Abstract
A regional assessment of multi-decadal changes in nitrate concentrations was done using historical data and a spatially stratified non-biased approach. Data were stratified into physiographic subregions on the basis of geomorphology and soils data to represent zones of historical recharge and discharge patterns in the basin. Data were also stratified by depth to represent a shallow zone generally representing domestic drinking-water supplies and a deep zone generally representing public drinking-water supplies. These stratifications were designed to characterize the regional extent of groundwater with common redox and age characteristics, two factors expected to influence changes in nitrate concentrations over time. Overall, increasing trends in nitrate concentrations and the proportion of nitrate concentrations above 5 mg/L were observed in the east fans subregion of the Central Valley. Whereas the west fans subregion has elevated nitrate concentrations, temporal trends were not detected, likely due to the heterogeneous nature of the water quality in this area and geologic sources of nitrate, combined with sparse and uneven data coverage. Generally low nitrate concentrations in the basin subregion are consistent with reduced geochemical conditions resulting from low permeability soils and higher organic content, reflecting the distal portions of alluvial fans and historical groundwater discharge areas. Very small increases in the shallow aquifer in the basin subregion may reflect downgradient movement of high nitrate groundwater from adjacent areas or overlying intensive agricultural inputs. Because of the general lack of regionally extensive long-term monitoring networks, the results from this study highlight the importance of placing studies of trends in water quality into regional context. Earlier work concluded that nitrate concentrations were steadily increasing over time in the eastern San Joaquin Valley, but clearly those trends do not apply to other physiographic subregions within the Central Valley, even where land use and climate are similar.
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Anning DW, Paul AP, McKinney TS, Huntington JM, Bexfield LM, Thiros SA (2012) Predicted nitrate and arsenic concentrations in basin-fill aquifers of the southwestern United States. USGS Sci Investig Rep 2012-5065. http://pubs.usgs.gov/sir/2012/5065/
Belitz K, Dubrovsky NM, Burow K, Jurgens B, Johnson T (2003) Framework for a ground-water quality monitoring and assessment program for California. USGS Water Resour Investig 03-4166. http://pubs.usgs.gov/wri/wri034166/
Belitz K, Jurgens B, Landon MK, Fram MS, Johnson T (2010) Estimation of aquifer scale proportion using equal area grids: assessment of regional scale groundwater quality. Water Resour Res 46 W11550. doi:10.1029/2010WR009321
Bennett GL, Fram MS, Belitz K, Jurgens BC (2010) Status and understanding of groundwater quality in the northern San Joaquin Basin, 2005: California GAMA priority basin project. USGS Sci Investig Rep 2010-5175. http://pubs.usgs.gov/sir/2010/5175/
Bennett GL, Fram MS, Belitz K (2011) Status of groundwater quality in the southern, middle, and northern Sacramento Valley study units, 2005–08: California GAMA priority basin project. USGS Sci Investig Rep 2011-5002. http://pubs.usgs.gov/sir/2011/5002/
Bertoldi GL, Johnston RH, Evenson KD (1991) Ground water in the Central Valley, California—a summary report. USGS Prof Pap 1401-A. http://pubs.usgs.gov/pp/1401a/
Böhlke JK (2002) Groundwater recharge and agricultural contamination. Hydrogeol J 10:153–179
Broers HP, van der Grift B (2004) Regional monitoring of temporal changes in groundwater quality. J Hydrol 296:192–220. doi:10.1016/j.jhydrol.2004.03.022
Browne BA, Kraft GJ, Bowling JM, DeVita WM, Mechenich DJ (2008) Collateral geochemical impacts of agricultural nitrogen enrichment from 1963 to 1985: a southern Wisconsin ground water depth profile. J Environ Qual 37:1456–1467. doi:10.2134/jeq2007.0070
Burow KR, Shelton JL, Dubrovsky NM (1998) Occurrence of nitrate and pesticides in ground water beneath three agricultural land-use settings in the eastern San Joaquin Valley, California, 1993–1995. USGS Water Resour Investig 98-4284. http://ca.water.usgs.gov/sanj/pub/usgs/wrir97-4284/wrir97-4284.pdf
Burow KR, Dubrovsky NM, Shelton JL (2007) Temporal trends in concentrations of DBCP and nitrate in ground water in the eastern San Joaquin Valley, California, USA. Hydrogeol J 15:991–1007. doi:10.1007/s10040-006-0148-7
Burow KR, Jurgens BC, Kauffman LJ, Dalgish BA, Phillips SP, Shelton JL (2008a) Simulations of ground-water flow and particle pathline analysis in the zone of contribution of a public-supply well in Modesto, eastern San Joaquin Valley, California: USGS Sci Investig Rep 2008-5035. http://pubs.usgs.gov/sir/2008/5035/
Burow KR, Shelton JL, Dubrovsky NM (2008b) Regional nitrate and pesticide trends in ground water in the eastern San Joaquin Valley, California. J Environ Qual 37(5 Suppl):S249–S263. doi:10.2134/jeq2007.0061
Burton CA, Belitz K (2008) Ground-water quality data in the southeast San Joaquin Valley, 2005–2006—results from the California GAMA program. USGS Data Series 351. http://pubs.usgs.gov/ds/351/
California State Water Resources Control Board (2002) Nitrate/nitrite groundwater information sheet, California State Water Resources Control Board, Sacramento, CA. http://www.waterboards.ca.gov/gama/docs/nitrate_oct2002_rev3.pdf. Cited 27 September 2011
Conover WJ (1980) Practical nonparametric statistics, 2nd edn. Wiley, New York
Dubrovsky NM, Burow KR, Clark GM, Gronberg JM, Hamilton PA, Hitt KJ, et al. (2010) The quality of our nation’s water—nutrients in the nation’s streams and groundwater, 1992–2004. USGS Circular 1350. http://water.usgs.gov/nawqa/nutrients/pubs/circ1350/
Dyer KL (1965) Interpretation of chloride and nitrate ion distribution patterns in adjacent irrigated and nonirrigated Panoche soils. Soil Sci Am Proc 29:170–178
Faunt CC (ed) (2009) Groundwater availability in the Central Valley aquifer, California. USGS Prof Pap 1776. http://pubs.usgs.gov/pp/1766/
Faunt CC, Belitz K, Hanson RT (2010) Development of a three-dimensional model of sedimentary texture in valley-fill deposits of Central Valley, California, USA. Hydrogeol J 18:625–649. doi:10.1007/s10040-009-0539-7
Flipo N, Jeannee N, Poulin M, Even S, Ledoux E (2007) Assessment of nitrate pollution in the Grand Morin aquifers (France): combined use of geostatistics and physically based modeling. Environ Pollut 146:241–256
Fujii R, Swain WC (1995) Areal distribution of selected trace elements, salinity, and major ions in shallow ground water, Tulare Basin, southern San Joaquin Valley, California. USGS Water Resour Investig 95-4048
Glandon LR, Beck LA (1971) Nutrients from tile drain systems: Water Pollut Control Res Ser 13030ELY5/71-3. US Govt Printing Office, Washington, DC
Great Valley Center (2009) The state of the great Central Valley of California, assessing the region via indicators—the economy, 3rd edn. Great Valley Center, Modesto. http://www.greatvalley.org/artman2/uploads/1/econindicators09_final.pdf. Accessed 15 Sept 2011
Green CT, Puckett LJ, Böhlke JK, Bekins BA, Phillips SP, Kauffman LJ, Denver JM, Johnson HM (2008) Limited occurrence of denitrification in four shallow aquifers in agricultural areas of the United States. J Environ Qual 37:994–1009
Hansen B, Thorling L, Dalgaard T, Erlandsen M (2011) Trend reversal of nitrate in Danish groundwater—a reflection of agricultural practices and nitrogen surpluses since 1950. Environ Sci Technol 45:228–234. doi:10.1021/es102334u
Harter T, Davis H, Mathews MC, Meyer RD (2002) Shallow groundwater quality on dairy farms with irrigated forage crops. J Contam Hydrol 55:287–315
Helsel DR, Frans LM (2006) Regional Kendall test for trend. Environ Sci Technol 40(13):4066–4073
Holloway JM, Smith RL (2005) Nitrogen and carbon flow from rock to water: regulation through soil biogeochemical processes, Mokelumne River watershed, California, and Grand Valley, Colorado. J Geophys Res 110 F01010. doi:10.1029/2004JF000124
Hull LC (1984) Geochemistry of ground water in the Sacramento Valley, California. USGS Prof Pap 1401-B. http://pubs.usgs.gov/pp/1401b/
Jurgens BC, Burow KR, Dalgish BA, Shelton JL (2008) Hydrogeology, water chemistry, and factors affecting the transport of contaminants in the zone of contribution of a public-supply well in Modesto, eastern San Joaquin Valley, California. USGS Sci Investig Rep 2008-5156. http://pubs.usgs.gov/sir/2008/5156/
Katz BG, Eberts SM, Kauffman LJ (2011) Using Cl/Br ratios and other indicators to assess potential impacts on groundwater quality from septic systems: a review and examples from principal aquifers in the United States. J Hydrol 397:151–166
Landon MK, Belitz K, Jurgens BC, Kulongoski JT, Johnson TD (2010) Status and understanding of groundwater quality in the Central-Eastside San Joaquin Basin, 2006: California GAMA priority basin project: USGS Sci Investig Rep 2009-5266. http://pubs.usgs.gov/sir/2009/5266/
Landon MK, Green CT, Belitz K, Singleton MJ, Esser BK (2011) Relations of hydrogeologic factors, groundwater reduction-oxidation conditions, and temporal and spatial distributions of nitrate, Central-Eastside San Joaquin Valley, California, USA. Hydrogeol J 19:1203–1224
Letey J, Blair JW, Devitt D, Lund LJ, Nash P (1977) Nitrate-nitrogen in effluent from agricultural tile drains in California. Hilgardia 45:289–319
McMahon PB, Chapelle FH (2008) Redox processes and water quality of selected principal aquifer systems. Ground Water 46:259–271. doi:10.1111/j.1745-6584.2007.00385.x
McMahon PB, Burow KR, Kauffman LJ, Eberts SM, Böhlke JK, Gurdak JJ (2008) Simulated response of water quality in public supply wells to land use change. Water Resour Res 44 W00A06. doi:10.1029/2007WR006731
Mendenhall WC, Dole RB, Stabler H (1916) Groundwater in the San Joaquin Valley. USGS Water Suppl Pap 398. http://pubs.usgs.gov/wsp/0398
Merz C, Steidl J, Dannowski R (2009) Parameterization and regionalization of redox based denitrification for GIS-embedded nitrate transport modeling in Pleistocene aquifer systems. Environ Geol 58:1587–1599
Nightingale HI (1970) Statistical evaluation of salinity and nitrate content and trends beneath urban and agricultural areas—Fresno, California. Ground Water 8(1):22–28
Page RW (1986) Geology of the fresh ground-water basin of the Central Valley, California, with texture maps and sections. USGS Prof Pap 1401-C. http://pubs.usgs.gov/pp/1401c/
Puckett LJ, Tesoriero AJ, Dubrovsky NM (2011) Nitrogen contamination of surficial aquifers—a growing legacy. Environ Sci Technol 45:839–844. doi:10.1021/es1038358
Scanlon BR, Reedy RC, Bronson KF (2008) Impacts of land use change on nitrogen cycling archived in semiarid unsaturated zone nitrate profiles, southern high plains, Texas. Environ Sci Technol 42(20):7566–7572
Schmidt KD, Sherman I (1987) Effect of irrigation on groundwater quality in California. J Irrig Drain Eng 113:16–29
Scott JC (1990) Computerized stratified random site-selection approaches for design of a ground-water-quality sampling network. USGS Water Resour Investig Rep 90-4101. http://pubs.usgs.gov/wri/1990/4101/
Shelton JL, Pimentel Isabel, Fram MS, Belitz Kenneth (2008) Ground-water quality data in the Kern County subbasin study unit, 2006—results from the California GAMA program. USGS Data Series 337. http://pubs.usgs.gov/ds/337/
Shelton JL, Fram MS, Belitz K (2009) Groundwater-quality data in the Madera-Chowchilla study unit, 2008: results from the California GAMA program. USGS Data Series 455. http://pubs.usgs.gov/ds/455/
Spalding RF, Exner ME (1993) Occurrence of nitrate in groundwater—a review. J Environ Qual 22:392–402
Stigter TY, Dill AC, Ribeiro L (2011) Major issues regarding the efficiency of monitoring programs for nitrate contaminated groundwater. Environ Sci Technol 45:8674–8682. doi:10.1021/es201798g
Strathouse SM, Sposito G, Sullivan PJ, Lund LJ (1980) Geologic nitrogen: a potential geochemical hazard in the San Joaquin Valley, California. J Environ Qual 9(1):54–60
Strebel O, Duynisveld WHM, Böttcher J (1989) Nitrate pollution of groundwater in western Europe. Agric Ecosyst Environ 26:223–231
Sullivan PJ, Sposito G, Strathouse SM, Hansen CL (1979) Geologic nitrogen and the occurrence of high nitrate soils in the western San Joaquin Valley, California. Hilgardia 47:15–49
Thorburn PJ, Biggs JS, Weier KL, Keating BA (2003) Nitrate in groundwaters of intensive agricultural areas in coastal northeastern Australia. Agric Ecosyst Environ 94:49–58
van der Schans ML, Harter T, Leijnse A, Mathews MC, Meyer RD (2009) Characterizing sources of nitrate leaching from an irrigated dairy farm in Merced County, California. J Contam Hydrol 110:9–21
Visser A, Broers HP, Heerdink R, Bierkens MFP (2009a) Trends in pollutant concentrations in relation to time of recharge and reactive transport at the groundwater body scale. J Hydrol 369:427–439
Visser A, Dubus I, Broers HP, Brouyère S, Korcz M, Orban P et al (2009b) Comparison of methods for the detection and extrapolation of trends in groundwater quality. J Environ Monit 11:2030–2043. doi:10.1039/b905926a
Vitousek PM, Aber JD, Howarth RW, Likens GE, Matson PA, Schindler DW, Schlesinger WH, Tilman DG (1997) Human alteration of the global nitrogen cycles: sources and consequences. Ecol Appl 7(3):737–750
Walvoord MA, Phillips FM, Stonestrom DA, Evans RD, Hartsough PC, Newman BD, Striegl RG (2003) A reservoir of nitrate beneath desert soils. Nature 302:1021–1024
Wassenaar LI, Hendry MJ, Harrington N (2006) Decadal geochemical and isotopic trends for nitrate in a transboundary aquifer and implications for agricultural beneficial management practices. Environ Sci Technol 40:4626–4632
Wendland F, Kunkel R, Grimvall A, Kronvang B, Müller-Wohlfeil DI (2002) The SOIL-N/WEKU model system—a GIS supported tool for the assessment and management of diffuse nitrogen leaching at the scale of river basins. Water Sci Technol 45:285–292
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This work was supported by the USGS National Water-Quality Assessment Program (NAWQA) and the California Ambient Groundwater Monitoring Program (GAMA), which is a joint effort of the USGS and the California State Water Resources Control Board. We gratefully acknowledge David W. Anning and the anonymous reviewers for their insightful and constructive comments in the preparation of the manuscript.
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Burow, K.R., Jurgens, B.C., Belitz, K. et al. Assessment of regional change in nitrate concentrations in groundwater in the Central Valley, California, USA, 1950s–2000s. Environ Earth Sci 69, 2609–2621 (2013). https://doi.org/10.1007/s12665-012-2082-4
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DOI: https://doi.org/10.1007/s12665-012-2082-4