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Studies on Intermolecular Interactions in Liquid Mixtures of Alkoxyalkanols and Branched Alcohols by Volumetric and Acoustic Measurements at Different Temperatures

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Abstract

Densities and speeds of sound for binary mixtures of diethylene glycol monomethyl ether and triethylene glycol monomethyl ether with 3-methyl-1-butanol and 2-methyl-2-butanol were measured at 288.15, 298.15 and 308.15 K, over the entire range of compositions at atmospheric pressure, using an Anton Paar DSA 5000 density meter. The experimental densities and speeds of sound have been used to calculate excess molar volumes and excess molar isentropic compressibilities. The speed of sound data are compared with theoretical speeds of sound calculated using several approaches.

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Authors and Affiliations

  1. Department of Chemistry, Dr. B. R. Ambedkar National Institute of Technology, Jalandhar, 144 011, Punjab, India

    Harsh Kumar, Meenu Singla & Akanksha Khosla

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  1. Harsh Kumar
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  2. Meenu Singla
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  3. Akanksha Khosla
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Correspondence to Harsh Kumar.

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Kumar, H., Singla, M. & Khosla, A. Studies on Intermolecular Interactions in Liquid Mixtures of Alkoxyalkanols and Branched Alcohols by Volumetric and Acoustic Measurements at Different Temperatures. J Solution Chem 42, 428–440 (2013). https://doi.org/10.1007/s10953-013-9967-z

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