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Organometallic Ion Chemistry pp 197–228Cite as

Development of a Fourier-Transform Ion Cyclotron Resonance (FTICR) Mass Spectrometry Method for Studies of Metal Ion Excited States

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Part of the book series: Understanding Chemical Reactivity ((UCRE,volume 15))

Abstract

Studies of ion-molecule reaction chemistry of gas-phase transition metal ions have rapidly expanded and the field of gas phase organometallic chemistry has emerged [1]. Eller and Schwarz have compiled an amazingly comprehensive review of this entire field that covers the period 1973 to 1992 [2]. The pioneering gas-phase ion chemistry studies emphasized the type of reactions, product ion distribution, and speculation on reaction mechanisms; however, the most important contribution of much of this work is to the understanding of reaction energetics and bond energies to metal centers [3]. In the last few years, several groups have placed considerable attention on the specific electronic state(s) of the reacting metal ion (M+) and how the reactivity of M+ might change if different excited states are formed by the ionizing process.

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Author information

Authors and Affiliations

  1. Department of Chemistry, Texas A&M University, College Station, Texas, 77843, USA

    David H. Russell, J. V. B. Oriedo & Touradj Solouki

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  1. David H. Russell
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  2. J. V. B. Oriedo
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  3. Touradj Solouki
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Editors and Affiliations

  1. H.C. Brown Laboratory of Chemistry, Purdue University, West Lafayette, Indiana, USA

    Ben S. Freiser

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© 1996 Kluwer Academic Publishers

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Russell, D.H., Oriedo, J.V.B., Solouki, T. (1996). Development of a Fourier-Transform Ion Cyclotron Resonance (FTICR) Mass Spectrometry Method for Studies of Metal Ion Excited States. In: Freiser, B.S. (eds) Organometallic Ion Chemistry. Understanding Chemical Reactivity, vol 15. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-0111-7_6

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  • DOI: https://doi.org/10.1007/978-94-009-0111-7_6

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-94-010-6536-8

  • Online ISBN: 978-94-009-0111-7

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