Skip to main content
Log in

Niobium carbonitride precipitation and austenite recrystallization in hot-rolled microalloyed steels

  • Published:
Metallurgical Transactions A Aims and scope Submit manuscript

Abstract

The response of austenites to thermomechanical treatments is studied in a series of niobium (columbium) HSLA steels. Interactions between composition, plastic deformation, strain-induced precipitation, and austenite recrystallization are described and related to previous work in the field. Niobium in solution prior to deformation leads to significant retardation of subsequent austenite recrystallization if Nb(C,N) precipitation takes place prior to or during the early stages of recrystallization. Such straininduced precipitation proceeds in two stages: initially at austenitic grain boundaries and deformation bands, and later on substructural features in the unrecrystallized austenite. The latter precipitation is accelerated only if it occurs in the unrecrystallized austenite; if recrystallization precedes Nb(C,N) precipitation, then the precipitation reaction is much slower. Thus, the Nb(C,N) precipitation and austenite recrystallization reactions are coupled phenomena. The conditions necessary for such an interaction are analyzed, and it is proposed that the level of supersaturation of Nb(C,N) in the austenite at the deformation temperature is a critical factor in determining whether or not an effective interaction will operate at that temperature.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. W. E. Duckworth, R. Phillips, and J. A. Chapman:J. Iron Steel Inst., 1965, vol. 203, p. 1108.

    CAS  Google Scholar 

  2. K. J. Irvine, F. B. Pickering, and T. Gladman:J. Iron and Steel Inst., 1967, vol. 205, p. 161.

    CAS  Google Scholar 

  3. F. B. Pickering:Microalloying 75, Proceedings, p. 9, Union Carbide Corpora- tion, New York, 1977.

    Google Scholar 

  4. T. Gladman, D. Dulieu, and I. D. McIvor:Microalloying 75, Proceedings, p. 32, Union Carbide Corporation, New York, 1977.

    Google Scholar 

  5. L. Meyer, F. Heisterkamp, and W. Mueschenborn:Microalloying 75, Pro- ceedings, p. 153, Union Carbide Corporation, New York, 1977.

    Google Scholar 

  6. J. D. Baird and R. R. Preston:Processing and Properties of Low Carbon Steel, p. 1, The Metallurgical Society of AIME, New York, 1973.

    Google Scholar 

  7. M. Cohen and S. S. Hansen:MICON ’78: Optimization of Processing, Proper- ties and Service Performance Through Microstructural Control, H. Abrams, G. N. Manian, D. A. Nail, and H. D. Solomon, eds., p. 34, ASTM, Philadelphia, PA, 1979.

    Google Scholar 

  8. K. J. Irvine, T. Gladman, J. Orr, and F. B. Pickering:J. Iron Steel Inst., 1970, vol. 208, p. 717.

    CAS  Google Scholar 

  9. R. A. P. Djaic and J. J. Jonas:J. Iron Steel Inst., 1972, vol. 210, p. 256.

    CAS  Google Scholar 

  10. R. A. Petkovic, M. J. Luton, and J. J. Jonas:Can. Met. Quart., 1975, vol. 14, p. 137.

    CAS  Google Scholar 

  11. R. A. Petkovic, M. J. Luton, and J. J. Jonas:The Hot Deformation of Aus- tenite, p. 68, The Metallurgical Society of AIME, New York, 1977.

    Google Scholar 

  12. M. J. Stewart:The Hot Deformation of Austenite, p. 233, The Metallurgical Society of AIME, New York, 1977.

    Google Scholar 

  13. L. J. Cuddy:The Hot Deformation of Austenite, p. 169, The Metallurgical Society of AIME, New York, 1977.

    Google Scholar 

  14. J. N. Cordea and R. E. Hook:Met. Trans., 1970, vol. 1, p. 111.

    CAS  Google Scholar 

  15. T. L. Capaletti, L. A. Jackson, and W. J. Childs:Met. Trans., 1972, vol. 3, p. 789.

    Article  Google Scholar 

  16. H. Weiss, A. Gittins, G. G. Brown, and W. J. McG. Tegart:J. Iron Steel Inst., 1973, vol. 211, p. 703.

    CAS  Google Scholar 

  17. A. LeBon, J. Rofes-Vernis, and C. Rossard:Mem. Sci. Rev. Met., 1973, vol. 70, p. 577.

    CAS  Google Scholar 

  18. A. LeBon, J. Rofes-Vernis, and C. Rossard:Met. Sci., 1975, vol. 9, p. 36.

    Article  CAS  Google Scholar 

  19. K. J. Irvine, T. Gladman, J. Orr, and F. B. Pickering:J. Iron Steel Inst., 1970, vol. 208, p. 717.

    CAS  Google Scholar 

  20. J. D. Jones and A. B. Rothwell:Iron Steel Inst., Publication No. 108, 1968, p. 78.

  21. R. Preistner, C. C. Early, and J. H. Rendall:J. Iron Steel Inst., 1968, vol. 206, p. 1252.

    Google Scholar 

  22. I. Kosazu, T. Shimuzu, and H. Kubota:Trans. Iron Steel Inst. Jpn, 1971, vol. 11, p. 367.

    Google Scholar 

  23. B. L. Phillipo and F. A. A. Crane:J. Iron Steel Inst., 1973, vol. 211, p. 653.

    CAS  Google Scholar 

  24. H. Sekine and T. Maruyama:Trans. Iron Steel Inst. Jpn, 1976, vol. 16, p. 427.

    Google Scholar 

  25. T. M. Hoogendoorn and M. J. Spanraft:Microalloying 75, Proceedings, p. 75, Union Carbide Corporation, New York, 1977.

    Google Scholar 

  26. A. T. Davenport, R. E. Miner, and R. A. Kot:The Hot Deformation of Aus- tenite, p. 186, The Metallurgical Society of AIME, New York, 1977.

    Google Scholar 

  27. H. Watanabe, Y. E. Smith, and R. D. Pehlke:The Hot Deformation of Aus- tenite, p. 140, The Metallurgical Society of AIME, New York, 1977.

    Google Scholar 

  28. I. Weiss and J. J. Jonas:Met Trans. A, 1979, vol. 10A, p. 831.

    Article  CAS  Google Scholar 

  29. I. Weiss and J. J. Jonas:Met. Sci., 1979, vol. 13, p. 238.

    Google Scholar 

  30. H. Nordberg and B. Aronsson:J. Iron Steel Inst., 1968, vol. 206, p. 1263.

    CAS  Google Scholar 

  31. G. E. Dieter, Jr.:Mechanical Metallurgy, 1st edition, p. 509, McGraw-Hill Book Co., New York, 1961.

    Google Scholar 

  32. M. F. Ashby and R. Ebeling:Trans. TMS-AIME, 1966, vol. 236, p. 1396.

    CAS  Google Scholar 

  33. C. Zener (1949)-Private communication to C. S. Smith:Trans. AIME, 1949, vol. 175, p. 15.

  34. T. Gladman:Proc. Roy. Soc., 1966, vol. A294, p. 298.

    Google Scholar 

  35. A. T. English and W. A. Backofen:Trans. TMS-AIME, 1964, vol. 230, p. 396.

    CAS  Google Scholar 

  36. C. Wells:Atom Movements, p. 30, American Society for Metals Publication, Metals Park, Ohio, 1951.

    Google Scholar 

  37. T. Gladman, I. D. McIvor, and F. B. Pickering:J. Iron Steel Inst., 1971, vol. 209, p. 380.

    CAS  Google Scholar 

  38. J. W. Cahn:Acta Met., 1956, vol. 4, p. 449.

    Article  CAS  Google Scholar 

  39. J. W. Cahn and W. C. Hagel:Acta Met., 1963, vol. 11, p. 561. 40. G. R. Speich and R. M. Fisher: Recrystallization, Grain Growth and Textures, p. 563, ASM Publication, Metals Park, Ohio, 1966.

    Article  CAS  Google Scholar 

  40. M. F. Ashby:Oxide Dispersion Strengthening, p. 143, The Metallurgical Society of AIME, New York, 1958.

    Google Scholar 

  41. T. Gladman, B. Holmes, and I. D. McIvor:The Effects of Second Phase Parti- cles on the Mechanical Properties of Steel, p. 68, The Iron and Steel Institute, London, England, 1971.

    Google Scholar 

  42. R. W. Cahn:Recrystallization, Grain Growth and Textures, p. 99, ASM Publi- cation, Metals Park, Ohio, 1966.

    Google Scholar 

  43. E. Orowan:Dislocations in Metals, p. 181, AIME Publication, New York, 1954.

    Google Scholar 

  44. H. Hu:Recovery and Recrystallization of Metals, p. 311, Interscience Pub- lishers, New York, 1963.

    Google Scholar 

  45. P. A. Beck and P. R. Sperry:J. Appl. Phys., 1950, vol. 21, p. 150.

    Article  CAS  Google Scholar 

  46. J. E. Bailey and P. B. Hirsch:Proc. Roy. Soc., 1962, vol. A267, p. 11.

    Google Scholar 

  47. U. F. Kocks, A. S. Argon, and M. F. Ashby:Progress in Materials Science, vol. 19, Pergamon Press, New York, 1976.

    Google Scholar 

  48. H. Gleiter and B. Chalmers:Progress in Materials Science, vol. 16, Pergamon Press, New York, 1972.

    Google Scholar 

  49. L. E. Murr:Interfacial Phenomena in Metals and Alloys, Addison-Wesley, Reading, MA, 1975.

    Google Scholar 

  50. H. Kreye and E. Hornbogen:J. Mater. Sci., 1970, vol. 5, p. 89.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Additional information

This paper is based on a presentation made at a symposium on “Precipitation Processes in Structural Steels” held at the annual meeting of the AIME, Denver, Colorado, February 27 to 28, 1978, under the sponsorship of the Ferrous Metallurgy Committee of The Metallurgical Society of AIME.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Hansen, S.S., Sande, J.V. & Cohen, M. Niobium carbonitride precipitation and austenite recrystallization in hot-rolled microalloyed steels. Metall Trans A 11, 387–402 (1980). https://doi.org/10.1007/BF02654563

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02654563

Keywords

Navigation