Summary
The influence of an adsorption process on the oxidation of oxalic acid on a gold electrode has been analysed. To disclose this influence, different supporting electrolytes have been used with different adsorption of the anion (SO 2−4 , NO −3 and ClO −4 ). Moreover, it has been studied the modifications produced in the oxidation process by the presence of some species in solution with a strong adsorption (halides), but at low concentration levels.
Zusammenfassung
Um den Einfluß der Adsorption auf die Oxidation von Oxalsäure an der Goldelektrode in saurem Medium zu untersuchen, wurden Support-Elektrolyten mit verschiedener Anionenadsorption verwendet (SO 2−4 , NO −3 und ClO −4 ). Außerdem wurden Modifikationen des Oxidationsprozesses in der Gegenwart von stark adsorbierten Spezies, diese allerdings in geringen Konzentrationen, untersucht (Halogenide).
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Albalat, R., Gómez, E., Sarret, M. et al. Influence of the adsorption on the oxidation of oxalic acid on a gold electrode in acid media. Monatsh Chem 120, 651–659 (1989). https://doi.org/10.1007/BF00809955
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DOI: https://doi.org/10.1007/BF00809955