Abstract
Extensive research has been conducted on the removal of organic pollutants in water using heterogeneous photocatalysis. This study reviews some of the recent reports on TiO2 photocatalysis applied for degradation of pesticides. The role of the operating parameters in the optimization of the process, the strategies used to develop visible active titania based photocatalysts and various ways to increase the cost-effectiveness of the photocatalytic processes are discussed. From the papers reviewed it can be concluded that under optimal conditions high efficiency in the photodegradation of pesticides can be reached.
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Ahmed S, Rasul MG, Brown R, Hashib MA (2011) Influence of parameters on the heterogeneous photocatalytic degradation of pesticides and phenolic contaminants in wastewater: a short review. J Environ Manage 92:311–330
Akpan UG, Hameed BH (2009) Parameters affecting the photocatalytic degradation of dyes using TiO2-based photocatalysts: a review. J Hazard Mater 170:520–529
Araña J, Garriga i Cabo C, Fernández Rodríguez C, Herrera Melián JA, Ortega Méndez JA, Doña Rodríguez JM, Pérez Peña J (2008) Combining TiO2-photocatalysis and wetland reactors for the efficient treatment of pesticides. Chemosphere 71:788–794
Arias-Estévez M, Lopez-Periago E, Martinez-Carballo E, Simal-Gandara J, Mejuto J-C, García-Río L (2008) The mobility and degradation of pesticides in soils and the pollution of groundwater resources. Ecosyst Environ 123:247–260
Barka N, Assabbane A, Nounahb A, Aît Ichou Y (2008) Photocatalytic degradation of indigo carmine in aqueous solution by TiO2-coated non-woven fibres. J Hazard Mater 152:1054–1059
Barka N, Qourzal S, Assabbane A, Nounahb A, Aît-Ichou Y (2008) Factors influencing the photocatalytic degradation of Rhodamine B by TiO2-coated non-woven paper. J Photochem Photobiol A Chem 195:346–351
Chowdhury P, Moreira J, Gomaa H, Ray AK (2012) Visible-solar-light-driven photocatalytic degradation of phenol with dye-sensitized TiO2: parametric and kinetic study. Ind Eng Chem Res 51:4523–4532
Damardji B, Khalaf H, Duclaux L, David B (2009) Preparation of TiO2-pillared montmorillonite as photocatalyst Part II. Photocatalytic degradation of a textile azo dye. Appl Clay Sci 45:98–104
Devi LG, Murthy BN, Kumar SG (2009) Photocatalytic activity of V5+, Mo6+ and Th4+ doped polycrystalline TiO2 for the degradation of chlorpyrifos under UV/solar light. J Mol Catal A Chem 308:174–181
Devipriya S, Yesodharan S (2005) Photocatalytic degradation of pesticide contaminants in water. Sol Energy Mater Sol Cells 86:309–348
Fenoll J, Ruiz E, Hellín P, Flores P, Navarro S (2011) Heterogeneous photocatalytic oxidation of cyprodinil and fludioxonil in leaching water under solar irradiation. Chemosphere 85:1262–1268
Furukawa S, Shishido T, Teramura K, Tanaka T (2012) Photocatalytic oxidation of alcohols over TiO2 covered with Nb2O5. ACS Catal 2:175–179
Gaya UI, Abdullah AH (2008) Heterogeneous photocatalytic degradation of organic contaminants over titanium dioxide: a review of fundamentals, progress and problems. J Photochem Photobiol C Photochem Rev 9:1–12
Hoffmann MR, Martin ST, Choi W, Bahnemannt DW (1995) Environmental applications of semiconductor photocatalysis. Chem Rev 95:69–96
Kaneco S, Li N, Itoh K, Katsumata H, Suzuki T, Ohta K (2009) Titanium dioxide mediated solar photocatalytic degradation of thiram in aqueous solution: kinetics and mineralization. Chem Eng J 148:50–56
Kashif N, Ouyang F (2009) Parameters effect on heterogeneous photocatalysed degradation of phenol in aqueous dispersion of TiO2. J Environ Sci 21:527–533
Kuo WS, Chiang YH, Lai LS (2008) Solar photocatalysis of carbaryl rinsate promoted by dye photosensitization. Dye Pigment 76:82–87
Lhomme L, Brosillon S, Wolbert D (2008) Photocatalytic degradation of pesticides in pure water and a commercial agricultural solution on TiO2 coated media. Chemosphere 70:381–386
Liu W, Chen S, Zhao W, Zhang S (2009) Titanium dioxide mediated photocatalytic degradation of methamidophos in aqueous phase. J Hazard Mater 164:154–160
Liu W, Chen S, Zhao W, Zhang S (2009) Study on the photocatalytic degradation of trichlorfon in suspension of titanium dioxide. Desalination 249:1288–1293
Mahalakshmi M, Priya SV, Arabindoo B, Palanichamy M, Murugesan V (2009) Photocatalytic degradation of aqueous propoxur solution using TiO2 and Hβ zeolite-supported TiO2. J Hazard Mater 161:336–343
Mahmoodi NM, Arami M, Gharanjiga K, Nourmohammadiana F, Bidokhti AY (2008) Purification of water containing agricultural organophosphorus pollutant using titania nanophotocatalysis: laboratory studies and numerical modeling. Desalination 230:183–192
Malato S, Fernández-Ibáñez P, Maldonado MI, Blanco J, Gernjak W (2009) Decontamination and disinfection of water by solar photocatalysis: recent overview and trends. Catal Today 147:1–59
Oppenlander T (2003) Photochemical purification of water and air. WILEY-VCH Verlag, Weinheim
Park J-H (2009) Photochemical degradation and toxicity reduction of methyl 1-[(butylamino)carbonyl]-1H-benzimidazol-2-ylcarbamate in agricultural wastewater: comparative study of photocatalysis and sonophotocatalysis. Desalination 249:480–485
Pourata R, Khataee AR, Aber S, Daneshvar N (2009) Removal of the herbicide Bentazon from contaminated water in the presence of synthesized nanocrystalline TiO2 powders under irradiation of UV-C light. Desalination 249:301–307
Robert D, Malato S (2002) Solar photocatalysis: a clean process for water detoxification. Sci Total Environ 291:85–97
Robertson PKJ (1996) Semiconductor photocatalysis: an environmentally acceptable alternative production technique and effluent treatment process. J Clean Prod 4:203–212
Robertson PKJ, Robertson JMC, Bahnemann DW (2012) Removal of microorganisms and their chemical metabolites from water using semiconductor photocatalysis. J Hazard Mater 211–212:161–171
Saien J, Khezrianjoo S (2008) Degradation of the fungicide carbendazim in aqueous solutions with UV/TiO2 process: optimization, kinetics and toxicity studies. J Hazard Mater 157:269–276
Senthilnathan J, Philip L (2010) Photocatalytic degradation of lindane under UV and visible light using N-doped TiO2. Chem Eng J 161:83–92
Sharma MVP, Durgakumari V, Subrahmanyam M (2008) TiO2 supported over SBA-15: an efficient photocatalyst for the pesticide degradation using solar light. Chemosphere 73:1562–1569
Sharma MVP, Durgakumari V, Subrahmanyam M (2008) Solar photocatalytic degradation of isoproturon over TiO2/H-MOR composite systems. J Hazard Mater 160:568–575
Sharma MVP, Durgakumari V, Subrahmanyam M (2008) Photocatalytic degradation of isoproturon herbicide over TiO2/Al-MCM-41 composite systems using solar light. Chemosphere 72:644–651
Sharma MVP, Lalitha K, Durgakumari V, Subrahmanyam M (2008) Solar photocatalytic mineralization of isoproturon over TiO2/HY composite systems. Sol Energy Mater Sol Cell 92:332–342
Sharma MVP, Sadanandam G, Ratnamala A, Durgakumari V, Subrahmanyam M (2009) An efficient and novel porous nanosilica supported TiO2 photocatalyst for pesticide degradation using solar light. J Hazard Mater 171:626–633
Vilar VJP, Moreira FC, Ferreira ACC, Sousa MA, Gonçalves C, Alpendurada MF, Boaventura RAR (2012) Biodegradability enhancement of a pesticide-containing bio-treated wastewater using solar photo-Fenton treatment step followed by a biological oxidation process. Water Res 46:4599–4613
Wang H, Wang H-L, Jiang W-F, Li Z-Q (2009) Photocatalytic degradation of 2,4-dinitrophenol (DNP) by multi-walled carbon nanotubes (MWCNTs)/TiO2 composite in aqueous solution under solar irradiation. Water Res 43:204–210
Wu R-J, Chen C-C, Chen M-H, Lu C-S (2009) Titanium dioxide-mediated heterogeneous photocatalytic degradation of terbufos: parameter study and reaction pathways. J Hazard Mater 162:945–953
Yahiat S, Fourcade F, Brosillon S, Amrane A (2011) Photocatalysis as a pre-treatment prior to a biological degradation of cyproconazole. Desalination 281:61–67
Zhang M, Shao C, Guo Z, Zhang Z, Mu J, Zhang P, Cao T, Liu Y (2011) Highly efficient decomposition of organic dye by aqueous-solid phase transfer and in situ photocatalysis using hierarchical copper phthalocyanine hollow spheres. ACS Appl Mater Interfaces 3:2573–2578
Zhiyong Y, Keppner H, Laub D, Mielczarski E, Mielczarski J, Kiwi-Minsker L, Renken L, Kiwi J (2008) Photocatalytic discoloration of Methyl Orange on innovative parylene–TiO2 flexible thin films under simulated sunlight. Appl Catal Environ 79:63–71
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Dârjan, A., Drăghici, C., Perniu, D., Duţă, A. (2013). Degradation of Pesticides by TiO2 Photocatalysis. In: Simeonov, L., Macaev, F., Simeonova, B. (eds) Environmental Security Assessment and Management of Obsolete Pesticides in Southeast Europe. NATO Science for Peace and Security Series C: Environmental Security. Springer, Dordrecht. https://doi.org/10.1007/978-94-007-6461-3_14
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DOI: https://doi.org/10.1007/978-94-007-6461-3_14
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