Abstract
The aim of present work was to use jute fibrous waste from textile industries for the preparation of cellulose nanoparticles/nanofibrils suitable as reinforcement of biodegradable composites for applications in food packaging, agriculture mulch films, automotive plastics, etc. In the present study, waste jute fibers were wet pulverized to the scale of nanofibrils of 50 nm diameter using high energy planetary ball milling for 3 h. Subsequently, 3 wt% of jute fibers of millimeter, micrometer and nanometer scales were incorporated into poly lactic acid (PLA) matrix to prepare composite films by solvent casting. The reinforcement potentials of fibers at different sizes from millimeter to nanometer were investigated from the improvements in elastic modulus of composite films based on nanoindentation measurements. The increase in elastic modulus was observed to be 65.21, 25.40 and 13.04 % for composite films of nanofibrils, microfibrils and milifibers, respectively compared to neat PLA film. These improvements were attributed to the increased interaction between fibers and matrix as well as to the increased crystallinity of PLA in composites.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
References
W. Wang, Recycling in textiles, (2006) Woodhead publishing UK.
R. Horrocks, Recycling textile and plastic waste, (1996) Woodhead publishing, UK.
C.W.M. Yuen, Y. F. Cheng, Y. Li, and J. Y. Hu, Journal of Textile Institute, 100,165 (2009).
H. P. S. Khalil, A. H. Bhat, and A. F. Yusra, Carbohydrate Polymers, 87, 963 (2012).
D. Klemm, D. Schumann, F. Kramer, N. Hebler, M. Hornung, H. Schmauder, and S. Marsch, Advances in Polymer Science, 205, 49 (2006).
J. Mussig, and C. Stevens, Industrial Applications of Natural Fibers: Structure, Properties and Technical Applications, (2010) Wiley.
A. Dufresne, M. B. Kellerhals, and B. Witholt, Macromolecules, 32, 7396 (1999).
M. F. Rosa, E. S. Medeiros, J. A. Malmonge, K. S. Gregorski, D. F. Wood, L. H. C. Mattoso, G. Glenn, W. J. Orts and S. H. Imam, Carbohydrate Polymers, 81, 83 (2010).
D. Pasquini, E. D. M. Teixeira, A. A. D. S. Curvelo, M. N. Belgacem and A. Dufresne, Industrial Crops and Products, 32, 486 (2010).
R. Zuluaga, J. L. Putaux, J. Cruz, J. Velez, I. Mondragon and P. Ganan, Carbohydrate Polymers, 76, 51 (2009).
R. Li, J. Fei, Y. Cai, Y. Li, J. Feng and J. Yao, Carbohydrate Polymers, 76, 94 (2009).
B. Wang and M. Sain, Composite Science and Technology, 67, 2521 (2007).
A. Alemdar and M. Sain, Bioresource Technology, 99, 1664 (2008).
N. Reddy and Y. Yang, Polymer, 46, 5494 (2005).
D. Y. Liu, X. W. Yuan, D. Bhattacharyya, and A. J. Easteal, Express Polymer Letters, 4, 26 (2010).
P. Satyamurthy, P. Jain, R. Balasubramanya, and N. Vigneshwaran, Carbohydrate Polymers, 83,122 (2011).
W. Li, J. Yue, and S. Liu, Ultrasonics Sonochemistry, 19, 479 (2012).
J. Leitner, B. Hinterstoisser, M. Wastyn, J. Keches, and W. Gindl, Cellulose, 14, 419 (2007).
S. Thomas, and L. A. Pothan, Natural fiber reinforced polymer composites, (2008) Old City Publishing USA.
J. Lunt, Polymer Degradation and Stability, 59, 145 (1998).
M. Jonnobi, J. Harun, A. P. Mathew, and K. Oksman, Composite Science and Technology, 70, 1742 (2010).
K. Petersen, P. Nielsen, and M. Olsen, Starch, 53, 356 (2001).
L. Petersson, and K. Oksman, Composite Science and Technology, 66, 2187 (2006).
M. D. Sanchez-Garcia, E. Gimenez, and J. M. Lagaron, Carbohydrate Polymers, 71, 235 (2008).
X. Li, and B. Bhushan, Materials Characterization, 48, 11 (2002).
B. D. Beake, and G. J. Leggett, Polymer, 43, 319 (2002)
A.H.W. Ngan, and B. Tang, Journal of Materials Research,17, 2604 (2002).
C. A. Schuh, Materials Today, 9, 32 (2006).
V. Baheti, and J. Militky, Fibers and Polymers, 14, 133 (2013).
V. Baheti, J. Militky, and M. Marsalkova, Polymer Composites, 34, 2133 (2013).
Author information
Authors and Affiliations
Corresponding author
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2016 RILEM
About this paper
Cite this paper
Baheti, V., Militky, J. (2016). Nanoindentation Measurements of Jute/Poly Lactic Acid Composites. In: Fangueiro, R., Rana, S. (eds) Natural Fibres: Advances in Science and Technology Towards Industrial Applications. RILEM Bookseries, vol 12. Springer, Dordrecht. https://doi.org/10.1007/978-94-017-7515-1_11
Download citation
DOI: https://doi.org/10.1007/978-94-017-7515-1_11
Published:
Publisher Name: Springer, Dordrecht
Print ISBN: 978-94-017-7513-7
Online ISBN: 978-94-017-7515-1
eBook Packages: EngineeringEngineering (R0)