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Nitro- and Nitro-Oxy-Compounds in Multiphase Particle Chemistry: Field and Analytical Studies

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Book cover Disposal of Dangerous Chemicals in Urban Areas and Mega Cities

Abstract

Recent field evidence shows the presence of nitro-phenolic compounds in biomass burning influenced secondary organic aerosol. The results from laboratory and smog chamber experiments suggest that these compounds likely form from the reaction of gas-phase phenolic compounds originating from biomass burning in the presence of NOx. These compounds contribute as much as 3.8% to the organic carbon fraction of wintertime aerosols collected in a rural German village, indicating that they are important secondary organic aerosol constituents during the winter months.

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References

  1. Altieri KE, Turpin BJ, Seitzinger SP (2009) Composition of dissolved organic nitrogen in continental precipitation investigated by ultra-high resolution FT-ICR mass spectrometry. Environ Sci Technol 43:6950–6955

    Article  CAS  Google Scholar 

  2. Altieri KE, Turpin BJ, Seitzinger SP (2009) Oligomers, organosulfates, and nitrooxy organosulfates in rainwater identified by ultra-high resolution electrospray ionization FT-ICR mass spectrometry. Atmos Chem Phys 9:2533–2542

    Article  CAS  Google Scholar 

  3. Anastasio C, Sun J (2009) SOA formation via aqueous reactions of phenols from wood combustion. Geochim Cosmochim Ac 73:A39

    Google Scholar 

  4. Atkinson R, Aschmann SM, Arey J (1992) Reactions of OH and NO3 radicals with phenol, cresols, and 2-nitrophenol at 296-K+-2-K. Environ Sci Technol 26:1397–1403

    Article  CAS  Google Scholar 

  5. Barzaghi P, Herrmann H (2002) A mechanistic study of the oxidation of phenol by OH/NO2/NO3 in aqueous solution. Phys Chem Chem Phys 4:3669–3675

    Article  CAS  Google Scholar 

  6. Goldstein AH, Galbally IE (2007) Known and unexplored organic constituents in the earth’s atmosphere. Environ Sci Technol 41:1514–1521

    Article  CAS  Google Scholar 

  7. Gómez-González Y, Surratt JD, Cuyckens F, Szmigielski R, Vermeylen R, Jaoui M, Lewandowski M, Offenberg JH, Kleindienst TE, Edney EO, Blockhuys F, Van Alsenoy C, Maenhaut W, Claeys M (2008) Characterization of organosulfates from the photooxidation of isoprene and unsaturated fatty acids in ambient aerosol using liquid chromatography/(-) electrospray ionization mass spectrometry. J Mass Spectrom 43:371–382

    Article  Google Scholar 

  8. Grieshop AP, Donahue NM, Robinson AL (2009) Laboratory investigation of photochemical oxidation of organic aerosol from wood fires 2: analysis of aerosol mass spectrometer data. Atmos Chem Phys 9:2227–2240

    Article  CAS  Google Scholar 

  9. Grieshop AP, Logue JM, Donahue NM, Robinson AL (2009) Laboratory investigation of photochemical oxidation of organic aerosol from wood fires 1: measurement and simulation of organic aerosol evolution. Atmos Chem Phys 9:1263–1277

    Article  CAS  Google Scholar 

  10. Hallquist M, Wenger JC, Baltensperger U, Rudich Y, Simpson D, Claeys M, Dommen J, Donahue NM, George C, Goldstein AH, Hamilton JF, Herrmann H, Hoffmann T, Iinuma Y, Jang M, Jenkin ME, Jimenez JL, Kiendler-Scharr A, Maenhaut W, McFiggans G, Mentel TF, Monod A, Prevot ASH, Seinfeld JH, Surratt JD, Szmigielski R, Wildt J (2009) The formation, properties and impact of secondary organic aerosol: current and emerging issues. Atmos Chem Phys 9:5155–5236

    Article  CAS  Google Scholar 

  11. Iinuma Y, Müller C, Berndt T, Böge O, Claeys M, Herrmann H (2007) Evidence for the existence of organosulfates from β-pinene ozonolysis in ambient secondary organic aerosol. Environ Sci Technol 41:6678–6683

    Article  CAS  Google Scholar 

  12. Iinuma Y, Böge O, Gräfe R, Herrmann H (2010) Methyl-nitrocatechols: atmospheric tracer compounds for biomass burning secondary organic aerosols. Environ Sci Technol 44:8453–8459

    Article  CAS  Google Scholar 

  13. Kristensen K, Glasius M (2011) Organosulfates and oxidation products from biogenic hydrocarbons in fine aerosols from a forest in North West Europe during spring. Atmos Environ 45:4546–4556

    Article  CAS  Google Scholar 

  14. Lukács H, Gelencsér A, Hoffer A, Kiss G, Horváth K, Hartyáni Z (2009) Quantitative assessment of organosulfates in size-segregated rural fine aerosol. Atmos Chem Phys 9:231–238

    Article  Google Scholar 

  15. Maenhaut W, Raes N, Chi XG, Cafmeyer J, Wang W (2008) Chemical composition and mass closure for PM2.5 and PM10 aerosols at K-puszta, Hungary, in summer 2006. X-Ray Spectrom 37:193–197

    Article  CAS  Google Scholar 

  16. Schauer JJ, Kleeman MJ, Cass GR, Simoneit BRT (2001) Measurement of emissions from air pollution sources. 3. C-1-C-29 organic compounds from fireplace combustion of wood. Environ Sci Technol 35:1716–1728

    Article  CAS  Google Scholar 

  17. Sun YL, Zhang Q, Anastasio C, Sun J (2010) Insights into secondary organic aerosol formed via aqueous-phase reactions of phenolic compounds based on high resolution mass spectrometry. Atmos Chem Phys 10:4809–4822

    Article  CAS  Google Scholar 

  18. Surratt JD, Gomez-Gonzalez Y, Chan AWH, Vermeylen R, Shahgholi M, Kleindienst TE, Edney EO, Offenberg JH, Lewandowski M, Jaoui M, Maenhaut W, Claeys M, Flagan RC, Seinfeld JH (2008) Organosulfate formation in biogenic secondary organic aerosol. J Phys Chem A 112:8345–8378

    Article  CAS  Google Scholar 

  19. van Pinxteren D, Bruggemann E, Gnauk T, Iinuma Y, Muller K, Nowak A, Achtert P, Wiedensohler A, Herrmann H (2009) Size- and time-resolved chemical particle characterization during CAREBeijing-2006: different pollution regimes and diurnal profiles. J Geophys Res [Atmos] 114. doi:10.1029/2008JD010890

    Google Scholar 

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Correspondence to Yoshiteru Iinuma .

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Iinuma, Y., Herrmann, H. (2013). Nitro- and Nitro-Oxy-Compounds in Multiphase Particle Chemistry: Field and Analytical Studies. In: Barnes, I., Rudziński, K. (eds) Disposal of Dangerous Chemicals in Urban Areas and Mega Cities. NATO Science for Peace and Security Series C: Environmental Security. Springer, Dordrecht. https://doi.org/10.1007/978-94-007-5034-0_15

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