract:

Small angle X-ray and neutron scattering data on an effective three-component lamellar phase composed of water, a non adsorbing water-soluble polymer (polyvynilpyrolidone), fluid membranes, made from a mixture of a cationic surfactant (cetylpiridiumchloride) and a cosurfactant (hexanol), are presented for various membrane as well as polymer concentrations. The data are fitted with a recently proposed model which takes into account the geometry and the fluctuations of these periodic structures. This allows a quantitative study of the polymer contribution to the smectic compression modulus of the lamellar phase. Four different regimes of polymer confinement are expected. The associated variations in are compared to a recent theoretical model, which predicts the polymer-mediated contribution to the smectic compression modulus.