Abstract
In 2007/2008 the Institute for Reference Materials and Measurements (IRMM) organised an interlaboratory comparison (ILC) on the determination of 226Ra, 228Ra, 234U and 238U activity concentrations in mineral water. This paper describes the determination of the reference values for the activity concentrations of 234U and 238U by radiochemical separation and α-particle spectrometry performed at two independent laboratories. The experimental uncertainty of the reference values is discussed in detail.
Similar content being viewed by others
References
ISO: International Standard ISO 13528, Statistical methods for use in proficiency testing by interlaboratory comparisons. Geneva, Switzerland (2005)
Der Bundesminister für Umwelt: Naturschutz und Reaktorsicherheit: „Messanleitungen für die Überwachung der Radioaktivität in der Umwelt und zur Erfassung radioaktiver Emissionen aus kerntechnischen Anlagen”. Elsevier-Urban & Fischer Verlag, Lieferungen 1 – 7, Stand 2006, ISBN 3-437-11456-5 und ISBN 3-437-21599-x
Horwitz, E.P., Chiarizia, R., Dietz, M.L., Diamond, H.: Separation and preconcentration of actinides from acidic media by extraction chromatography. Anal. Chim. Acta 281, 361–372 (1993)
Benedik, L., Spasova, Y., Vasile, M., Wätjen, U.: Determination of 234U, 238U and 226Ra in bottled drinking water by alpha spectrometry. CD Proceedings of the 7th International Conference on Nuclear and Radiochemistry (NRC-7), Budapest, Hungary, 24–29 August 2008
Sill, C.W., Williams, R.L.: Preparation of actinides for alpha spectrometry without electrodeposition. Anal. Chem. 53, 415–421 (1981)
Sibbens, G., Pommé, S., Altzitzoglou, T.: Standardisation of low-activity actinide solutions by alpha-particle counting at a defined solid angle. Appl. Radiat. Isot. 61, 405–408 (2004)
ISO/IEC: ISO Guide 43-1, Proficiency testing by interlaboratory comparisons. Part I: Development and operation of proficiency testing schemes. Geneva, Switzerland (1997)
Pommé, S., Spasova, Y.: A practical procedure for assigning a reference value and uncertainty in the frame of an interlaboratory comparison. Accred. Qual. Assur. 13, 83–89 (2008)
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Spasova, Y., Benedik, L., Vasile, M. et al. 234U and 238U in mineral water: reference value and uncertainty evaluation in the frame of an interlaboratory comparison. J Radioanal Nucl Chem 281, 113–117 (2009). https://doi.org/10.1007/s10967-009-0069-8
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10967-009-0069-8