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CsF-Celite, an Efficient Solid State Reagent for the Syntheses of Thioesters and Thioethers

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Summary.

Coupling reactions of a number of aliphatic, aromatic, and heterocyclic compounds bearing an acidic hydrogen atom attached to sulfur, with alkyl, acyl, benzyl, or benzoyl halides in acetonitrile with cesium fluoride-Celite are described. This procedure is convenient, efficient, and practical for the preparation of thioethers and thioesters.

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Authors and Affiliations

  1. Abteilung für Physikalische Biochemie des Physiologisch-chemischen Instituts der Universität Tübingen, D-72076, Tübingen, Germany

    Syed T. A. Shah & Wolfgang Voelter

  2. HEJ Research Institute of Chemistry, International Center for Chemical Sciences, University of Karachi, 75270, Karachi, Pakistan

    Khalid M. Khan, Hidayat Hussain & Safdar Hayat

Authors
  1. Syed T. A. Shah
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  2. Khalid M. Khan
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  3. Hidayat Hussain
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  4. Safdar Hayat
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  5. Wolfgang Voelter
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Correspondence to Wolfgang Voelter.

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Shah, S., Khan, K., Hussain, H. et al. CsF-Celite, an Efficient Solid State Reagent for the Syntheses of Thioesters and Thioethers. Monatsh. Chem. 136, 1583–1589 (2005). https://doi.org/10.1007/s00706-005-0351-6

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  • DOI: https://doi.org/10.1007/s00706-005-0351-6

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