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Comparison of FT-IR and Raman Spectroscopy

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Analytical Applications of FT-IR to Molecular and Biological Systems

Part of the book series: NATO Advanced Study Institutes Series ((ASIC,volume 57))

Abstract

Paralleling the evolution of Fourier Transform Infrared Spectroscopy during the 1960’s and 1970’s there have been rapid developments in the area of Raman spectroscopy. The laser serves only in a secondary role for FT-IR spectroscopy, but as a source for excitation it has greatly revolutionized conventional Raman spectroscopy and led to the advent of new techniques including coherent anti-Stokes Raman scattering (CARS), Raman gain, inverse or hyper- Raman spectroscopy. Both FT-IR and Raman techniques have also benefited from the improvements in optoelectronic and data processing systems. While a moving mirror with high mechanical precision and a high quality beam splitter are basic to an FT-IR instrument, a double monochromator with precision gratings, which may be holographic, and a laser as light source are intrinsic to a Raman spectrometer. Improved detector systems (pyroelectric bolometers, such as triglycine sulfate, TGS, for FT-IR or photon counting for Raman), not available a decade ago now serve vital functions. Utilization of an on-line mini-computer is all but essential for practical FT-IR spectroscopy in order to facilitate the data handling and computation; it can also serve as a valuable accessory for the signal averaging and manipulation of Raman data.

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Authors and Affiliations

  1. Physikalisches Institut, Universität der Bayreuth, Bayreuth, West Germany

    W. Kiefer & J. Laane

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  1. W. Kiefer
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  2. J. Laane
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Editors and Affiliations

  1. College of Science and Mathematics, University of South Carolina, Columbia, South Carolina, USA

    James R. Durig

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Kiefer, W., Laane, J. (1980). Comparison of FT-IR and Raman Spectroscopy. In: Durig, J.R. (eds) Analytical Applications of FT-IR to Molecular and Biological Systems. NATO Advanced Study Institutes Series, vol 57. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-9070-8_26

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  • DOI: https://doi.org/10.1007/978-94-009-9070-8_26

  • Publisher Name: Springer, Dordrecht

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