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Functionalized multi-walled carbon nanotubes with hyperbranched aromatic polyamide for poly(methyl methacrylate) composites

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Abstract

Multi-walled carbon nanotubes (MWCNTs) were functionalized with hyperbranched aromatic polyamide (HAP) by in situ polymerization and by the AB 2 approach to enhance the mechanical properties of poly(methylmethacrylate) (PMMA) composites. Various concentrations of HAP-functionalized MWCNTs (HAP-f-MWCNTs) were used to prepare HAP-f-MWCNT-reinforced PMMA composite films. The covalent attachment of HAP to the MWCNTs, as achieved by in situ functionalization, resulted in effective dispersion of the MWCNTs in the PMMA matrix, thus enhancing the mechanical and thermal properties of the composite films. The breaking stress of the composites increased largely with the HAP-f-MWCNT loading.

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References

  1. R. H. Baughman, A. A. Zakhidov, and W. A. de Heer, Science, 297, 787 (2002).

    Article  CAS  Google Scholar 

  2. M. Moniruzzaman and K. I. Winey, Macromolecules, 39, 5194 (2006).

    Article  CAS  Google Scholar 

  3. E. T. Thostenson, Z. Ren, and T. W. Chou, Compos. Sci. Technol., 61, 1899 (2001).

    Article  CAS  Google Scholar 

  4. F. H. Gojny, M. H. G. Wichmann, B. Fiedler, and K. Schulte, Compos. Sci. Technol., 65, 2300 (2005).

    Article  CAS  Google Scholar 

  5. S. Kanagaraj, F. R. Varanda, T. V. Zhil’tsova, M. S. A. Oliveira, and J. A. O. Simoes, Compos. Sci. Technol., 67, 3071 (2007).

    Article  CAS  Google Scholar 

  6. A. I. Zhbanov, E. G. Pogorelov, and Y. C. Chang, ACS Nano, 4, 5937 (2010).

    Article  CAS  Google Scholar 

  7. Y. S. Song and J. R. Youn, Carbon, 43, 1378 (2005).

    Article  CAS  Google Scholar 

  8. P. Pötschke, A. R. Bhattacharyya, and A. Janke, Carbon, 42, 965 (2004).

    Article  Google Scholar 

  9. R. Haggenmueller, H. H. Gommans, A. G. Rinzler, J. E. Fischer, and K. I. Winey, Chem. Phys. Lett., 330, 219 (2000).

    Article  CAS  Google Scholar 

  10. S. Rana, N. Karak, J. W. Cho, and Y. H. Kim, Nanotechnology, 19, 495707 (2008).

    Article  Google Scholar 

  11. B. K. Kuil, S. Malik, S. K. Batabyal, and A. K. Nandi, Macromolecules, 40, 278 (2007).

    Article  Google Scholar 

  12. S. K. Yadav, S. S. Mahapatra, J. W. Cho, and J. Y. Lee, J. Phys. Chem. C, 114, 11395 (2010).

    Article  CAS  Google Scholar 

  13. S. S. Mahapatra, S. K. Yadav, H. J. Yoo, and J. W. Cho, J. Mater. Chem., 21, 7686 (2011).

    Article  CAS  Google Scholar 

  14. C. Y. Hong, Y. Z. You, D. Wu, Y. Liu, and C. Y. Pan, Macromolecules, 38, 2606 (2005).

    Article  CAS  Google Scholar 

  15. A. Star and J. F. Stoddart, Macromolecules, 35, 7516 (2002).

    Article  CAS  Google Scholar 

  16. S. S. Mahapatra, S. K. Yadav, H. J. Yoo, J. W. Cho, and J. S. Park, Compos. Part B-Eng., 45, 165 (2013).

    Article  CAS  Google Scholar 

  17. Y. Yang, X. Xie, J. Wu, Z. Yang, X. Wang, and Y. W. Mai, Macromolecular Rapid Communications, 27, 1695 (2006).

    Article  CAS  Google Scholar 

  18. R. Song, D. Yang, and L. He, J. Mater. Sci., 43, 1205, (2008).

    Article  CAS  Google Scholar 

  19. Y. Wang, Z. Shi, and J. Yin, Polymer, 52, 3661 (2011).

    Article  CAS  Google Scholar 

  20. Y. I. Andrew, C. F. Sun, M. Jikei, and M. Kakimoto, Macromolecules, 33, 2832 (2000).

    Article  Google Scholar 

  21. S. K. Yadav, S. S. Mahapatra, J. W. Cho, H. C. Park, and J. Y. Lee, Fiber. Polym., 10, 756 (2009).

    Article  CAS  Google Scholar 

  22. S. Wei, Y. Zhu, Y. Zhang, and J. Xu, Reactive and Functional Polymers, 66, 1272 (2006).

    Article  CAS  Google Scholar 

  23. S. S. Mahapatra, S. Rana, and J. W. Cho, J. Appl. Polym. Sci., 120, 474 (2011).

    Article  CAS  Google Scholar 

  24. M. Das, D. Ray, S. Bandyopadhyay, S. Banerjee, N. R. Bandyopadhyay, and A. Basumallik, J. Appl. Polym. Sci., 120, 2954 (2011).

    Article  CAS  Google Scholar 

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Correspondence to Jae Whan Cho.

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Madeshwaran, S.R., Kwon, J.K. & Cho, J.W. Functionalized multi-walled carbon nanotubes with hyperbranched aromatic polyamide for poly(methyl methacrylate) composites. Fibers Polym 14, 182–187 (2013). https://doi.org/10.1007/s12221-013-0182-8

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  • DOI: https://doi.org/10.1007/s12221-013-0182-8

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