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Solid Electrolytes for Advanced Applications pp 297–334Cite as

All-Solid-State Batteries Based on Glass-Ceramic Lithium Vanadate

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Abstract

In this chapter, challenges in the development of all-solid-state batteries designed to solve the problem of safety of the chemical power sources are discussed. Difficulties in the development of such batteries are poor adhesion and electrical conductivity of solids and change in the volume of materials during charge/discharge processes. To solve these problems, the use of glassy or glass-ceramic materials as the electrode is suggested. Based on vanadates glasses and glass-ceramics have attracted the most significant attention among glassy electrode materials since glassy vanadates have rather high electrical conductivity in comparison with other oxide glasses (about 10−5 S·cm−1 at room temperature). In addition, the electrical conductivity of vanadate glasses can be significantly improved by obtaining of glass-ceramic based on them. Further, results of the test of all-solid-state battery with vanadate cathode are presented. It is shown that the voltage of Li–Ga | glassy vanadate single cell achieves the value of 3.3 V.

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Abbreviations

ASSB:

ALL-SOLID-STATE BATTERY

CI:

Current interrupt

CPE:

Constant phase element

CV:

Cyclic voltammetry

DSC:

Differential scanning calorimetry

EIS:

Electrochemical impedance spectroscopy

EMF:

Electromotive force

EPR:

Electron paramagnetic resonance

h:

An hour

LAGP:

Li1.3Al0.3Ge1.7(PO4)3

LATP:

Li1.3Al0.3Ti1.7(PO4)3

LLTO:

Li0.5La0.5TiO3

LLZO:

Li7La3Zr2O12

NaS:

Sodium–sulfur battery

OCV:

Open-circuit voltage

S:

Siemens (=Ohm−1)

SHE:

Standard hydrogen electrode

TFB:

Thin-film battery

T g :

Glass transition temperature

XRD:

X-ray diffraction analysis

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Acknowledgements

The authors are grateful to Prof. R. Murugan for kindly invitation to write this chapter.

The research has been carried out with the equipment of the Shared Access Center “Composition of Compounds” of the Institute of High-Temperature Electrochemistry of Ural Branch of RAS, Yekaterinburg, Russian Federation.

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  1. Institute of High Temperature Electrochemistry, Ural Branch of RAS, Yekaterinburg, Russian Federation

    Anton A. Raskovalov & Nailya S. Saetova

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  1. Anton A. Raskovalov
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  2. Nailya S. Saetova
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Correspondence to Anton A. Raskovalov .

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  1. Department of Physics, Pondicherry University, Puducherry, India

    Ramaswamy Murugan

  2. LS Sensorik und Festkörperionik, Universität zu Kiel, Kiel, Germany

    Werner Weppner

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Raskovalov, A.A., Saetova, N.S. (2019). All-Solid-State Batteries Based on Glass-Ceramic Lithium Vanadate. In: Murugan, R., Weppner, W. (eds) Solid Electrolytes for Advanced Applications. Springer, Cham. https://doi.org/10.1007/978-3-030-31581-8_13

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