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New routes to molybdenum nitrides and oxynitrides: preparation and characterization of new phases

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The Chemistry of Transition Metal Carbides and Nitrides

Abstract

This paper presents the synthesis of new forms of molybdenum nitride and oxynitride. A face-centred cubic γ-Mo2N type oxynitride phase with excess nonmetal content is prepared by the reaction of ammonia with MoO3 and is characterized by X-ray and neutron diffraction. Its composition, surface area, and morphology depend on the synthesis conditions. The reaction between MoCl5 and calcium nitride in a flux leads to a new Mo2N structure type isotypic with pseudohexagonal α-Mo2C. Starting from MoS2, the products of the reaction with ammonia are two phases related to hexagonal δ-MoN depending on the reaction conditions.

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References

  1. S.T. Oyama. Catal. Today, 15, 179 (1992).

    Article  CAS  Google Scholar 

  2. A.I. Gusev. Russ. Chem. Rev., 57, 913 (1988)

    Article  Google Scholar 

  3. A.I. Gusev. Phys. Stat. Sol., 156, 11 (1989)

    Article  CAS  Google Scholar 

  4. A.I. Gusev. Phys. Stat. Sol., 163, 17 (1991).

    Article  CAS  Google Scholar 

  5. L.E. Toth. Transition metal carbides and nitrides. (Academic Press, New York, 1971).

    Google Scholar 

  6. E.K. Storm. The refractory carbides. (Academic Press, New York, 1967).

    Google Scholar 

  7. S.T. Oyama and G.L. Haller. Catalysis Specialist Periodical Report, (Royal Society of Chemistry, London, vol. 5, 1982).

    Google Scholar 

  8. L. Leclerq. In: Surface properties and catalysis by nonmetals, J.P. Bonnelle, B. Delmon and E. Derouanne, Eds, (Reidel, Dordrecht, 1983).

    Google Scholar 

  9. L. Volpe and M. Boudart. J. Solid State Chem., 59, 332 (1985).

    Article  CAS  Google Scholar 

  10. L. Volpe and M. Boudart. J. Solid State Chem., 59, 348 (1985).

    Article  CAS  Google Scholar 

  11. J.S. Lee, L. Volpe et al. J. Catal., 112, 44 (1988).

    Article  CAS  Google Scholar 

  12. J.S. Lee, S.T. Oyama and M. Boudart. J. Catal., 106, 125 (1987).

    Article  CAS  Google Scholar 

  13. M. Boudart, S.T. Oyama and L. Volpe. U.S. Patent 4, 515, 763 (1985).

    Google Scholar 

  14. M. Boudart, S.T. Oyama and L. Volpe. U.S. Patent 4, 851, 206 (1989).

    Google Scholar 

  15. L. Volpe, S.T. Oyama and M. Boudart. In: Preparation of Catalysts, III, G. Poncelet, P. Grange and P.A. Jacobs, Eds, (1983).

    Google Scholar 

  16. S.T. Oyama, Ph.D. Thesis, Stanford University (1981).

    Google Scholar 

  17. L. Volpe and M. Boudart. Catal. Rev.-Sci. Eng., 27, 515 (1985).

    Article  CAS  Google Scholar 

  18. S.T. Oyama, J.C. Schlatter, J.E. Metcalfe and J.M. Lambert. Ind. Eng. Chem. Res., 27, 1639 (1988).

    Article  CAS  Google Scholar 

  19. S.T. Oyama, R. Kapoor, H.T. Oyama and D.J. Hofmann. J. Mater. Res., 8, 1450 (1993).

    Article  CAS  Google Scholar 

  20. C.H. Jaggers, Ph.D. Thesis, University of California, Berkeley (1988).

    Google Scholar 

  21. C.H. Jaggers, J.N. Michaels and A.M. Stacy. Chem. Mat., 2, 150 (1990).

    Article  CAS  Google Scholar 

  22. J.-G. Choi, J.R. Brenner, C.W. Colling, B.G. Demezyk, J.L. Dunning and L.T. Thompson. Catal. Today, 15, 201 (1992).

    Article  CAS  Google Scholar 

  23. G.S. Ranhotra, G.W. Haddix, A.T. Bell and J.A. Reimer. J. Catal., 108, 24 (1987).

    Article  CAS  Google Scholar 

  24. M.D. Lyutaya. Sov. Powder Metal. Met. Ceram. (Engl. Transl.), 3, 190 (1979).

    Article  Google Scholar 

  25. R. Marchand, Y. Laurent, J. Guyader, P. L’Haridon and P. Verdier. J. Europ. Ceram. Soc, 8, 197(1991).

    Article  Google Scholar 

  26. X. Gouin, R. Marchand, P. L’Haridon and Y. Laurent. J. Solid State Chem., 109, 175 (1994).

    Article  CAS  Google Scholar 

  27. G. Bienvenu, French Patent no 87 00097 FR 2, 609, 461 (1987).

    Google Scholar 

  28. C. Barat and R. Marchand, Unpublished results.

    Google Scholar 

  29. E.D. Eastman, D.D. Cubicciotti and C.D. Thurmond. In: Phase diagrams for Ceramists, Vol. II, E.M. Levin, C.R. Robbins and H.F. McMurdie, Eds, (The American Ceramic Society, 1969).

    Google Scholar 

  30. E. Parthe and V. Sadagopan. Acta Cryst., 16, 202 (1963).

    Article  CAS  Google Scholar 

  31. A.L. Bowman, T.C. Wallace, J.L. Yarnell, R.G. Wenzel and E.K. Storms. Acta Cryst., 19, 6 (1965).

    Article  CAS  Google Scholar 

  32. P. Ettmayer, A. Vendl and R. Kieffer. High Temp.-High Press., 10, 699 (1978).

    CAS  Google Scholar 

  33. Ca5MoN5 JCPDS file no 23–121.

    Google Scholar 

  34. F. Tessier, R. Marchand and Y. Laurent. To be published.

    Google Scholar 

  35. A.F. Wells. Structural inorganic chemistry. (Clarendon Press, Oxford, 1975).

    Google Scholar 

  36. J. Milbauer. Z. anorg. Allgem. Chem., 42, 433 (1904).

    CAS  Google Scholar 

  37. D.H. Kerridge and S.J. Walker. J. Inorg. Nucl. Chem., 39, 1579 (1977).

    Article  CAS  Google Scholar 

  38. F. Tessier and R. Marchand. Unpublished results.

    Google Scholar 

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Authors and Affiliations

  1. URA 1496 CNRS “Verres et Céramiques”, Laboratoire de Chimie des Matériaux, Université de Rennes 1, Campus de Beaulieu, F-35042, Rennes Cedex, France

    R. Marchand, X. Gouin, F. Tessier & Y. Laurent

Authors
  1. R. Marchand
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  2. X. Gouin
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  3. F. Tessier
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  4. Y. Laurent
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Editor information

Editors and Affiliations

  1. Department of Chemical Engineering, Virginia Polytechnic Institute and State University, Blacksburg, Virginia, 24061-0211, USA

    S. T. Oyama (Professor) (Professor)

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© 1996 Chapman & Hall

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Marchand, R., Gouin, X., Tessier, F., Laurent, Y. (1996). New routes to molybdenum nitrides and oxynitrides: preparation and characterization of new phases. In: Oyama, S.T. (eds) The Chemistry of Transition Metal Carbides and Nitrides. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-1565-7_13

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  • DOI: https://doi.org/10.1007/978-94-009-1565-7_13

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-94-010-7199-4

  • Online ISBN: 978-94-009-1565-7

  • eBook Packages: Springer Book Archive

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