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Filler and Rubber Reinforcement

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Book cover Reinforcement of Rubber

Abstract

In a sense, rubber reinforcement is very unique because it includes several functional properties other than mechanical ones. Among quite a number of compounding ingredients, reinforcing fillers, carbon black (CB) in particular, were focused in 1930s, and the effect has been actively researched for several decades. Ability of CB to immobilize rubber on its surface (known as bound rubber, CB-to-rubber interaction) and clustering tendency of CB in rubber matrix (known as CB structuring, filler-to-filler interaction) have been recognized and studied for many years. Together with the third, hydrodynamic volume effect, the three factors have been extensively researched, but the acting mechanism of the three factors for rubber reinforcement has remained unsolved up to the end of the twentieth century. This chapter presents the most recent elucidations related to the reinforcement mechanism.

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References

  1. C.C. Davis, J.T. Blake (eds.), The Chemistry and Technology of Rubber (Reinhold Publishing, New York, 1937) (This textbook is historically the first compilation of the reports relevant to rubber science and rubber technics. During the World War II, illegal publication of this book was tacitly permitted in Japan for efficient production of the military rubber goods, which suggested that this book was recognized to be a world standard then)

    Google Scholar 

  2. P. Schidrowitz, T.R. Dawson (eds.), History of the Rubber Industry (W. Heffer & Sons, Cambridge, 1952) (This book gives a detailed and good summary of technical aspects of many rubber goods up to 1950, written by 35 engineers in UK. However, it failed to give the historical significance of rubber industry in general in the modern society)

    Google Scholar 

  3. G.S. Whitby, C.C. Davis, R.F. Dunbrook (eds.), Synthetic Rubber (Wiley, New York, 1954)

    Google Scholar 

  4. L. Bateman (ed.), The Chemistry and Physics of Rubber-Like Substances (Maclaren & Sons, London, 1963)

    Google Scholar 

  5. G. Kraus (ed.), Reinforcement of Elastomers (Interscience, New York, 1965)

    Google Scholar 

  6. H. Long (ed.), Basic Compounding and Processing of Rubber (Rubber Division, American Chemical Society, Akron, 1985)

    Google Scholar 

  7. A.D. Roberts (ed.), Natural Rubber Science and Technology (Oxford University Press, Oxford, 1988)

    Google Scholar 

  8. W. Hoffmann, Rubber Technology Handbook, translated into English by R. Bauer, E.A. Meinecke (Hanser, Munich, 1989)

    Google Scholar 

  9. A.N. Gent (ed.), Engineering with Rubber: How to Design Rubber Components, 2nd edn. (Hanser, Munich, 2001)

    Google Scholar 

  10. B. Rodgers (ed.), Rubber Compounding: Chemistry and Applications (Marcel Dekker, New York, 2004)

    Google Scholar 

  11. J.E. Mark, B. Erman, C.M. Roland (eds.), The Science and Technology of Rubber, 4th edn. (Academic Press, Waltham, MA, 2013)

    Google Scholar 

  12. Y. Ikeda, A. Kato, S. Kohjiya, Y. Nakajima, Rubber Science: A Modern Approach (Springer, Singapore, 2017)

    Google Scholar 

  13. J.R. Katz, Naturwissenschaften 13, 410, 900 (1925)

    Google Scholar 

  14. S. Kohjiya, Y. Ikeda, Crystallization of Natural Rubber. Paper presented at the 191th technical meeting of rubber division, American Chemical Society, Beachwood, OH, April 25, 2017

    Google Scholar 

  15. S. Kohjiya, P. Junkong, Y. Ikeda, Kaut. Gummi Kunstst. (October issue), 38 (2017)

    Google Scholar 

  16. G. Holden, N.R. Legge, R. Quirk, H.E. Schroeder (eds.), Thermoplatic Elastomers, 2nd edn. (Hanser, Munchen, 1996)

    Google Scholar 

  17. S. Kohjiya, Y. Ikeda, in Solid State Ionics for Batteries, Chap. 6, ed. by T. Minami (Springer, Tokyo, 2005)

    Google Scholar 

  18. S. Hashizume, Y. Ikeda, S. Kohjiya, Peculiar Behavior of Natural Rubber in the Mixing Process (TechnoBiz, Bangkok, 2018)

    Google Scholar 

  19. D.J. Angier, W.F. Watson, J. Polym. Sci. 18, 129 (1956)

    Google Scholar 

  20. G. Ayhey, C.G. Moor, W.F. Watson, J. Polym. Sci. 19, 1 (1956)

    Google Scholar 

  21. D.J. Angier, W.T. Chambers, W.F. Watson, J. Polym. Sci. 25, 129 (1958)

    Google Scholar 

  22. R.J. Ceresa, W.F. Watson, J. Appl. Polym. Sci. 1, 101 (1959)

    Google Scholar 

  23. C.C. Webster, W.J. Baulkwill (eds.), Rubber (Longman Scientific & Technical, Harlow, 1989)

    Google Scholar 

  24. D. Wititsuwannakul, R. Wititsuwannakul, Biochemistry of natural rubber and structure of latex, in Biopolymers, Chap. 6, vol. 2, ed. by T. Koyama, A. Steinbuechel (Wiley-VCH, Weinheim, 2001)

    Google Scholar 

  25. S. Kohjiya, Natural Rubber: From the Odyssey of the Hevea Tree to the Transportation Age (Smithers Rapra, Shrewsbury, 2015)

    Google Scholar 

  26. C. Goodyear, Gum-Elastic and Its Varieties, with a Detailed Account of Its Application and Uses and of the Discovery of Vulcanization (Published for the author, New Haven, 1855)

    Google Scholar 

  27. B.K. Peirce, Trials of an Inventor: Life and Discoveries of Charles Goodyear (Reprinted from the 1866 edition by University Press of the Pacific, Honolulu, 2003)

    Google Scholar 

  28. A.G. Regli, Rubber’s Goodyear: The Story of a Man’s Perseverance (Julian Messner, New York, 1941)

    Google Scholar 

  29. C. Slack, Noble Obsession: Charles Goodyear, Thomas Hancock, and the Race to Unlock the Greatest Industrial Secret of the Nineteenth Century (Hyperion, New York, 2002)

    Google Scholar 

  30. R. Korman, The Goodyear Story: An Inventor’s Obsession and the Struggle for a Rubber Monopoly (Encounter Books, San Francisco, 2002)

    Google Scholar 

  31. C.O. Weber, The Chemistry of India Rubber, Including the Outline of a Theory on Vulcanisation (Charles Griffin & Co., London, 1902)

    Google Scholar 

  32. Y. Ikeda, Y. Yasuda, T. Ohashi, H. Yokoyama, S. Minoda, H. Kobayashi, T. Honma, Macromolecules 48, 462 (2015)

    Google Scholar 

  33. Y. Sakaki, R. Usami, A. Tohsan, P. Junkong, Y. Ikeda, RSC Adv. 8, 10727 (2018)

    Google Scholar 

  34. A. Tohsan, Y. Yasuda, R. Usami, T. Ohashi, Y. Sakaki, P. Junkong, Y. Ikeda, Kautsch. Gummi Kunstst. (June issue), 111 (2018)

    Google Scholar 

  35. T. Ohashi, T. Sato, T. Nakajima, P. Junkong, Y. Ikeda, RSC Adv. 8, 32930 (2018)

    Google Scholar 

  36. Y. Ikeda, Y. Sakaki, Y. Yasuda, P. Junkong, T. Ohashi, K. Miyaji, H. Kobayashi, Organometallics 38, 2363 (2019)

    Google Scholar 

  37. K.F. Heinisch, Dictionary of Rubber (Halsted Press, New York, 1974)

    Google Scholar 

  38. R.F. Ohm (ed.), The Vanderbilt Rubber Handbook, Parts 3 & 4, 13th edn. (R.T. Vanderbilt Co., Norwalk, 1990)

    Google Scholar 

  39. Nippon Gomu Kyokai (ed.), Gomu Kogyou Binran (Handbook of Rubber Technology), 4th edn. (Nippon Gomu Kyokai, Tokyo, 1994) (in Japanese)

    Google Scholar 

  40. W.R. Cline, The Economics of Global Warming (Institute for International Economics, Washington, DC, 1992)

    Google Scholar 

  41. S. Solomon, G.-K. Plattner, R. Knutti, P. Friedlingstein, Proc. Natl. Acad. Sci. USA 106, 1704 (2009)

    Google Scholar 

  42. National Research Council of the National Academy of the United States of America, Climate Change: Evidence, Impact, and Choices (National Academies Press, Washington DC, 2012)

    Google Scholar 

  43. R.K. Pachauri, L. Meyer (eds.), Climate Change 2014: Synthesis Report (IPCC, Geneva, 2015) (Available at IPCC (Intergovernmental Panel on Climate Change) home page)

    Google Scholar 

  44. S. Ikkatai, Japan’s Choice at the Low-Carbon Age (Iwanami Shoten, Tokyo, 2008) (in Japanese)

    Google Scholar 

  45. R.I. Block, A.D. Kopp, A. Limi, Turning the Right Corner: Ensuring Development through a Low-Carbon Transport Sector (World Bank, Washington DC, 2013) (World Bank, Report No. 78086, available at the World Bank home page)

    Google Scholar 

  46. K. Sumida, D.L. Rogow, J.A. Mason, T.M. McDonald, E.D. Bloch, Z.R. Herm, T.-H. Bae, J.R. Long, Chem. Rev. 112, 724 (2012)

    Google Scholar 

  47. International Energy Agency (IEA), 20 Years of Carbon Capture and Storage (IEA, 15 Nov 2016) (Available at IEA home page)

    Google Scholar 

  48. J.-B. Donnet, R.C. Bansal, M.-J. Wang (eds.), Carbon Black (Marcel Dekker, New York, 1993)

    Google Scholar 

  49. W.A. Wampler, T.F. Carlson, in Rubber Compounding: Chemistry and Applications, Chap. 6, ed. by B. Rodgers (Marcel Dekker, New York, 2004)

    Google Scholar 

  50. J.E. Mark, B. Erman, C.M. Roland (eds.), The Science and Technology of Rubber, Chaps. 8 & 9, 4th edn. (Academic Press, Waltham, MA, 2013)

    Google Scholar 

  51. K. Okita, Nippon Gomu Kyokaishi 37, 35 (1964) (in Japanese)

    Article  Google Scholar 

  52. W.B. Wiegand, Trans. Inst. Rubber Ind. 1, 141 (1925)

    Google Scholar 

  53. R. Kubo, Gomudansei (Kawade Shobo, Tokyo, 1947) (in Japanese. Translation of the paragraph in the text into English is by one of the authors, S. K.)

    Google Scholar 

  54. M.P. Wagner, Rubber Chem. Technol. 49, 703 (1976)

    Article  CAS  Google Scholar 

  55. R.K. Iler, The Chemistry of Silica (Wiley, New York, 1979)

    Google Scholar 

  56. Y. Ikeda, S. Kohjiya, Polymer 38, 4417 (1997)

    Article  CAS  Google Scholar 

  57. S. Wolff, Kautsch. Gummi Kunstst. 30, 516 (1977)

    CAS  Google Scholar 

  58. S. Wolff, Rubber Chem. Technol. 69, 325 (1996)

    Article  CAS  Google Scholar 

  59. A.S. Hashim, B. Azahari, Y. Ikeda, S. Kohjiya, Rubber Chem. Technol. 71, 289 (1998)

    Article  CAS  Google Scholar 

  60. K. Murakami, S. Iio, Y. Ikeda, M. Tosaka, H. Ito, S. Kohjiya, J. Mater. Sci. 38, 1447 (2003)

    Article  CAS  Google Scholar 

  61. C.J. Brinker, G.W. Scherer, Sol-Gel Science (Academic Press, New York, 1982)

    Google Scholar 

  62. J.E. Mark, S.-J. Pan, Macromol. Rapid Commun. 3, 681 (1982)

    Article  CAS  Google Scholar 

  63. S. Kohjiya, A. Yajima, Y. Ikeda, J.R. Yoon, Nippon Gomu Kyokaishi 67, 859 (1994) (in Japanese)

    Article  CAS  Google Scholar 

  64. Y. Ikeda, A. Tanaka, S. Kohjiya, J. Mater. Chem. 7, 1497 (1997)

    Article  CAS  Google Scholar 

  65. S. Kohjiya, Y. Ikeda, Rubber Chem. Technol. 73, 534 (2000)

    Article  CAS  Google Scholar 

  66. S. Kohjiya, K. Murakami, S. Iio, T. Tanahashi, Y. Ikeda, Rubber Chem. Technol. 74, 16 (2001)

    Article  CAS  Google Scholar 

  67. A. Tohsan, Y. Ikeda, in Chemistry, Manufacture and Applications of Natural Rubber, Chap.6, ed. by S. Kohjiya, Y. Ikeda (Woodhead/Elsevier, Cambridge, 2014)

    Google Scholar 

  68. A. Kato, A. Tohsan, S. Kohjiya, T. Phakkeeree, P. Phinyocheep, Y. Ikeda, in Progress in Rubber Nanocomposites, Chap. 12, ed. by S. Thomas, H.J. Maria (Woodhead/Elsevier, Amsterdam, 2017)

    Google Scholar 

  69. T. Ohashi, A. Tohsan, Y. Ikeda, Polym. Int. 66, 250 (2017)

    Article  CAS  Google Scholar 

  70. S. Yamashita, S. Kohjiya, in Wood Processing and Utilization, Chap. 23, ed. by J. F. Kennedy, G.O. Phillips, P.A. Williams (Ellis Horwood, Chichester, 1989)

    Google Scholar 

  71. Y. Ikeda, T. Phakkeeree, P. Junkong, H. Yokohama, P. Phinyocheep, R. Kitano, A. Kato, RSC Adv. 7, 5222 (2017)

    Article  CAS  Google Scholar 

  72. World Commission on Environment and Development, Our Common Future (Oxford University Press, Oxford, 1987)

    Google Scholar 

  73. E.B. Barbier, Natural Resources and Economic Development (Cambridge University Press, Cambridge, 2005)

    Book  Google Scholar 

  74. J.W. Tester, E.M. Drake, M.W. Golay, M.J. Driscoll, W.A. Peters, Sustainable Energy: Choosing among Options (MIT Press, Cambridge, MA, 2005)

    Google Scholar 

  75. E. Dinjus, U. Arnold, N. Dahmen, R. Hoefer, W. Wach, in Sustainable Solutions for Modern Economics, Chap. 8, ed. by R. Hoefer (RSC Publishing, Cambridge, 2009)

    Google Scholar 

  76. K.C. Baranwal, in Vignettes from the International Rubber Science Hall of Fame 1958–1988: 36 Major Contributors to Rubber Science, ed. by B.N. Zimmerman (Rubber Division of American Chemical Society, Akron, 1989), pp. 170–177

    Google Scholar 

  77. J.H. Fielding, Ind. Eng. Chem. 29, 880 (1937)

    Article  CAS  Google Scholar 

  78. D.F. Twiss, J. Soc. Chem. Ind. 44, 106T (1925)

    Google Scholar 

  79. K. Fujimoto, Nippon Gomu Kyokaishi 37, 602 (1964) (in Japanese)

    Article  Google Scholar 

  80. S. Fujiwara, K. Fujimoto, Rubber Chem. Technol. 44, 1273 (1971)

    Article  Google Scholar 

  81. B. Bueche, J. Appl. Polym. Sci. 5, 271 (1961)

    Article  CAS  Google Scholar 

  82. J. Furukawa, Nippon Gomu Kyokaishi 30, 909 (1957) (in Japanese)

    Article  Google Scholar 

  83. L.L. Ban, W.M. Hess, L.A. Papazian, Rubber Chem. Technol. 47, 858 (1974)

    Article  Google Scholar 

  84. M. Klüppel, Adv. Polym. Sci. 164, 1 (2003)

    Article  CAS  Google Scholar 

  85. A.R. Payne, in Reinforcement of Elastomers, Chap. 3, ed. by G. Kraus (Interscience, New York, 1965)

    Google Scholar 

  86. A. Einstein, Ann. Phys. 17, 549 (1905) (Title of this paper is “On the movement of small particles suspended in stationary liquids required by the molecular-kinetic theory of heat”)

    Google Scholar 

  87. J. Stachel (ed.), Einstein’s Miraculous Year: Five Papers that Changed the Face of Physics (Princeton University Press, Princeton, 1998)

    Google Scholar 

  88. J.S. Ligden, EINSTEIN 1995: The Standard of Greatness (Harvard University Press, Cambridge, MA, 2005)

    Google Scholar 

  89. J. Renn, Ann. Phys. (Leipzig) 14(S1, Supplement) (2005), Einstein’s Annalen Papers, 23 (This supplemental issue was published to commemorate the pathbreaking papers of Einstein’s annus mirabilis 1905, which had changed our understanding of space, time, and radiation. Renn begins his review paper by “Einstein’s 1905 paper on Brownian motion was an essential contribution to the foundation of modern atomism [20].” Here, Ref. [86] shown above is cited as 20)

    Google Scholar 

  90. A. Einstein, Ann. Phys. 19, 758 (1906)

    Google Scholar 

  91. A. Einstein, Ann. Phys. 34, 289 (1911)

    Google Scholar 

  92. A. Einstein, Ann. Phys. 34, 591 (1911) (error correction)

    Article  CAS  Google Scholar 

  93. A. Einstein, in Investigations on the Theory of the Brownian Movement, edited with notes by R. Fürth, translated by A.D. Cowper (Dover, New York, 1956) (This book is the English translation of the original German version published in 1926. The explanation of Eq. (2.1) by Einstein in the text is taken from p. 54 of this book)

    Google Scholar 

  94. R.M. Mazo, Brownian Motion: Fluctuations, Dynamics and Applications, Chap. 1 (Clarendon Press, Oxford, 2002)

    Google Scholar 

  95. J. Perrin, C. R. Acad. Sci. (Paris) 147, 475, 530 (1908)

    Google Scholar 

  96. J. Perrin, Ann. Chim. Phys. 18, 1 (1909)

    Google Scholar 

  97. M.J. Nye (ed.), The Question of the Atom: From the Karlsruhe Congress to the First Solvay Conference, 1860–1911 (Tomash Publishers, Los Angeles, 1984) (Contributions of Einstein and Perrin to atomism are described in Chaps. 18 and 20, respectively)

    Google Scholar 

  98. H. Morawetz, Polymers: The Origins and Growth of a Science (Wiley, New York, 1985)

    Google Scholar 

  99. E. Guth, O. Gold, Phys. Rev. 53, 322 (1938)

    CAS  Google Scholar 

  100. W.H. Stockmayer, in Elastomeric Polymer Networks, Chap. 1, ed. by J.E. Mark, B. Erman (Prentice Hall, Englewood Cliffs, 1992) (This book was originally planned to celebrate the 85th birthday of E. Guth. But, he passed away on July 5, just short of his birthday on August 21, 1990. The book is instead, therefore, a memorial to him)

    Google Scholar 

  101. O. Gold, Beitraege zur Hydrodynamik der zaehen Fluessigkeiten, Dissertation, Universität Wien, 1936

    Google Scholar 

  102. E. Guth, H. Mark, Monatsch. Chem. 65, 93 (1934)

    Article  CAS  Google Scholar 

  103. Y. Ikeda, A. Kato, S. Kohjiya, Y. Nakajima, Rubber Science: A Modern Approach (Springer, Singapore, 2017), Subsection 2.3.4 (pp. 45–48)

    Google Scholar 

  104. H.M. James, E. Guth, J. Chem. Phys. 11, 455, 472 (1943)

    Google Scholar 

  105. H.M. James, E. Guth, J. Chem. Phys. 15, 669 (1943)

    Article  Google Scholar 

  106. H.M. James, E. Guth, J. Chem. Phys. 21, 1039 (1953)

    Article  CAS  Google Scholar 

  107. P.J. Flory, J. Rehner, J. Chem. Phys. 11, 512–521 (1943)

    Article  CAS  Google Scholar 

  108. P.J. Flory, J. Chem. Phys. 18, 108 (1950)

    Article  CAS  Google Scholar 

  109. P.J. Flory, F.T. Wall, J. Chem. Phys. 19, 1435 (1951)

    Article  Google Scholar 

  110. A.T. James, Ann. Math. 74, 456 (1961)

    Article  Google Scholar 

  111. B.E. Eichinger, in Elastomeric Polymer Networks, Chap. 7, ed. by J.E. Mark, B. Erman (Prentice Hall, Englewood Cliffs, 1992)

    Google Scholar 

  112. P.J. Flory, Proc. R. Soc. London, Ser. A 351, 351 (1976)

    Google Scholar 

  113. J.E. Mark, B. Erman, Rubberlike Elasticity: A Molecular Primer (Wiley, New York, 1988)

    Google Scholar 

  114. B. Erman, I. Bahar, A. Kloczkowski, J.E. Mark, in Elastomeric Polymer Networks, Chap. 11, ed. by J.E. Mark, B. Erman (Prentice Hall, Englewood Cliffs, 1992)

    Google Scholar 

  115. B. Erman, J.E. Mark, Structure and Properties of Rubberlike Networks (Oxford University Press, New York, 1997)

    Google Scholar 

  116. J.F. Douglas, G.B. McKenna, in Elastomeric Polymer Networks, Chap. 23, ed. by E. Mark, B. Erman (Prentice Hall, Englewood Cliffs, 1992)

    Google Scholar 

  117. A. Kloczkowski, J.E. Mark, B. Erman, Macromolecules 28, 5089 (1995)

    Article  CAS  Google Scholar 

  118. K. Urayama, T. Kawamura, S. Kohjiya, Macromolecules 34, 8261 (2001)

    Article  CAS  Google Scholar 

  119. T. Kawamura, K. Urayama, S. Kohjiya, J. Polym. Sci.: Part B: Polym. Phys. 40, 2780 (2002)

    Article  CAS  Google Scholar 

  120. K. Urayama, T. Kawamura, S. Kohjiya, J. Chem. Phys. 118, 5658 (2003)

    Article  CAS  Google Scholar 

  121. K. Urayama, J. Polym. Sci.: Part B: Polym. Phys. 44, 3440 (2006)

    Article  CAS  Google Scholar 

  122. H. Smallwood, J. Appl. Phys. 15, 758 (1944)

    Article  CAS  Google Scholar 

  123. E. Guth, J. Appl. Phys. 16, 20 (1945)

    Article  CAS  Google Scholar 

  124. H. Schweinler, B. Erman, J.E. Mark, A. Weinberg, Phys. Today 44(June), 133 & (October), 154 (1991) (The cited sentence is found in June issue. October issue is for the correction)

    Google Scholar 

  125. L.H. Cohan, India Rubber World 117(3), 343 (1947) (The reprint of this paper was published in Rubber Chem. Technol. 21, 667 (1948))

    Google Scholar 

  126. P. Singer, Hegel (Oxford University Press, Oxford, 1983)

    Google Scholar 

  127. M. Van den Tempel, J. Colloid Sci. 16, 28 (1961)

    Google Scholar 

  128. As a relevant excellent review, see M.-J. Wang, Rubber Chem. Technol. 72, 430 (1999)

    Google Scholar 

  129. N. Tokita, M.J. Wang, B. Chung, K. Mahmud, Nippon Gomu Kyokaishi 71, 522 (1998)

    Article  CAS  Google Scholar 

  130. D. Stauffer, Introduction to Percolation Theory (Taylor & Francis, London, 1985)

    Book  Google Scholar 

  131. On conductive composites using rubber matrix, quite a number of papers have been published so far. One recent interesting paper is mentioned here: M. Okano, M. Fujii, S. Watanabe, Appl. Phys. Lett. 111, 221902 (2017) (In this paper, percolation was observed at 30% CB in weight, roughly equivalent to 40 phr)

    Google Scholar 

  132. G. Heinrich, M. Klueppel, T.A. Vilgis, Curr. Opin. Solid State Mater. Sci. 6(3), 195 (2002)

    Article  CAS  Google Scholar 

  133. Y. Ikeda, A. Kato, S. Kohjiya, Macromol. Rapid Commun. 25, 1186 (2004)

    Article  CAS  Google Scholar 

  134. S. Kohjiya, A. Kato, J. Shimanuki, T. Hasegawa, Y. Iked, Polymer 46, 4440 (2005)

    Article  CAS  Google Scholar 

  135. S. Kohjiya, A. Kato, T. Suda, J. Shimanuki, Y. Ikeda, Polymer 47, 3298 (2006)

    Article  CAS  Google Scholar 

  136. S. Kohjiya, A. Kato, Y. Ikeda, Prog. Polym. Sci. 33, 979 (2008)

    Article  CAS  Google Scholar 

  137. L. Mullins, Rubber Chem. Technol. 21, 281 (1948)

    Google Scholar 

  138. L. Mullins, J. Phys. Chem. 54, 239 (1950)

    Article  CAS  Google Scholar 

  139. L. Mullins, N.R. Tobin, J. Appl. Polym. Sci. 9, 2993 (1965)

    Article  CAS  Google Scholar 

  140. L. Mullins, Rubber Chem. Technol. 42, 339 (1969)

    Article  CAS  Google Scholar 

  141. C.M. Roland, in The Science and Technology of Rubber, Chap. 6, 4th edn., ed. by B. Erman, J.E. Mark, C.M. Roland (Academic Press, Watham, MA, 2013)

    Google Scholar 

  142. K.M. Schmoller, A.R. Bausch, Nat. Mater. 12(April), 278 (2013)

    Article  CAS  PubMed  Google Scholar 

  143. J.A. Haarwood, L. Mullins, A.R. Pain, J. Appl. Polym. Sci. 9, 3011 (1965)

    Article  Google Scholar 

  144. J.A. Haarwood, A.R. Pain, J. Appl. Polym. Sci. 10, 315.137 (1966)

    Google Scholar 

  145. J.A. Haarwood, A.R. Pain, J. Appl. Polym. Sci. 10, 1203 (1966)

    Article  Google Scholar 

  146. B.P. Grady, S.L. Cooper, C.C. Robertson, in The Science and Technology of Rubber, Chap. 13, 4th edn., ed. by B. Erman, J.E. Mark, C.M. Roland (Academic Press, Watham, MA, 2013)

    Google Scholar 

  147. T.-T. Mai, Y. Morishita, K. Urayama, Soft Matter 13, 1966 (2017)

    Google Scholar 

  148. Y. Sato, Nippon Gomu Kyokaishi 30, 922 (1957) (in Japanese)

    Article  Google Scholar 

  149. Y. Sato, J. Furukawa, Rubber Chem. Technol. 35, 857 (1962)

    Article  CAS  Google Scholar 

  150. F.W. Boggs, J. Chem. Phys. 20, 632 (1952)

    Article  CAS  Google Scholar 

  151. A.N. Gent, Rubber Chem. Technol. 63, 49 (1990)

    Article  Google Scholar 

  152. C. Fond, J. Polym. Sci. B Polym. Phys. 39, 2081 (2001)

    Article  CAS  Google Scholar 

  153. J.B. Le Cam, Rubber Chem. Technol. 83, 247 (2010)

    Article  Google Scholar 

  154. J.B. Le Cam, E. Toussaint, Macromolecules 41, 7579 (2008)

    Article  CAS  Google Scholar 

  155. A.S. Pavlov, P.G. Khalatur, Chem. Phys. Lett. 653, 90 (2016)

    Article  CAS  Google Scholar 

  156. A. Voet, P. Aboytes, P.A. Marsh, Rubber Age 101(10), 78 (1969)

    CAS  Google Scholar 

  157. F.A. Heckman, A.I. Medalia, J. Insti, Rubber Ind. 3, 66 (1969)

    CAS  Google Scholar 

  158. A.K. Sircar, A. Voet, Rubber Chem. Technol. 43, 973 (1970)

    Article  CAS  Google Scholar 

  159. A.M. Gessler, Rubber Chem. Technol. 43, 943 (1970)

    Article  CAS  Google Scholar 

  160. A. Voet, Rubber Age 103(6), 50 (1971)

    Google Scholar 

  161. Y. Fukahori, A.A. Hon, V. Jha, J.J.C. Busfield, Rubber Chem. Technol. 86, 218 (2013)

    Article  CAS  Google Scholar 

  162. G. Kraus, J. Polym. Sci. B8, 601 (1970)

    Google Scholar 

  163. A.I. Medalia, J. Colloid Interf. Sci. 32, 115 (1970)

    Article  CAS  Google Scholar 

  164. A.I. Medalia, Rubber Chem. Technol. 46, 877 (1973)

    Article  CAS  Google Scholar 

  165. A.I. Medalia, Rubber Chem. Technol. 47, 411 (1974)

    Article  CAS  Google Scholar 

  166. G.K. Batchler, J.T. Green, J. Fluid Mech. 56, 401 (1972)

    Article  Google Scholar 

  167. G.K. Batchler, J. Fluid Mech. 83, 97 (1977)

    Article  Google Scholar 

  168. H.-S. Chen, A. Acrivos, J. Solids Struct. 14, 349 (1978)

    Article  Google Scholar 

  169. J. Domurath, M. Saphiannikova, G. Heinrich, Kautschuk. Gummi Kunstst. (January-February), 40 (2017)

    Google Scholar 

  170. H. Mooibroek, K. Cornish, Appl. Microbiol. Biotechnol. 53, 355 (2000)

    Article  CAS  PubMed  Google Scholar 

  171. K. Cornish, W. Xie, D. Kostyal, D. Shintani, R.G. Hamilton, J. Biotechnol. Biomater. 5, 1000207 (2015)

    Article  Google Scholar 

  172. Y. Ikeda, A. Tohsan, S. Kohjiya, in Sustainable Development: Processes, Challenges, and Prospectives, Chap. 3, ed. by D. Reyes (Nova Science Publishers, New York, 2015)

    Google Scholar 

  173. P. Junkong, K. Cornish, Y. Ikeda, RSC Adv. 7, 50739 (2017)

    Article  CAS  Google Scholar 

  174. C.S. Barrera, K. Cornish, Ind. Crop. Prod. 86, 132 (2016)

    Article  CAS  Google Scholar 

  175. C.S. Barrera, K. Cornish, Ind. Crop. Prod. 107, 217 (2017)

    Article  CAS  Google Scholar 

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Kohjiya, S., Kato, A., Ikeda, Y. (2020). Filler and Rubber Reinforcement. In: Reinforcement of Rubber. Springer Series on Polymer and Composite Materials. Springer, Singapore. https://doi.org/10.1007/978-981-15-3789-9_2

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